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Product Name |
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Product Type |
ETHYLAMINE SOLUTION 70% |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substances : ETHYLAMINE SOLUTION
CAS-No. : 75-04-7
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, H225
Category 2
Skin corrosion/irritation, H314
Category 1A
Specific target organ toxicity — Single exposure, H335
Category 3,
Respiratory tract irritation
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : Xi : Irritation.
Highly flammable
C: Corrosive
R Phrase(s) : R11: Highly flammable.
R35: Cause severe burns.
R37: Irritating to respiratory system.
Hazard pictograms
Signal word: Danger
Hazard statements : H225 - Highly flammable liquid and vapour.
H314 - Causes severe skin burns and eye damage.
H335 - May cause respiratory irritation.
Precautionary statements (CLP) : P210 - Keep away from open flames, sparks. No
smoking.
P261 - Avoid breathing dust, fume, gas, spray, vapours.
P280 - Wear protective gloves, protective clothing, face protection, eye protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER/doctor
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If
you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER/doctor. Call a POISON
CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Take off
immediately all contaminated clothing. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately
call a POISON CENTER/doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after inhalation : May cause respiratory irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers.
Exercise caution when fighting any chemical fire. Prevent fire fighting water from
entering the environment.
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric
charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual
vapours are flammable.
Precautions for safe handling : Provide good ventilation in process area to prevent
formation of vapour.Avoid contact with skin and eyes. Use only non-sparking tools. Do
not breathe vapours.
Avoid contact during pregnancy/while nursing. Keep away from sources of ignition -
No smoking. Use only outdoors or in a well-ventilated area.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be
followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions : Keep in fireproof place. Keep container tightly closed.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
Other information : Do not eat, drink or smoke during use.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : > 14 at 20 °C
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -74 °C
Freezing point : No data available
Boiling point : 38 °C
Flash point : -26 °C
Auto-ignition temperature : 375 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Highly flammable liquid and vapour.
Vapour pressure : 50 mm Hg at 20° C
Relative vapour density at 20 °C : 1.56
Relative density : 0.796
Density : 0.8 g/cm³
Solubility : Water: Soluble
Log Pow : -0.27
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.03 - 0.128 vol %
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Sparks. Heat. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide. May release flammable gases.
11.1. Information on toxicological effects
Acute toxicity: Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: > 14 at 20 °C
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: > 14 at 20 °C
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Reproductive toxicity : Not classified
Additional information : Based on available data, the classification criteria are not met
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Additional information : Based on available data, the classification criteria are not met
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential adverse human health effects and symptoms : Based on available data, the
classification criteria are not met.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Log Pow -0.27
Bioaccumulative potential
Not established.
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
Additional information : Avoid release to the environment.
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose in a safe manner in accordance with local/national
regulations. Dispose of contents/container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are
flammable.
Ecology - waste materials : Avoid release to the environment.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2270
UN-No. (IMDG) : 2270
UN-No. (IATA) : 2270
UN-No. (ADN) : 2270
UN-No. (RID) : 2270
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ETHYLAMINE, AQUEOUS SOLUTION
Proper Shipping Name (IMDG) : ETHYLAMINE, AQUEOUS SOLUTION
Proper Shipping Name (IATA) : Ethylamine, aqueous solution
Proper Shipping Name (ADN) : ETHYLAMINE, AQUEOUS SOLUTION
Proper Shipping Name (RID) : ETHYLAMINE, AQUEOUS SOLUTION
Transport document description (ADR) : UN 2270 ETHYLAMINE, AQUEOUS
SOLUTION, 3 (8), II, (D/E)
Transport document description (IMDG) : UN 2270 ETHYLAMINE, AQUEOUS
SOLUTION, 3 (8), II
Transport document description (IATA) : UN 2270 Ethylamine, aqueous solution, 3 (8),
II
Transport document description (ADN) : UN 2270 ETHYLAMINE, AQUEOUS
SOLUTION, 3 (8), II
Transport document description (RID) : UN 2270 ETHYLAMINE, AQUEOUS
SOLUTION, 3 (8), II
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 3 (8)
Danger labels (ADR) : 3, 8
IMDG - Transport hazard class(es) (IMDG) : 3 (8)
Danger labels (IMDG) : 3, 8
IATA- Transport hazard class(es) (IATA) : 3 (8)
Hazard labels (IATA) : 3, 8
ADN- Transport hazard class(es) (ADN) : 3 (8)
Danger labels (ADN) : 3, 8
RID- Transport hazard class(es) (RID) : 3 (8)
Danger labels (RID) : 3, 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : FC
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions (ADR) : T7
Portable tank and bulk container special provisions (ADR) : TP1
Tank code (ADR) : L4BH
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage – Operation (ADR) : S2, S20
Hazard identification number (Kemler No.) : 338
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2PE
APP code : A(fl)
Transport by sea- Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Segregation (IMDG) : SG35
MFAG-No : 132
Air transport- PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y340
PCA limited quantity max net quantity (IATA) : 0.5L
PCA packing instructions (IATA) : 352
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 363
CAO max net quantity (IATA) : 5L
ERG code (IATA) : 3CH
Inland waterway transport- Classification code (ADN) : FC
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
Rail transport- Classification code (RID) : FC
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions (RID) : T7
Portable tank and bulk container special provisions (RID) : TP1
Tank codes for RID tanks (RID) : L4BH
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE7
Hazard identification number (RID) : 338
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
ETHYLAMINE SOLUTION is not on the REACH Candidate List
ETHYLAMINE SOLUTION is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification
according to AwSV; ID No. 97)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen –
Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Classification remarks : Emergency management guidelines for the storage of flammable
liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.