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Product Name |
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Product Type |
BLEACHING POWDER |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substances : BLEACHING POWDER
CAS-No. : 7778-54-3
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Acute toxicity (oral), H302
Category 4
Skin corrosion/irritation, H314
Category 1B
Hazardous to the aquatic
environment — Acute
Hazard, H400
Category 1
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : N : Dangerous for the environment
O : Oxidizing
C: Corrosive
R Phrase(s) : R8: Contact with combustible material may cause fire.
R22: Harmful if swallowed.
R31: Contact with acids librates toxic gas.
R34: Cause burns.
R50: Very toxic to aquatic organisms.
S Phrase(s) : S26: In the case of contact with eyes, rinse immediately with plenty of
water and seek medical advise.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
S61: avoid release to the environment . refer to special instruction/safety data sheets.
S36/37/39 : Wear suitable protective clothing and gloves & eye/face protecting.
Hazard pictograms :
Signal word : Danger
Hazard statements : H272 - May intensify fire; oxidiser.
H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H400 - Very toxic to aquatic life.
Precautionary statements (CLP) : P220 - Keep/Store away from clothing and other
combustible materials.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection,
face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact : Rinse immediately contaminated clothing and skin
with plenty of water before removing clothes. Take off immediately all contaminated
clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately
call a POISON CENTER/doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May intensify fire; oxidiser.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire
and increasing risk of burns and injuries.
5.3. Advice for firefighters
Firefighting instructions : In case of major fire and large quantities: Evacuate area. Fight
fire remotely due to the risk of explosion.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Soak
up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Additional hazards when processed : Hazardous waste due to potential risk of explosion.
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours.
Take precautionary measures against static discharge.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash
contaminated clothing before reuse. Wash hands and other exposed areas with mild soap
and water before eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be
followed. Comply with applicable regulations.
Storage conditions : Keep in fireproof place. Store in a well-ventilated place.
Incompatible materials : Heat sources. combustible materials.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Personal protective equipment : Wear fire/flame resistant/retardant clothing.
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 100 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 2.35 g/cm³
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : May cause fire or explosion; strong oxidiser.
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Highly reactive material. Contact with acids liberates toxic gas.
10.4. Conditions to avoid
Heat. Sparks. Open flame.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed
12.1. Toxicity
Ecology - water : Very toxic to aquatic life.
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation.
Additional information : Hazardous waste due to potential risk of explosion
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1748
UN-No. (IMDG) : 1748
UN-No. (IATA) : 1748
UN-No. (ADN) : 1748
UN-No. (RID) : 1748
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CALCIUM HYPOCHLORITE, DRY
Proper Shipping Name (IMDG) : CALCIUM HYPOCHLORITE, DRY
Proper Shipping Name (IATA) : Calcium hypochlorite, dry
Proper Shipping Name (ADN) : CALCIUM HYPOCHLORITE, DRY
Proper Shipping Name (RID) : CALCIUM HYPOCHLORITE, DRY
Transport document description (ADR) : UN 1748 CALCIUM HYPOCHLORITE, DRY,
5.1, II, (E), ENVIRONMENTALLY
HAZARDOUS
Transport document description (IMDG) : UN 1748 CALCIUM HYPOCHLORITE
, DRY, 5.1, II, MARINE
POLLUTANT/ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 1748 Calcium hypochlorite, dry, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1748 CALCIUM HYPOCHLORITE, DRY,
5.1, II, ENVIRONMENTALLY
HAZARDOUS
Transport document description (RID) : UN 1748 CALCIUM HYPOCHLORITE, DRY,
5.1, II, ENVIRONMENTALLY
HAZARDOUS
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 5.1
Danger labels (ADR) : 5.1
IMDG- Transport hazard class(es) (IMDG) : 5.1
Danger labels (IMDG) : 5.1
IATA- Transport hazard class(es) (IATA) : 5.1
Hazard labels (IATA) : 5.1
ADN- Transport hazard class(es) (ADN) : 5.1
Danger labels (ADN) : 5.1
RID- Transport hazard class(es) (RID) : 5.1
Danger labels (RID) : 5.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : O2
Special provisions (ADR) : 314
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4, B13
Mixed packing provisions (ADR) : MP10
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage – Packages (ADR) : V11
Special provisions for carriage - Loading
, unloading and handling (ADR) : CV24, CV35
Hazard identification number (Kemler No.) : 50
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 1W
Transport by sea- Special provisions (IMDG) : 314
Packing instructions (IMDG) : P002
Special packing provisions (IMDG) : PP85
EmS-No. (Fire) : F-H
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : D
Stowage and handling (IMDG) : SW1, SW11
Segregation (IMDG) : SG35, SG38, SG49, SG53, SG60
Properties and observations (IMDG) : White or yellowish solid (powder, granules or
tablets) with chlorine-like odour.
Soluble in water. May cause fire in contact with organic material or ammonium
compounds. Substances are liable to exothermic decomposition at elevated
temperatures. This condition may lead to fire or explosion. Decomposition can be
initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt,
magnesium) and their compounds). Liable to heat slowly. Reacts with acids,
evolving chlorine, an irritating, corrosive and toxic gas. In the presence of moisture,
corrosive to most metals. Dust irritates mucous membranes.
MFAG-No : 140
Air transport- PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y544
PCA limited quantity
max net quantity (IATA) : 2.5kg
PCA packing instructions (IATA) : 558
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 562
CAO max net quantity (IATA) : 25kg
Special provisions (IATA) : A136, A803
ERG code (IATA) : 5L
Inland waterway transport- Classification code (ADN) : O2
Special provisions (ADN) : 314
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
Rail transport -Classification code (RID) : O2
Special provisions (RID) : 314
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4, B13
Mixed packing provisions (RID) : MP10
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 2
Special provisions for carriage – Packages (RID) : W11
Special provisions for carriage - Loading,
unloading and handling (RID) : CW24, CW35
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 50
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
BLEACHING POWDER is not on the REACH Candidate List
BLEACHING POWDER is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water
(Classification according to AwSV; ID No. 2062)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen –
Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.