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Sodium molybdate, Na2MoO4, is useful as a source of molybdenum. This white, crystalline salt is often found as the dihydrate, Na2MoO4·2H2O. The molybdate(VI) anion is tetrahedral. Two sodium cations coordinate with every one anion.

Application

Used in the measurement of acid and alkali, raw material for the production of fire retardant. It can also be used in circulating cooling systems, metalworking liquid, and other fields as corrosion in. And also can use for fertilizer.

 Sodium molybdate can be used in the making of alkaloids, reagents, dye, molybdenum red pigment, molybdenum, the material of fire retardant, and its catalyst can be used as an inhibitor.

Applications: used as a catalyst for the petrochemical industry, in the metallurgic industry, it is used for making molybdenum powder, molybdenum bar, molybdenum wire, and molybdenum plate, it can also be used for the microelement of the fertilizer and ceramic pigment making and metal surface treatment, raw materials for pigment and other molybdenum products.

Uses

The agriculture industry uses 1 million pounds per year as a fertilizer. In particular, its use has been suggested for the treatment of whiptail in broccoli and cauliflower in molybdenum-deficient soils. However, care must be taken because a level of 0.3 ppm sodium molybdate can cause copper deficiencies in animals, particularly cattle.

It is used in industry for corrosion inhibition, as it is a non-oxidizing anodic inhibitor. The addition of sodium molybdate significantly reduces the nitrite requirement of fluids inhibited with nitrite-amine and improves the corrosion protection of carboxylate salt fluids. In industrial water treatment applications where galvanic corrosion is a potential due to bimetallic construction, the application of sodium molybdate is preferred over sodium nitrite. Sodium molybdate has the advantage in that the dosing of lower ppm's of molybdate allows for lower conductivity of the circulating water. 

Sodium molybdate at levels of 50-100 ppm offers the same levels of corrosion inhibition as sodium nitrite at levels of 800+ ppm. By utilizing lower concentrations of sodium molybdate, conductivity is kept at a minimum and thus galvanic corrosion potentials are decreased.

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