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Product Name |
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Product Type |
BUTAN -2-OL AR (2-BUTYL ALCOHOL) |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation : BUTAN-2-OL
CAS No :78-92-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
2.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : R10 ]
R67
Xi; R36
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Specific Target Organ Toxicity - Single exposure - Respiratory tract
irritation - Category 3 - Warning (CLP : STOT SE 3) H335 Specific Target Organ
Toxicity - Single exposure - Narcotic
effects - Category 3 - Warning (CLP : STOT SE 3) H336
Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319
Physical hazards : Flammable liquids - Category 3 - Warning (CLP : Flam. Liq. 3)
H226
2.2. Label elements Labelling
EC 67/548 or EC 1999/45
Symbol(s) : Xi : Irritant R
Phrase(s) : R10 : Flammable.
R36 : Irritating to eyes.
R37 : Irritating to respiratory system.
R67 : Vapours may cause drowsiness and dizziness.
S Phrase(s) : S13 : Keep away from food, drink and animal feedingstuffs.
S24 : Avoid contact with skin.
S25 : Avoid contact with eyes.
S26 : In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S46 : If swallowed seek medical advice immediately
and show this container or label.
S7 : Keep container tightly closed.
S9 : Keep container in a well-ventilated place.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Warning
Hazard statements : H226 : Flammable liquid and vapour.
H319 : Causes serious eye irritation.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
Precautionary statements
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P233: Keep container tightly closed.
P264: Wash thoroughly after handling.
• Response : P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing.
Rinse skin with water/shower. P337+P313: If eye irritation persists: Get medical advice/attention.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed
P403+P235: Store in well-ventilated place. Keep cool. P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or international regulation.
2.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Call a POISON CENTER or doctor if you feel unwell.
Remove to fresh air and keep at rest in a position comfortable for breathing.
Skin contact : Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing.
Eye contact : Rinse cautiously with water for several minutes.
If eye irritation persists : Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice.
Ingestion : Obtain emergency medical attention. Do NOT induce vomiting. Rinse mouth.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Causes serious eye irritation.
May cause respiratory irritation. May cause drowsiness or dizziness.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If you feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area.
Avoid breathing dust, fume, gas, mist, vapours, spray.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources.
No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters.
Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours are flammable.
Wash thoroughly after handling. Use only outdoors or in a well-ventilated area.
Take precautionary measures against static discharge.
Technical protective measures : Provide good ventilation in process area to prevent formation of vapour.
Proper grounding procedures to avoid static electricity should be followed.
Use only non-sparking tools.
Use explosion-proof electrical, ventilating, lighting, …, equipment.
Special precautions : No naked lights. No smoking. Avoid breathing dust, fume, gas, mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep in fireproof place.
Keep container tightly closed. Ground/bond container and receiving equipment.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Where exposure through inhalation may occur from use,
respiratory protection equipment is recommended.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : 3.2 ppm
pH value : No data available.
Melting point [°C] : -115 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 405 0C
Flammability (solid, gas) : Flammable liquid and vapour.
Flammable. Flash point [°C] : 24 °C
Boiling point [°C] : 99.5°C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : 12 mm Hg @ 20C
Vapour density : 2,6
Density [g/cm3] : 0,808
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water : N/A Log Pow octanol / water at 20°C :
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 7
Viscosity at 40°C [mm2/s] : 3.5 cps @ 20 deg C
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : 9,80%
Explosion limits - lower [%] : 1,70%
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
May release flammable gases.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes serious eye irritation. May cause respiratory irritation.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : May cause drowsiness or dizziness.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment.
Dispose in a safe manner in accordance with local/national regulations.
Dispose of this material and its container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation.
Special precautions : Handle empty containers with care because residual vapours are flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : BUTANOLS
UN N° : 1120
H.I. nr : 30 ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid.
ADR - Classification code : F1
ADR - Group : III
ADR - Packing instructions : P001 R001 LP001
ADR - Limited Quantity : 5 L
ADR - Tunnel code: D/E : Bulk or tank
carriage: Passage forbidden through tunnels of category D and E.
Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : BUTANOLS
UN N° : 1120
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P001 LP01
IMO-IMDG - Limited quantities : 5 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-D
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : BUTANOLS
UN N° : 1120
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED -
Passenger and Cargo - Packing : 355
instruction -
Passenger and Cargo - Maximum : 60 L
Quantity/Packing
IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 366 -
Cargo only - Maximum Quantity/ : 220 L
Packing IATA - Limited Quantites : 10 L
ERG-Nr : 3L
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.