|
Product Name |
Potassium perchlorate |
|
Part Number |
RXSOL-19-3356-058 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
|
Phone |
+91 22 20871200 - 1400 |
|
Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
|
Email |
rxsolchemicals@gmail.com |
|
Website |
www.rxmraine.com |
|
Chemical Name |
CAS |
EC number |
Weight% |
Moleculer Formula |
|
Potassium perchlorate |
7778-74-7 |
231-912-9 |
<= 100 |
ClKO4 |
|
Signal word |
Danger |
|
Hazard Statements |
H271 May cause fire or explosion; strong oxidizer. |
|
Precautionary statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep away from clothing and other combustible materials. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. |
|
Classification according to Directive 67/548/EEC or 1999/45/EC |
Classification according to Directive 67/548/EEC or 1999/45/EC |
|
Disposal |
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
|
Prevention |
P273 Avoid release to the environment. |
|
Supplemental Hazard Statements |
None |
|
Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
|
General advice |
Show this material safety data sheet to the doctor in attendance. |
|
If inhaled |
After inhalation: fresh air. |
|
Eye Contact |
After eye contact: rinse out with plenty of water. Remove contact lenses. |
|
Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
|
Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
|
Inhalation |
Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
|
Ingestion |
If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain immediate medical attention. Do NOT induce vomiting. Give nothing to eat or drink. |
|
Notes to Physician |
Treat symptomatically |
|
Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
|
Indication of any immediate medical attention and special treatment needed |
No data available |
|
Flammability |
May be combustible at high temperature. |
|
Suitable extinguishing media |
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
|
Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
|
Special hazards arising from the substance or mixture |
Hydrogen chloride gas Potassium oxides Not combustible. Has a fire-promoting effect due to release of oxygen. Ambient fire may liberate hazardous vapours. |
|
Further information |
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
|
Advice for firefighters |
In the event of fire, wear self-contained breathing apparatus. |
|
Protective Equipment |
Use personal protective equipment. |
|
Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
|
Additional information |
Do not allow run-off from fire-fighting to enter drains or water courses. Do not inhale explosion and combustion gases. Use caution when applying carbon dioxide in confined spaces. Carbon dioxide can displace oxygen. Use water spray jet to protect personnel and to cool endangered containers. |
|
Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
|
Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
|
Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
|
Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
|
Advice on safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
|
Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition. |
|
Hygiene measures |
Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance. For precautions see section 2.2. |
|
Precautions for safe handling |
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. |
|
Conditions for safe storage, including any incompatibilities |
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air sensitive. Handle and store under inert gas. |
|
Storage conditions |
Tightly closed. Separately or together with other oxidising substances only and away from sources of ignition and heat.Because of their oxidation potential these products can raise the burning rate of combustible substances substantially or ignite combustible substances on contact with them. hygroscopic |
|
Storage class |
Storage class (TRGS 510): 5.1A: Strongly oxidizing hazardous materials |
|
Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated. |
|
Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
|
Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
|
Personal protection equipment |
Wear suitable protective clothing. When handling with chemical substances, protective clothing with CE-labels including the four control digits must be worn. For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes). Eye/face protection Eye glasses with side protection DIN-/EN-Norms: DIN EN 166 Recommendation: VWR 111-0432 Skin protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. Recommended glove articles DIN-/EN-Norms: DIN EN 374 In the case of wanting to use the gloves again, clean them before taking off and air them well. |
|
Control parameters |
Does not contain substances above concentration limits fixing an occupational exposure limit. |
|
Biological limit values |
No data available |
|
Exposure controls |
