MUCIC ACID Galactaric acid
- Part number
- RXSOL-60-6605-016
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Mucic acid can be used to replace tartaric acid in self-rising flour or fizzies. It has been used as a precursor of adipic acid in the way to nylon by a rhenium-catalyzed deoxydehydration reaction. It has been used as a precursor of Taxol in Nicolaou Taxol total synthesis (1994).
Applications
Mucic acid test is a test that is highly specific and is used for the detection of the presence of galactose and lactose. It is also termed galactaric acid that is named after the product of the reaction.
Characteristics and notes
Sugar acids obtained by aldohexose oxidation of both the terminal aldehyde group and the hydroxy group at the other end to carboxyl groups are called hexaric acids (i.e., six-carbon aldaric acids). Because hexaric acids have four secondary hydroxy groups that are stereochemically diverse and two carboxyl groups, various applications of these acids have been studied. Conventionally, hexaric acids have been produced mainly by nitric acid oxidation of aldohexose, but full-scale commercialization has not been realized; there are many problems regarding yield, safety, environmental burden, etc.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Mucic acid GALACTARIC ACID |
| Part Number | RXSOL-60-6605-016 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 2087 1500:::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmarine.com |
| Chemical Name | CAS-No | EC NO. | Weight % |
| Mocic acid | 526-99-8 | 208-404-0 | 98 |
| Hazard Statements |
None identified |
| P280 Wear protective gloves.P305 + P351 + P338 | Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Precautionary statements - response |
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,bioaccumulative and bioaccumulative and toxic (PBT),or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Lachrymator.
SECTION 3: Composition/information on ingredients
3.1 Substances
Synonyms : n-Amyl alcohol
Pentyl alcohol
|
| General advice | Consult a physician. Show this safety data sheet to the doctor in attendance. | |
| If inhaled | If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. | |
| Eye Contact | Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. | |
| Skin Contact | Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes | |
| Inhalation | Remove from exposure, lie down. Remove to fresh air. | |
| Ingestion | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. If possible drink milk afterwards | |
| Notes to Physician | Treat symptomatically | |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. | |
| Most important symptoms and effects, both acute and delaye | No information available. | |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Suitable Extinguishing Media | Water spray. Carbon dioxide (CO 2). Dry chemical. Alcohol resistant foam. |
| Flammability | May be combustible at high temperature. |
| Flash Point | No information available. |
| Suitable extinguishing media | Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture | Keep product and empty container away from heat and sources of ignition |
| Further information | Use water spray to cool unopened containers.. |
|
Hazardous combustion products |
Thermal decomposition can lead to release of irritating gases and vapors. Carbon monoxide (CO). Carbon dioxide (CO2). |
| Advice for firefighters | Wear self-contained breathing apparatus for firefighting if necessary. |
| Protective Equipment |
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. |
| Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Ensure adequate ventilation. Use personal protective equipment as required |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | See Section 12 for additional Ecological Information. |
|
Methods and materials for containment and cleaning |
Sweep up and shovel into suitable containers for disposal. |
| Advice on safe handling | Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.For precautions see section 2.2. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions |
| Precautions for safe handling | Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam. |
| Conditions for safe storage, including any incompatibilities | Store in cool place. Keep container tightly closed in opened must be carefully resealed and kept upright to Storage class (TRGS 510): Flammable liquids. |
| Storage conditions | Tightly closed. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Light sensitive. Moisture sensitive. |
| Storage conditions | Keep in a dry, cool and well-ventilated place. Refer product specification and/or product label for specific storage temperature requirement. Keep container tightly closed |
| Storage class | Storage class (TRGS 510): 13: Non Combustible Solids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling |
Avoid contact with skin and eyes. Avoid contact with skin and clothing. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Avoid breathing vapors or mists. Do not ingest. If swallowed then seek immediate medical assistance. Wash thoroughly after handling |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Occupational Exposure limit values | This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. |
| Biological limit values | No data available |
| Exposure controls | Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the riskelimination area |
| Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday
at the end of workday.
