Sulfuric Acid 98%
- Part number
- RXSOL-19-1104-060
- Category
- Solvent Chemicals
- Brand
- RXSOL
Overview
Pure sulfuric acid has a specific gravity of 1.830 at 25° C (77° F); it freezes at 10.37° C (50.7° F). When heated, the pure acid partially decomposes into water and sulfur trioxide; the latter escapes as a vapour until the concentration of the acid falls to 98.3 percent. This mixture of sulfuric acid and water boils at a constant temperature of 338° C (640° F) at one atmosphere pressure. Sulfuric acid is commonly supplied at concentrations of 78, 93, or 98 percent.
Characteristics and notes
-
CAS Number of Sulfuric Acid 7664-93-9
-
Linear Formula of Sulfuric Acid H2SO4
-
Molecular Weight of Sulfuric Acid 98.08
When concentrated Sulfuric Acid and water are mixed, a tremendous amount of heat is released due to ionization of the acid. For instance, adding 1 volume of concentrated Sulfuric Acid to an equal volume of water (both at 25°C) results in a temperature rise to over 135°C. Therefore, the acid should always be diluted by adding it to the water. If the water is added to the acid, spattering could result which creates a hazardous situation and the possibility for severe chemical burns. The use of a 1 + 1 dilution of Sulfuric Acid with water (50% Sulfuric Acid, Group No. 8180) offers a much safer alternative in many instances when the use of Sulfuric Acid is required. For example, when 1 volume of concentrated Sulfuric Acid is added to 3 volumes of water, the temperature rises from 25°C to over 90°C. When the same solution is made by diluting 1 volume of 50% Sulfuric Acid with 1 volume of water, the temperature rises to less than 50°C.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Sulfuric Acid 98% |
| Part Number | RXSOL-19-1104-060 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai, Chennai, Vizag, Kolkata, UAE, Oman
| Phone | +91 22 27815540 / 41 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmarine.com |
| Name of Substance | Cas Number | EC Number |
| Sulfuric Acid | 7664-93-9 | 231-693-5 |
| Hazard Pictogram | |
| Signal Word | Danger |
| Hazard Statements |
Causes severe skin burns and eye damage May cause respiratory irritation Fatal if inhaled May cause cancer |
| Prevention |
Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wear respiratory protection Wash face, hands and any exposed skin thoroughly after handling |
| Response | Immediately call a POISON CENTER or doctor/physician. |
| Hazards not otherwise classified (HNOC) | Reacts violently with water. |
| Eye Contact | Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. |
| Skin Contact | Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. |
| Inhalation | Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. |
| Ingestion | Do not induce vomiting. Call a physician or Poison Control Center immediately. |
| Most important symptoms and effects, both acute and delayed | Causes burns by all exposure routes. . Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation. |
| Notes to Physician | Treat symptomatically |
| Suitable Extinguishing Media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable Extinguishing Media | For this substance/mixture no limitations of extinguishing agents are given. DO NOT USE WATER |
| Flash Point | No information available |
| Specific Hazards Arising from the Chemical |
Not combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: Sulphur oxides |
| Advice for firefighters |
Special protective equipment for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information | Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. |
| Environmental precautions | Should not be released into the environment. Prevent product from entering drains. Keep out of waterways. See Section 12 for additional ecological information. |
| Methods and materials for containment and cleaning up | Use personal protective equipment. Provide adequate ventilation. Neutralize with lime milk or soda and flush with plenty of water. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Keep from any possible contact with water, because of violent reaction and possible flash fire. Do not flush into surface water or sanitary sewer system. |
| Handling | Use only under a chemical fume hood. Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Do not breathe vapors or spray mist. Do not ingest. Do not allow contact with water because of violent reaction. Handle under inert gas, protect from moisture. |
| Storage | Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Non-combustible, corrosive hazardous materials |
| Engineering Measures |
Use only under a chemical fume hood. Ensure that eyewash stations and safety showers are close to the workstation location. |
| Personal Protective Equipment |
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Eye/face protection :
Skin protection : |
| Body Protection |
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. |
| Respiratory Protection | Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU) |