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the riskelimination area |
|
Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
|
Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
|
Body Protection |
Protective clothing |
|
Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
|
Respiratory protection |
Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
|
Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
|
Control of environmental exposure |
Do not let product enter drains. |
|
Physical state |
Crystalline |
|
Colour |
White |
|
Odour |
No data available |
|
Odor Threshold |
Not Applicable |
|
pH |
5,0 - 6,5 at 13,9 g/l at 25 °C |
|
Melting Point |
400 °C - dec. |
|
Boiling Point |
No data available |
|
Flash Point |
No data availabl |
|
Viscosity |
No data available |
|
Evaporation Rate |
Not Applicable |
|
Flammability (solid, gas) |
Flammability (solids) |
|
Explosive limits |
No Data Available |
|
Upper/lower flammability or explosive limits |
No data available |
|
Autoignition temperature |
No data available |
|
Decomposition temperature |
No data available |
|
Vapour pressure |
No data available |
|
Density |
2,520 g/cm3 |
|
Relative density |
No data available |
|
Vapour Density |
No data available |
|
Specific Gravity |
No data available |
|
Partition coefficient |
No data available |
|
Explosive properties |
None |
|
Solubility |
ca.13,9 g/l at 20 °C |
|
Ignition temperature |
No information available. |
|
Particle characteristics |
No data available |
|
Reactivity |
No data availabl |
|
Stability |
The product is chemically stable under standard ambient conditions (room temperature) |
|
Possibility of hazardous reactions |
Exothermic reaction with: Fluorine Risk of explosion with: Activated charcoal powdered aluminium combustible substances Halogenated compounds ethanol charcoal Organic Substances Polyvinyl chloride Reducing agents Acids sulfur resins sugars Powdered metals Ethylene glycol powdered magnesium Ammonium salts combustible substances hydrides Aldehydes nitrates calcium carbonate potassium nitrate with Aluminum and Water. |
|
Conditions to avoid |
No data available |
|
Incompatible materials |
No data available |
|
Hazardous decomposition products |
In the event of fire: see section 5 |
|
Acute toxicity |
Oral: No data available Inhalation: No data available Dermal: No data available |
|
Skin corrosion/irritation |
Remarks: No data available Remarks: No data available |
|
Serious eye damage/eye irritation |
No data available |
|
Respiratory or skin sensitization |
No data available |
|
Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
|
Germ cell mutagenicity |
No data available |
|
Reproductive toxicity |
No data available |
|
Specific target organ toxicity - single exposure |
No data available |
|
Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
|
Additional Information |
RTECS: GF8750000 Kidney injury may occur., Damage to the eyes., Lung irritation, Throat., Rash, Vomiting, Diarrhoea |
|
Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: SC9700000 Blood disorders, Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. |
|
Persistence and degradability |
No data available |
|
Toxicity |
Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 670 mg/l - 24 h |
|
Bioaccumulative potential |
No data available |
|
Toxicity to fish |
LC50 - Danio rerio (zebra fish) - 100,01 mg/l - 96 |
|
Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia magna (Water flea) - 11,2 mg/l - 48 h (ISO 6341) Remarks: (ECHA)semi-static test NOEC - Daphnia magna (Water flea) - 0,20 mg/l - 21 d Remarks: (ECHA) |
|
Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata (algae) - 91 mg/l - 72 h (ISO 8692) Remarks: (ECHA) |
|
Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
|
Mobility in soil |
No Information available |
|
Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
|
Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
|
Other adverse effects |
No data available |
|
Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
|
Contaminated packaging |
Dispose of as unused . |
|
Waste treatment Method |
No data available |
|
UN number |
ADR/RID: 1489 IMDG: 1489 IATA: 1489 |
|
UN proper shipping name |
ADR/RID:POTASSIUMPERCHLORAT, IMDG:POTASSIUMPERCHLORATE IATA: POTASSIUM PERCHLORATE |
|
Transport hazard class(es) |
ADR/RID: 5.1 IMDG: 5.1 IATA: 5.1 |
|
Packaging group |
ADR/RID: II IMDG: II IATA: II |
|
Environmental hazards |
ADR/RID: NO IMDG: NO IATA: NO |
|
Special precautions for user |
No data available |
|
Further information |
No data available |
|
Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
|
Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
|
National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : OXIDISING LIQUIDS AND SOLIDS : OXIDISING LIQUIDS AND SOLIDS |
|
Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
|
Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out. |
|
Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
|