Page
|
| Eye/face protection | Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. |
| Body Protection |
Wear appropriate protective gloves and clothing to prevent skin exposure.
type of protective equipment must be selected
type of protective equipment must be selected according to the concentration and amount of the
|
| Skin protection |
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices Wash and dry hands
contaminated gloves after use in accordance with applicable laws and good laboratory
|
| Respiratory protection | No protective equipment is needed under normal use conditions. |
| Other Protection Measure | None under normal use conditions |
| Contro of environmental exposure | Prevent further leakage or spillage if safe to do so. Do not let product enter drains |
| Hygiene Measures | Handle in accordance with good industrial hygiene and safety practice. |
| Thermal hazards | No data available |
Gloves Suit
| Physical state | Powder Solid |
| Appearance | Beige |
| Colour | Colourless |
| Odour | Odorless |
| Odor Threshold | No data available |
| pH | No information available |
| Melting Point | 230 °C / 446 °F |
| Initial boiling point and boiling range | No information available |
| Boiling Point | No data available |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No Data Available |
| Density | No data available |
| Vapour Density | No Data Available |
| Specific Gravity | No data available |
|
Upper/lower flammability or explosive limits |
Upper explosion limit: 10 %(V) Lower explosion limit: 1.2 %(V) |
| Vapour density | 3.04 - (Air = 1.0) |
| Vapour pressure | 1.5 mmHg at 20 °C |
| Partition coefficient | No data available |
| Auto-ignition emperature | 300 °C |
| Explosive properties | None |
| Solubility | DMSO (Slightly), Water (Slightly) |
| Ignition temperature | No information available. |
| Molecular Weight | 210.14 |
| Molecular Formula | C6 H10 O8 |
| Particle characteristics | No data available |
| Reactivity | None known, based on information available |
| Stability | Stable under normal conditions. |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | Incompatible products |
| Incompatible materials | Strong oxidizing agents, Alkali metals, Strong acids, Halides, Aldehydes |
| Hazardous Polymerization | Hazardous decomposition products formed under fire conditions - Carbon oxides In the event of fire: see section 5 |
| Acute toxicity | No acute toxicity information is available for this product |
| Skin corrosion/irritation | Skin - Rabbit(Pentan-1-ol)Result: Skin irritation - 24 h |
| Serious eye damage/eye irritation |
Eyes - In vitro study(Pentan-1-ol) Result: Irritating to eyes. |
| Carcinogenicity | The table below indicates whether each agency has listed any ingredient as a carcinogen. |
| Respiratory or skin sensitization | Did not cause sensitisation on laboratory animals.(Pentan-1-ol) |
| Serious eye damage/eye irritation | No data available |
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat]. |
| Toxic Effects on Human | May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
| Germ cell mutagenicity | Ames test(Pentan-1-ol) Salmonella typhimurium Result: negative |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans: |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Additional Information | Endocrine disrupting properties |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: OD2800000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. |
| Endocrine disrupting properties | No information available |
| Persistence and degradability | Soluble in water Persistence is unlikely based on information available |
| Toxicity | Toxicity to fish: no data available Toxicity to daphnia and other aquatic invertebrates: no data available Toxicity to algae: no data available Toxicity to microorganisms: no data available |
| Bioaccumulative potential | No information available |
| Toxicity to fish | static test LC50 - Danio rerio (zebra fish) - 530 mg/l - 96 h(Pentan-1-ol) |
| Toxicity to daphnia and other aquatic invertebrates | static test EC50 - Daphnia magna (Water flea) - 341.21 mg/l - 48 h(Pentan-1-ol) |
| Toxicity to algae | static test ErC50 - SELENASTRUM - > 998 mg/l - 72 h (OECD Test Guideline 201) |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: |
Aerobic - Exposure time 28 d(Pentan-1-ol) Result: 80 - 90 % - Readily biodegradable |
| Mobility in soil | Will likely be mobile in the environment due to its water solubility |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available |
| Waste Disposal Methods |
Chemical waste generators must determine whether a discarded chemical is classified as aChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and.
|
| DOT | Not regulated |
| TDG | Not regulated |
| IATA | Not regulated |
| MDG/IMO | Not regulated |
| SARA 313 | Not applicable |
| SARA 311/312 Hazard Categories | See section 2 for more information |
| CWA (Clean Water Act) | Not applicable |
| Clean Air Act | Not applicable |
| OSHA - Occupational Safety and Health Administration | Not applicable |
| CERCLA | Not applicable |
| California Proposition 65 | This product does not contain any Proposition 65 chemicals. |
| U.S. State Right-to-Know Regulations | Not applicable |
| Reportable Quantity (RQ): | Not applicable |
| DOT Marine Pollutant | Not applicable |
| DOT Severe Marine Pollutant | Not applicable |
| U.S. Department of Homeland Security | This product does not contain any DHS chemicals |
| Mexico - Grade | No information available |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |