Acrylonitrile
- Part number
- RXSOL-19-1218-160
- Category
- Solvent Chemicals
- Brand
- RXSOL
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Porduct Name | Acrylonitrile |
| Part Number | RXSOL-19-1218-160 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Product name | Cas No | EC No | Weight | Formula |
| Acrylonitrile | 107-13-1 | 203-466-5 | 53,06 g/mol | C3H3N |
| Signal Word | Danger |
| Hazard Statements | H225 Highly flammable liquid and vapor. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H350 May cause cancer. H411 Toxic to aquatic life with long lasting effects |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| Swallowed | If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Nitrogen oxides (NOx) Combustible. Fire may cause evolution of: nitrogen oxides, Hydrogen cyanide (hydrocyanic acid) Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area |
| Reference to other sections | For disposal see section 13. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2 |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols |
| Conditions for safe storage including any incompatibilities |
No data available |
| Storage conditions | Protected from light.Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label. . |
| Storage class | Storage class (TRGS 510): 3: Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing. |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 30 min Material tested:KCL 720 Camapren® |
| Respiratory protection |
Recommended Filter type: Filter A-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | No data available |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Pungent |
| Odor Threshold | No data available |
| pH | No data available |
| Melting Point | -83,5 °C at ca.1.013 hPa |
| Boiling Point | 77,3 °C at ca.1.013 hPa |
| Flash Point | -5 °C - closed cup |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data Available |
| Upper/lower flammability or explosive limits | Upper explosion limit: 28 %(V) Lower explosion limit: 2 %(V) |
| Autoignition temperature | 481 °C at 1.013 hPa |
| Decomposition temperature | No data available |
| Vapour pressure | 133,3 hPa at 23,6 °C |
| Viscosity | dynamic: 0,34 mPa.s at 25 °C |
| Density | 0,806 g/cm3 |
| Relative Density | No data available |
| Specific Gravity | No data available |
| Partition coefficient | log Pow: 0,016 at 21 °C - Bioaccumulation is not expected. |
| Explosive properties | No data available |
| Solubility | 353 g/l at 24 °C at 1.013 hPa |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Vapors may form explosive mixture with air. |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): hydroquinone monomethyl ether (0,004 %) |
| Possibilityof hazardous reactions | Risk of explosion with: Bromine Sodium hydroxide Esters Chlorine Nitric acid Violent polymerization may be caused by: alkali hydroxides Strong bases Oxidizing agents Copper Copper alloys sulfuric acid silver salt polymerisation initiators Peroxides sodium amide with Sodium hydroxide Exothermic reaction with: chlorosulfonic acid Strong acids |
| Conditions to avoid | Heat. May polymerize on exposure to light. Warming. |
| Incompatible materials |
No data available
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | Acute toxicity estimate Oral - 96,06 mg/kg (Calculation method) LD50 Oral - Rat - female - 95,1 mg/kg (acrylonitrile) Remarks: (ECHA) Acute toxicity estimate Inhalation - 4 h - 2,07 mg/l - vapor(Calculation method) LC50 Inhalation - Rat - female - 4 h - 2,05 mg/l - vapor (acrylonitrile) (OECD Test Guideline 403) Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract Acute toxicity estimate Dermal - 252,53 mg/kg (Calculation method) LD50 Dermal - Rabbit - 250 mg/kg (acrylonitrile) Remarks: (IUCLID) |
| Skin corrosion/irritation | Skin - Rabbit (acrylonitrile) Result: Skin irritation - 24 h (OECD Test Guideline 404) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Serious eye damage/irritation | Eyes - Rabbit (acrylonitrile) Result: Risk of serious damage to eyes. (OECD Test Guideline 405) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Respiratory or skin sensitization | Maximization Test - Guinea pig (acrylonitrile) Result: positive (OECD Test Guideline 406) |
| Carcinogenicity | Presumed to have carcinogenic potential for humans (acrylonitrile) |
| Germ cell mutagenicity | Test Type: Ames test (acrylonitrile) Test system: S. typhimurium Metabolic activation: Metabolic activation Method: OECD Test Guideline 471 Result: positive Test Type: Mutagenicity (mammal cell test): chromosome aberration. (acrylonitrile) Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Result: positive Remarks: (ECHA) Test Type: In vitro mammalian cell gene mutation test (acrylonitrile) Test system: mouse lymphoma cellsMetabolic activation: without metabolic activation Method: OECD Test Guideline 476 Result: positive |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure |
May cause respiratory irritation. (acrylonitrile) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea (acrylonitrile) To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. (acrylonitrile) After absorption: (acrylonitrile) Headache Nausea Vomiting Dizziness agitation Convulsions respiratory arrest Unconsciousness (acrylonitrile) The following applies to cyanogen compounds/ nitriles in general: utmost caution! Release of hydrocyanic acid is possible - blockade of cellular respiration. Cardiovascular disorders, dyspnoea, unconsciousness. (acrylonitrile) Other dangerous properties can not be excluded. (acrylonitrile) This substance should be handled with particular care. (acrylonitrile) |
| Persistence and degradability | Biodegradability aerobic - Exposure time 14 d (acrylonitrile) Result: 100 % - Inherently biodegradable. (OECD Test Guideline 302C) Ratio BOD/ThBOD 70 % (acrylonitrile) (Lit.) |
| Toxicity to fish | semi-static test LC50 - Oryzias latipes - 5,1 mg/l - 96 h (acrylonitrile) (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | static test EC50 - Daphnia magna (Water flea) - 2,5 mg/l - 48 h (acrylonitrile) (OECD Test Guideline 202) |
| Toxicity | No data available |
| Toxicity to bacteria | EC5 - Pseudomonas putida - 53 mg/l - 16 h (acrylonitrile) (Lit.) (maximum permissible toxic concentration) |
| Toxicity to algae | static test ErC50 - Pseudokirchneriella subcapitata - 10 mg/l - 72 h (acrylonitrile) (OECD Test Guideline 201) |
| Bioaccumulation potential | Bioaccumulation Lepomis macrochirus - 14 d - 9,94 µg/l(acrylonitrile) Bioconcentration factor (BCF): 48 |
| Mobility in soil | No data availalble |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting propertiesaccording to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Forms toxic mixtures in water, dilution measures notwithstanding. Discharge into the environment must be avoided |
| Product | No data available |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number | ADR/RID:1093 | IMDG:1093 |
IATA:1093 |
| UN proper shipping name | ADR/RID:ACRYLONITRILE, STABILIZED | IMDG:ACRYLONITRILE, STABILIZED | IATA:ACRYLONITRILE, STABILIZED |
| Transport hazard class(es) | ADR/RID:3 (6.1) | IMDG:3 (6.1) | IATA:3 (6.1) |
| Packaging group | ADR/RID:l | IMDG:l | IATA:l |
| Environmental hazards | ADR/RID:Yes | IMDG:Yes | IATA:No |
| Special precautions for user | Tunnel restriction code (C/E) | ||
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment was not carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
