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Product Name |
Benzyl Chloride |
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Part Number |
RXSOL-19-1239-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.comA |
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Chemical Name |
CAS |
EC number |
Weight |
Formula |
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Benzyl chloride |
100-44-7 |
202-853-6 |
<= 100 % |
C7H7Cl |
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Signal Word |
Danger |
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Hazard Statements |
H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H373 May cause damage to organs (Heart, forestomach) through prolonged or repeated exposure if swallowed. |
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Precautionary statements |
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None. |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachrymator. |
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General advice |
First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
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Flash Point |
Dry powder Dry sand |
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Suitable extinguishing media |
Water Foam Carbon dioxide (CO2) Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Carbon oxides Hydrogen chloride gas Mixture with combustible ingredients. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. |
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Further information |
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
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Precautions for safe handling |
For precautions see section 2.2. |
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Storage conditions |
Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Light sensitive. Moisture sensitive. |
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Storage class |
Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
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Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Control parameters |
Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
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Body Protection |
Protective clothing |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 30 min Material tested:KCL 720 Camapren® |
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Respiratory protection |
Recommended Filter type: Respirator. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. |
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Physical state |
Liquid |
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Colour |
Colorless |
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Odour |
Stinging |
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Odor Threshold |
No data available |
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pH |
No data available |
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Melting Point |
43 °C - lit. |
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Boiling Point |
177 - 181 °C - lit. |
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Flash Point |
67 °C - c.c. |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
14 %(V) / 1,1 %(V) |
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Autoignition temperature |
585 °C at 1.013 hPa |
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Decomposition temperature |
No data available |
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Vapour pressure |
1,6 hPa at 25 °C |
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Density |
1,1 g/cm3 at 25 °C - lit |
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Relative Density |
1,1 at 20 °C |
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Relative vapor density |
4,36 |
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Freezing point |
No data available |
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Viscosity dynamic |
1,380 mPa.s at 20 °C |
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Partition coefficient |
log Pow: 2,3 |
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Explosive properties |
No data available |
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Solubility |
0,46 g/l at 30 °C |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): propylene oxide (<1 %) |
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Possibility of hazardous reactions |
Violent reactions possible with: Strong oxidizing agents amides substances with a catalytic effect numerous inorganic and/or organic compounds Risk of explosion with: polymerisation initiators Acids A risk of explosion and/or of toxic gas formation exists with the following substances: Alkali metals Alkaline earth metals Metals Exothermic reaction with: Water Release of: Hydrogen chloride gas |
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Conditions to avoid |
Strong heating. |
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Incompatible materials |
Various plastics, Strong oxidizing agents |
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
Acute toxicity estimate Oral - 1.192,37 mg/kg (Calculation method) Acute toxicity estimate Oral - 560 mg/kg (Calculation method) LD50 Oral - Rat - male and female - 560 mg/kg (OECD Test Guideline 401) Symptoms: Possible damages:, Bloody vomiting Acute toxicity estimate Inhalation - 0,74 mg/l(Calculation method) Acute toxicity estimate Inhalation - 4 h - 4,98 mg/l - vapor(Calculation method) Acute toxicity estimate Inhalation - 4 h - 5 mg/l - vapor (Expert judgment) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Symptoms: Cough, Shortness of breath, mucosal irritations, Possible damages:, damage of respiratory tract, Lung edema, Symptoms may be delayed. Acute toxicity estimate Dermal - 124.400 mg/kg (Calculation method) Acute toxicity estimate Dermal - > 2.000 mg/kg (Calculation method) |
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Skin corrosion/irritation |
Remarks: Causes skin irritation. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
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Serious eye damage/eye irritation |
Remarks: Lacrimal irritation due to vapours. Remarks: Causes serious eye damage. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
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Respiratory or skin sensitization |
Local lymph node assay (LLNA) - Mouse Result: positive (OECD Test Guideline 429) |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
No data available |
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Germ cell mutagenicity |
Local lymph node assay (LLNA) - Mouse Result: positive (OECD Test Guideline 429) |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
Inhalation - May cause respiratory irritation. - Respiratory system Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: XS8925000 burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Systemic effects: Unconsciousness CNS disorders Damage to: Kidney Liver Other dangerous properties can not be excluded. This substance should be handled with particular care. Liver - Irregularities - Based on Human Evidence. |
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Bioaccumulative potential |
No data available |
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Persistence and degradability |
Biodegradability aerobic - Exposure time 14 d Result: 71 % - Readily biodegradable. (OECD Test Guideline 301C) |
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Toxicity to fish |
Static test LC50 - Danio rerio (zebra fish) - 4 mg/l - 96 h (OECD Test Guideline 203) |
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Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia magna (Water flea) - 6,1 mg/l - 48 h (OECD Test Guideline 202) |
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Toxicity to algae |
Flow-through test NOEC - algae - 0,002 mg/l - 7 Days Remarks: (in analogy to similar products) (ECHA) The value is given in analogy to the following substances: sodium hypochlorite solution |
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Toxicity to bacteria |
Static test EC50 - activated sludge - 563 mg/l - 3 h (OECD Test Guideline 209) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: sodium hypochlorite solution |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
Discharge into the environment must be avoided. Stability in water Test substance: Water Remarks: Rapid degradation. |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID: 1738 IMDG: 1738 IATA: 1738 |
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UN proper shipping name |
ADR/RID: BENZYL CHLORIDE IMDG:BENZYL CHLORIDE IATA:BENZYL CHLORIDE |
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Transport hazard class(es) |
ADR/RID: 6.1 (8) IMDG: 6.1 (8) IATA: 6.1 (8) |
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Packaging group |
ADR/RID: II IMDG: II IATA: II |
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Environmental hazards |
ADR/RID: NO IMDG: NO IATA: NO |
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Further information |
No data available |
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Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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Authorisations and/or restrictions on use |
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : propylene oxide REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles (Annex XVII) : Benzyl chloride propylene oxide |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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