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Product Name |
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Product Type |
PETROLEUM ETHER 60-800C |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation : Petroleum Ether 60-800C
CAS No :8032-32-4
Substance.
Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : F; R11 Xn; R65 R66 R67
N; R51/53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Carcinogenicity - Category 1B - Danger (CLP : Carc. 1B) H350
Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 -
Warning (CLP : STOT SE 3) H336 Specific Target Organ
Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373
Aspiration hazard - Category 1 - Danger (CLP : Asp. Tox. 1) H304
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Germ cell mutagenicity - Category 1B - Danger (CLP : Muta. 1B) H340
Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225
Environmental hazards : Hazardous to the aquatic
environment - Chronic hazard - Category 2 (CLP : Aquatic Chronic 2) H411
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F : Highly flammable
N : Dangerous for the environment
Xn : Harmful
R Phrase(s) : R11 : Highly flammable.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 : Harmful : may cause lung damage if swallowed.
R66 : Repeated exposure may cause skin dryness or cracking.
R67 : Vapours may cause drowsiness and dizziness.
S Phrase(s) : S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
S62 : If swallowed, do not induce vomiting : seek medical advice immediately and show this container or label.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H225 : Highly flammable liquid and vapour.
H304 : May be fatal if swallowed and enters airways.
H350 : May cause cancer.
H340 : May cause genetic defects.
H315 : Causes skin irritation.
H336 : May cause drowsiness or dizziness.
H373 : May cause damage to organs through prolonged or repeated exposure.
H411 : Toxic to aquatic life with long lasting effects. Precautionary statements
• General : P201: Obtain special instructions before use.
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe dust, fume, gas, mist, vapours, spray.
P273: Avoid release to the environment.
P233: Keep container tightly closed.
P264: Wash thoroughly after handling.
• Response : P301+P310: IF SWALLOWED : Immediately call a POISON CENTER or doctor.
P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P308+P313: If exposed or concerned : get medical advice.
P332+P313: If skin irritation occurs : Get medical advice.
P391: Collect spillage.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P314: Get medical advice if you feel unwell.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P403+P235: Store in well-ventilated place. Keep cool. P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or international regulation.
Special labelling : Restricted to professional users
. (Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008)
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Call a POISON CENTER or doctor if you feel unwell.
Remove to fresh air and keep at rest in a position comfortable for breathing.
Skin contact : Wash with plenty of soap and water.
Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse.
Specific treatment (see on this label). Get medical advice if skin irritation occurs
Eye contact : Rinse immediately with plenty of water.
Obtain medical attention if pain, blinking or redness persist
. Ingestion : Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : May cause cancer. May cause genetic defects.
Causes damage to organ. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If you feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Highly flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire.
Avoid (reject) fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area.
Avoid breathing dust, fume, gas, mist, vapours, spray.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters.
Notify authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours
are flammable. Wash thoroughly after handling. Obtain special instructions before use.
Eliminate all ignition sources if safe to do so. Use only outdoors or in a well-ventilated area.
Technical protective measures : Provide good ventilation in process area to prevent formation of vapour.
Proper grounding procedures to avoid static electricity should be followed.
Use explosion-proof electrical, ventilating, lighting, …, equipment.
Special precautions : No naked lights. No smoking. Avoid breathing dust, fume, gas, mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place.
Keep in fireproof place. Ground/bond container and receiving equipment.
Keep container tightly closed.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Where exposure through inhalation may
occur from use, respiratory protection equipment is recommended.
Wear respiratory protection. • Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Odour : gasoline or kerosene.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : 10 Melting
point : No data available
Freezing point : No data available
Boiling point : 60 - 80 °C
Flash point : -26 °C
Auto-ignition temperature : 288 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 °C : 2.5
Relative density : No data available
Density : 0.66 - 0.68 g/cm³
Solubility : Water: Insoluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under
recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight.
Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes.
Carbon monoxide. Carbon dioxide. May release flammable gases.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : May be fatal if swallowed and enters airways.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : May be fatal if swallowed and enters airways
. Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes skin irritation.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : May cause drowsiness or dizziness.
STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard : May be fatal if swallowed and enters airways.
112.1. Toxicity
Toxicity information : Toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause
long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance
does not fulfil the criteria to be identified as PBT substance
or vPvB substance according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment.
Dispose in a safe manner in accordance with local/national regulations.
Dispose of this material and its container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation.
Special precautions : Handle empty containers with care because residual
vapours are flammable. Hazardous waste due to toxicity.
14.1. Land transport (ADR-RID)
Proper shipping name : PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.
(vapour pressure at 50 °C
more than 110 kPa)
UN N° : 1268
H.I. nr : 33
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid.
ADR - Classification code : F1
ADR - Group : II
ADR - Packing instructions : P001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of category D and E.
Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.
(vapour pressure at 50 °C more than 110 kPa)
UN N° : 1268
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-E S-E
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.
(vapour pressure at 50 °C more than 110 kPa)
UN N° : 1268
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED -
Passenger and Cargo - Packing : 353
instruction - Passenger and Cargo - Maximum : 5 L
Quantity/Packing
IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 364 -
Cargo only - Maximum Quantity/ : 60 L
Packing IATA - Limited Quantites : 1 L
ERG-Nr : 3H
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : With the exception of those listed
below: The components of this product are not subject to restrictions. Annex XVII
REACH Authorisation - Annex XIV : The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.