KARL FISCHER REAGENT Pyridine Free

Product Code: RXSOL-60-6604-769

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Product Short Description: KARL FISCHER REAGENT Pyridine Free
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Karl Fischer titration is simply a method for quantifying water content of samples. The fundamental principle behind this reaction is based on the Bunsen reaction between compounds such as iodine, sulphur dioxide to form sulphuric acid and hydrogen iodide. Karl Fischer initiated a new method based on Bunsen’s reaction. He discovered that the reaction could be modified for determining water in a non-aqueous system containing an excess of sulphur dioxide in the presence of a suitable base. He used a primary alcohol (methanol) as the solvent and a base (pyridine) as the buffering agent.
 
What is the Karl Fischer Reaction?
(1) CH3OH + SO2 + RN [RNH]SO3CH3
 
Reaction-1:  is where the alcohol reacts with sulphur dioxide (SO2) and base to form an intermediate alkylsulfite salt
 
(2) H2O + I2 + [RNH]SO3CH3 + 2RN [RNH]SO4CH3 + 2[RNH]I
 
Reaction-2: is the oxidation step where the intermediate is then oxidised to an alkylsulphate salt. This reaction consumes water.

Water and iodine are consumed in a 1:1 ratio. Once all of the water present is consumed, the presence of excess iodine is detected by the indicator electrode. That signals the end-point of the titration. The amount of water present in the sample is calculated based on the concentration of iodine in the Karl Fisher titrating reagent and the amount of Karl Fisher Reagent consumed in the titration. Depending on the type of base used the rate of reaction will vary. Classic Karl Fischer reagents contained pyridine, a noxious carcinogen, as the base. Due to its weak basicity the reaction is slow and the end point is not stable. The most common base used today is imidazole where greatest accuracy and repeatability can be achieved. Coulometry is an absolute technique so standardisation of Karl Fischer reagents is not necessary.
 
 
Coulometric Titration Method
In coulometric Karl Fischer, iodine is generated electrochemically in situ during the titration.
The anolyte contains iodide, sulphur dioxide, bases and solvents such as methanol. Electrolytic oxidation occurs when a sample is added to this anolyte.
Iodine is generated at the anode of the titration cell as shown in formula (3)
(3) 2I--2e ---> I2
Stoichiometrically, 1 mole of water will react with 1 mole of iodine, so that 1 milligram of water is equivalent to 10⋅71 coulombs of electricity
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KAOLIN LR

Product Code: RXSOL-60-6604-768

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Product Short Description: KAOLIN LR
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HYPOXANTHINE FOR BIOCHEMISTRY 99%

Product Code: RXSOL-60-6604-707

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Product Short Description: HYPOXANTHINE FOR BIOCHEMISTRY 99%
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ISONIAZIDE PURE 99% Isonicotinic Acid Hydrazide

Product Code: RXSOL-60-6604-749

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Product Short Description: ISONIAZIDE PURE 99% Isonicotinic Acid Hydrazide
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ISO-BUTYL ACETATE FOR SYNTHESIS

Product Code: RXSOL-60-6604-748

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Product Short Description: ISO-BUTYL ACETATE FOR SYNTHESIS
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ISOPHTHALIC ACID 99%

Product Code: RXSOL-60-6604-751

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Product Short Description: ISOPHTHALIC ACID 99%
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ISO-PROPYL ALCOHOL DISINFECTANT IPA 70%

Product Code: RXSOL-60-6604-753

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Product Short Description: ISO-PROPYL ALCOHOL DISINFECTANT IPA 70%
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ISONICOTONIC ACID

Product Code: RXSOL-60-6604-750

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Product Short Description: ISONICOTONIC ACID
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ISO PROPYL ACETATE LR

Product Code: RXSOL-60-6604-752

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Product Short Description: ISO PROPYL ACETATE LR
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HYFLO SUPER CEL FILTERAID CALCINED

Product Code: RXSOL-60-6604-706

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Product Short Description: HYFLO SUPER CEL FILTERAID CALCINED
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Acacia Gum Powder

Product Code: RXSOL-19-6500-025

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Product Short Description: Acacia Gum also called Gum Arabic,is an emulsifying powerhouse! This natural, food-safe gum is obtained from the bark of the acacia tree.
Product Technical Specification:

 

Appearance                               : White to yellowish beige powder
Solubility : 1000 mg soluble in 1 mL of water
Identification test : Passes test
Ash (Total) : <= 4.0%
Insoluble matter : <= 1.0%
Starch or Dextrin : Passes test
Tannin-bearing gums : Passes test
pH : 4.2 - 4.8
Viscosity :131 CPS
Fiber Content (g/100g) :70-90

 

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Functional Properties of Acacia Gum


Acacia Gum / Gum Arabic readily dissolves in water to give clear solutions ranging in colour from very pale yellow to orange·brown and with a pH of - 4.5. The highly branched structure of Acacia senega/gum gives rise to compact molecules with a relatively small hydrodynamic volume and as a consequence gum solutions become viscous only at high concentrations. 30% gum Acacia  solutions have a lower viscosity than 1 % xanthan gum and sodium carboxymethylcellulose at low shear rates. In addition.
Acacia Gum is Newtonian in behaviour with viscosity being shear rate independent.The other major functional characteristic of gum Arabic is its ability to act as an emulsifier for essential oils and flavours. It is now known that the protein·rich high molecular mass component adsorbs preferentially onto the surface of the oil droplets. It is envisaged that the hydrophobic polypeptide chains adsorb and anchor the molecules to the surface while the carbohydrate blocks inhibit flocculation and coalescence through electrostatic and steric repulsions. Since only part of the gum is involved in the emulsification process, the concentration required to produce an emulsion is much higher than for pure proteins. For example, in order to produce a 20% orange oil emulsion then Acacia  concentrations of - 12% are required. Once formed the emulsions can remain stable for long periods of time.

 

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Marine Pollutant : No
ADR/RID : Not Dangerous Goods
IMDG : Not Dangerous Goods
Website : Not Dangerous Goods
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HAYMEM REAGENT

Product Code: RXSOL-60-6604-664

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Product Short Description: HAYMEM REAGENT
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