Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance.
Substance name Contents CAS No
Magnesium powder (pyrophoric) : 100 % 7439-95-4
Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
in contact with water, emit flammable gases - Category 1 - Danger (CLP : Water-react. 1) H260
Pyrophoric solids - Category 1 - Danger (CLP : Pyr. Sol. 1) H250
3.2. Label elements
R Phrase(s) : R15 : Contact with water liberates highly flammable gases.
R17 : Spontaneously flammable in air.
S Phrase(s) : S2 : Keep out of the reach of children.
S7/8 : Keep container tightly closed and dry.
S43 : In case of fire, use .
Hazard statements : H250 : Catches fire spontaneously if exposed to air.
H260 : In contact with water releases flammable gases which may ignite spontaneously.
• General : P102: Keep out of reach of children. P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
because of violent reaction and possible flash fire.
P222: Do not allow contact with air.
P231+P232: Handle under inert gas. Protect from moisture.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
• Response : P335+P334: Brush off loose particles from skin. Immerse in cool water, wrap in wet bandages.
P370+P378: In case of fire: Use for extinction.
• Storage : P422: Store contents under inert gas. (See information supplied by the manufacturer)
P402+P404: Store in a dry place. Store in a closed container.
• Disposal considerations : P501: Dispose of this material and its container to
hazardous or special waste collection point, in accordance with local, regional
, national and/or international regulation.
2.3. Other hazards Other hazards : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest.
skin area with mild soap and water, followed by warm water rinse.
Immerse in cool water, wrap in wet bandages. Brush off loose particles from skin.
Eye contact : Rinse immediately with plenty of water.
Obtain medical attention if pain, blinking or redness persist.
Ingestion : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
anticipated conditions of normal use. Not expected to present a significant hazard
under anticipated conditions of normal use.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Flammable solid.
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection. Special procedures : Exercise caution when fighting
any chemical fire. Avoid (reject) fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area.
Special precautions : Catches fire spontaneously if exposed to air. Do not allow contact with air.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters.
Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : On land, sweep or shovel into suitable containers.
Minimize generation of dust. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash hands and other exposed areas with mild soap
and water before eat, drink or smoke and when leaving work.
Handle empty containers with care because residual vapours are flammable.
Handle under inert gas. Protect from moisture. Do not allow contact with air.
Keep away from any possible contact with water, because of violent reaction a
nd possible flash fire.
Technical protective measures : Provide good ventilation in process area to prevent formation of vapour.
Special precautions : No naked lights. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place.
Keep container closed when not in use. Store contents under inert gas
. (See information supplied by the manufacturer) Protect from moisture.
Keep away from any possible contact with water, because of violent reaction
and possible flash fire. Storage - away from : Strong bases. Strong acids. Sources
of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : Not applicable.
Melting point [°C] : 648 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 4730C
Flammability (solid, gas) : Catches fire spontaneously if exposed to air. N/A
Flash point [°C] : N/A
Boiling point [°C] : 11000C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : N/A
Vapour density : N/A
Density [g/cm3] : 1,74
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Insoluble in water
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under
recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : In contact with water
releases flammable gases which may ignite spontaneously.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight.
Extremely high or low temperatures. Open flame.
Overheating. Heat. Sparks. Do not allow contact with air.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes.
Carbon monoxide. Carbon dioxide.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance
does not fulfil the criteria to be identified as PBT substance
or vPvB substance according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment.
Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material
and its container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international
regulation. Special precautions : Handle empty containers with care
because residual vapours are flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : MAGNESIUM or MAGNESIUM ALLOYS with more than
50% magnesium in pellets, turnings or ribbons
UN N° : 1869
H.I. nr : 40
ADR - Class : 4.1
Labelling - Transport : 4.1 : Flammable solids,
self-reactive substances and desensitized explosives.
ADR - Classification code : F3
ADR - Group : III
ADR - Packing instructions : P002 R001 LP002
ADR - Limited Quantity : 5 KG
ADR - Tunnel code: E : Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : MAGNESIUM or MAGNESIUM
ALLOYS with more than 50% magnesium in pellets, turnings or ribbons
UN N° : 1869
IMO-IMDG - Class or division : 4.1 : Flammable solids,
self-reactive substances and desensitized explosives.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P002 LP02
IMO-IMDG - Limited quantities : 5 kg
IMO-IMDG - Marine pollution : No
EMS-Nr : F-G S-G
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : MAGNESIUM or MAGNESIUM ALLOYS
with more than 50% magnesium in pellets, turnings or ribbons
UN N° : 1869
IATA - Class or division : 4.1 : Flammable solids,
self-reactive substances and desensitized explosives.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED -
Passenger and Cargo -
Packing : 446
instruction - Passenger and
Cargo - Maximum : 25 kg
Quantity/Packing
IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 449 -
Cargo only - Maximum Quantity/ : 100 kg
Packing IATA - Limited Quantites : 10 kg
ERG-Nr : 3L
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.