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Product Name |
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Product Type |
BRILLIANT CRESYL BLUE SOLUTION (ALCOHOLIC) |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substances
Not applicable
2.2. Mixtures
Substance name Contents CAS No
Ethanol 99% 64-17-5
Brilliant Cresyl Blue 1% 81029-05-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008
[CLP]Mixtures/Substances: SDS EU 2015: According to
Regulation (EU) 2015/830 (REACH Annex II)
Flammable liquids, H225
Category 2
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Hazard pictograms
Signal word : Danger
Hazard statements : H225 - Highly flammable liquid and vapour.
Precautionary statements : P210 - Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
3.3. Other hazards
No additional information available.
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately
call a POISON CENTER/doctor.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : Heating may cause a fire or explosion.
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric
charges.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable
containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Do not breathe vapours. Avoid contact with skin and eyes.
Keep away from sources
of ignition - No smoking. Provide good ventilation in process area to prevent
formation of vapour.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before
eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when
using this product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Keep in fireproof place.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 78 °C
Flash point : 15 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available Relative
density : No data available
Density : 0.808 g/cm³
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Heat. Sparks. Open flame. Overheating.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1170
UN-No. (IMDG) : 1170
UN-No. (IATA) : 1170
UN-No. (ADN) : 1170
UN-No. (RID) : 1170
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ETHANOL (ETHYL ALCOHOL) / ETHANOL
SOLUTION (ETHYL ALCOHOL SOLUTION)
Proper Shipping Name (IMDG) : ETHANOL SOLUTION (ETHYL ALCOHOL
SOLUTION)
Proper Shipping Name (IATA) : Ethanol solution Proper Shipping Name
(ADN) : ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Proper Shipping Name
(RID) : ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION) Transport document description
(ADR) : UN 1170 ETHANOL (ETHYL ALCOHOL) / ETHANOL SOLUTION
(ETHYL ALCOHOL SOLUTION), 3, II,
(D/E) Transport document description (IMDG) : UN 1170 ETHANOL SOLUTION
(ETHYL ALCOHOL SOLUTION), 3, II
Transport document description (IATA) : UN 1170 Ethanol solution, 3, II
Transport document description (ADN) : UN 1170 ETHANOL SOLUTION
(ETHYL ALCOHOL SOLUTION), 3, II
Transport document description (RID) : UN 1170 ETHANOL SOLUTION
(ETHYL ALCOHOL SOLUTION), 3, II
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 3
Danger labels (ADR) : 3
IMDG- Transport hazard class(es) (IMDG) : 3
Danger labels (IMDG) : 3
IATA- Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
ADN- Transport hazard class(es) (ADN) : 3
Danger labels (ADN) : 3
RID- Transport hazard class(es) (RID) : 3
Danger labels (RID) : 3
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : F1
Special provisions (ADR) : 144, 601
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions (ADR) : T4
Portable tank and bulk container special provisions (ADR) : TP1
Tank code (ADR) : LGBF Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage -
Operation (ADR) : S2, S20
Hazard identification number
(Kemler No.) : 33
Orange plates : Tunnel restriction
code (ADR) : D/E
EAC code :•2YE
Transport by sea-
Special provisions (IMDG) : 144
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001 IBC
packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Properties and observations (IMDG) : Colourless, volatile liquids.
Pure ETHANOL: flashpoint 13°C c.c.
Explosive limits: 3.3% to 19%
Miscible with water. MFAG-No : 127
Air transport-
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provisions (IATA) : A3, A58, A180
ERG code (IATA) : 3L
Inland waterway transport-
Classification code (ADN) : F1
Special provisions (ADN) : 144, 601
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
Rail transport-
Classification code (RID) : F1
Special provisions (RID) : 144, 601
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID) : T4
Portable tank and bulk container special
provisions (RID) : TP1
Tank codes for RID tanks (RID) : LGBF
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE7
Hazard identification number (RID) : 33
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and
E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ACETIC ACID,
UN N° : 2789
IMO-IMDG - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-C
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ACETIC ACID
UN N° : 2789
IATA - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 851
instruction
- Passenger and Cargo - Maximum : 1 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 855
- Cargo only - Maximum Quantity/ : 30 L
Packing
IATA - Limited Quantites : 0.5 L
ERG-Nr : 8F
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : Ethanol is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : Ethanol is listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen –
Vruchtbaarheid : Ethanol is listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : Ethanol is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1
liter Classification remarks : F ; Emergency management guidelines for the
storage of flammable
liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.