| Hygiene Measures | Handle in accordance with good industrial hygiene and safety practice. |
Gloves Suit
| Physical State | Liquid |
| Colour | Colourless |
| Odour | Odourless |
| Odor Threshold | Not Applicable |
| pH | 0.3 at 49 g/l 25 °C |
| Melting Point | -20 °C |
| Initial boiling point / Range | 335 °C at 1,013 hPa |
| Flash point | No information available |
| Evapouration rate | No information available |
| Flammability (solid, gas) | No information available |
| Upper/lower explosive limits | No data available |
| Vapour pressure | ca.0.0001 hPa at 20 °C |
| Vapour density | 3.4 (Air = 1.0) |
| Specific Gravity | 1.84 g/cm3 at 20 °C |
| Relative Density | No Information Available |
| Water Solubility | Soluble, (caution ! development of heat) |
| Partition coefficient | n-octanol/water No data available |
| Auto-ignition | No information available |
| Decomposition | No information available |
| Viscosity,Dynamic | ca.24 mPa.s at 20 °C |
| Molecular Formula | Formula H₂SO₄ |
| Molecular Weight | 98,08 g/mol |
| Reactive Hazard | Yes strong oxidising agent |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions |
A risk of explosion and/or of toxic gas formation exists with the following substances: Violent reactions possible with: Water, Alkali metals, alkali compounds, Ammonia, Aldehydes, acetonitrile, Alkaline earth metals, alkalines, Acids, alkaline earth compounds, Metals, metal alloys, Oxides of phosphorus, phosphorus, hydrides, halogen-halogen compounds, oxyhalogenic compounds, permanganates, nitrates, carbides, combustible substances, organic solvent, acetylidene, Nitriles, organic nitro compounds, anilines, Peroxides, picrates, nitrides, lithium silicide, iron(III) compounds, bromates, chlorates, Amines, perchlorates, hydrogen peroxide |
| Incompatible Materials | Bases, Strong oxidizing agents, Ammonia, Combustible material, Metals, Reducing agents |
| Conditions to avoid | No information available |
| Toxicologically | No information available |
| Irritation | Causes burns by all exposure routes |
| Sensitization | No information available |
| Carcinogenicity | The table below indicates whether each agency has listed any ingredient as a carcinogen. Exposure to strong inorganic mists containing sulfuric acid may cause cancer by inhalation. |
| Mutagenic Effects | No information available |
| Reproductive Effects | No information available |
| Developmental Effects | No information available |
| Teratogenicity | No information available |
| STOT - single exposure | Respiratory system |
| STOT - repeated exposure | None known |
| Aspiration hazard | No information available |
| Symptoms / effects,both acute and delayed | Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation. |
| Endocrine Disruptor Information | No information available |
| Other AdverseEffects |
See actual entry in RTECS for complete information.
|
| Further information | After inhalation of aerosols: damage to the affected mucous membranes. After skin contact: severe burns with formation of scabs. After eye contact: burns, corneal lesions. After swallowing: severe pain (risk of perforation!), nausea, vomiting and diarrhoea. After a latency period of several weeks possibly pyloric stenosis. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. |
.
| Toxicity | No information available. |
| Bioaccumulation/ Accumulation | No information available. |
| Persistence and degradability | No information available |
| Mobility in Soil | No information available |
| Results of PBT and vPvB assessment | No information available |
|
Other adverse effects Additional ecological information |
Biological effects: Forms corrosive mixtures with water even if diluted. Harmful effect due to pH shift. Endangers drinking-water supplies if allowed to enter soil or water. Discharge into the environment must be avoided. |
| Waste treatment methods | Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. |
DOT / ADR
| UN Number | UN 1830 |
| Proper shipping name | SULFURIC ACID, |
| Class | 8 |
| Packing Group | II |
| Environmentally hazardous | --- |
| Special precautions for user | yes |
TDG / IMDG / IMO
| UN Number | UN 1830 |
| Proper shipping name | SULFURIC ACID, |
| Class | 8 |
| Packing Group | II |
| Environmentally hazardous | --- |
| Special precautions for user | yes |
| Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code | Not relevant |
IATA
| UN Number | UN 1830 |
| Proper shipping name | SULFURIC ACID, |
| Class | 8 |
| Packing Group | II |
| Environmentally hazardous | --- |
| Special precautions for user | yes |
|
TSCA 12(b)Notices of Export |
This safety datasheet complies with the requirements of Regulation (EC) No. 190 7/2006. |
| SARA 313 | Not applicable |
| SARA 311/312 | Hazard Categories See section 3 for more information |
| CWA (Clean Water Act) | Not applicable |
| Clean Air Act | Not applicable |
| OSHA | Occupational Safety and Health Administration |
| Chemical Safety Assesment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
Availability
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