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Product Name |
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Product Type |
BUTYLATED HYDROXY ANISOLE (B.H.A.) |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substances : BUTYLATED HYDROXY ANISOLE
CAS-No. : 25013-16-5
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), H302
Category 4
Skin corrosion/irritation, H315
Category 2
Serious eye damage/eye irritation, H319
Category 2
Carcinogenicity, H351
Category 2
Specific target organ H335
toxicity — Single
exposure, Category 3,
Respiratory tract irritation
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : Xi : Irritation
Xn: Harmful
R Phrase(s) : R22: Harmful if swallowed.
R40: Possible risk of very serious irreversible effects.
R36/37/38:Irritating to eyes, respiratory system and skin.
S Phrase(s) :S26: In the case of contact with eyes, rinse immediately with plenty of water
and seek medical advise.
S36/37 : Wear suitable protective clothing and gloves.
Hazard pictograms
Signal word : Warning
Hazard statements : H302 - Harmful if swallowed.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
H351 - Suspected of causing cancer.
Precautionary statements : P261 - Avoid breathing vapours, mist, dust, fume, gas.
P281 - Use personal protective equipment as required.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
2.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated
clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Get medical
advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you
feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Soak up
spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Use only outdoors or in
a well-ventilated area. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in a well-ventilated place.
7.3. Specific end use(s)
No additional information available.
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 58 - 60 °C
Freezing point : No data available
Boiling point : 268 °C
Flash point : 113 °C
Auto-ignition temperature : 315 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : 6.2
Relative density : No data available
Density : 1.05 g/cm³
Solubility : Water: Insoluble in water
Log Pow : 3.335
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Air contact. Moisture. Water, humidity.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects
and symptoms : Harmful if swallowed.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Log Pow 3.335
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to
hazardous or special waste collection point, in accordance with local, regional, national
and/or international regulation.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : Not applicable
UN-No. (IMDG) : Not applicable
UN-No. (IATA) : Not applicable
UN-No. (ADN) : Not applicable
UN-No. (RID) : Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : Not applicable
IMDG- Transport hazard class(es) (IMDG) : Not applicable
IATA- Transport hazard class(es) (IATA) : Not applicable
ADN- Transport hazard class(es) (ADN) : Not applicable
RID- Transport hazard class(es) (RID) : Not applicable
14.4. Packing group
Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- No data available
Transport by sea- No data available
Air transport-No data available
Inland waterway transport- No data available
Rail transport- No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
BUTYLATED HYDROXY ANISOLE is not on the REACH Candidate List
BUTYLATED HYDROXY ANISOLE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen –
Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product Pregnant/breastfeeding women working with the product must
not be in direct contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.