Acetone cyanohydrin
2-hydroxy-2-methylpropanenitrile is a cyanohydrin. Acetone cyanohydrin (ACH) is an organic compound used in the production of acrylic
- Part number
- RXSOL-19-1215-026
- Category
- Paint and Cleaning solvent
- Brand
- RXSOL
Overview
Acetone cyanohydrin industrially used in the manufacturing of methyl methacrylate monomer of the transparent plastic polymethyl methacrylate PMMA.
Technical specifications
| PRODUCT NAME | : | ACETONECYANOHYDRIN |
| CAS number | : | 75-86-5 |
| UN number | : | 1541 |
| Formula | : | (CH3)2COHON |
| Odour | : | |
| Solubility in water | : | COMPLETE |
| Density | : | 0.932 at 19 oC |
| Boiling point | : | 95 oC |
| Melting point | : | 20 oC |
| Viscosity | : | |
| Flashpoint | : | 74 oC |
| Explosive limits | : | 2 – 11 Vol % |
| Vapour pressure | : | 1.1 mbar at 20 oC |
| Skin absorption/irriation | : | YES |
| TLV Country | : | |
| Pollution category 1994 | : | A |
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Acetone Cyanohydrin |
| Part Number | RXSOL-19-1215-026 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
Substances
| Synonyms |
α-Hydroxy iso butyronitrile
2-Hydroxyisobutyronitrile
|
| Formula | C4H7NO |
| Molecular weight | 85,10 g/mol |
| CAS-No. | 75-86-5 |
| EC-No. | 200-909-4 |
| Index-No. | 608-004-00-X |
| Component | Classification | Concentration |
| 2-Cyanopropan-2-ol | ||
|
CAS-No. 75-86-5
EC-No. 200-909-4
Index-No. 608-004-00-X
|
Acute Tox. 2; Acute Tox.
1; Aquatic Acute 1;
Aquatic Chronic 1; H300,
H330, H310, H400, H410
M-Factor - Aquatic Acute:
10
M-Factor - Aquatic
Chronic: 1
|
<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Acute toxicity, (Category 2) |
H300: Fatal if swallowed.
|
| Acute toxicity, (Category 2) | H330: Fatal if inhaled. |
| Acute toxicity, (Category 1) | H310: Fatal in contact with skin. |
|
Short-term (acute) aquatic
hazard, (Category 1)
|
H400: Very toxic to aquatic life. |
|
Long-term (chronic) aquatic
hazard, (Category 1)
|
H410: Very toxic to aquatic life with long lasting effects. |
Label elements
| Signal Word | Danger |
| Hazard Statements |
H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled.
H410 Very toxic to aquatic life with long lasting effects.
|
| Precautionary Statements |
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing.
P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (<= 125 ml) | |
| Signal Word | Danger |
| Hazard Statements | H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled. |
| Precautionary Statements |
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing.
P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a
POISON CENTER/ doctor.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Stench.
|
| General Advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| If swallowed | If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Suitable extinguishing media | Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
|
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
|
| Environmental precautions | Do not let product enter drains. |
| Methods and material for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities | |
| Storage conditions |
Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
|
| Storage class | Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection |
Protective clothing
|
| Respiratory protection |
Required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type ABEK
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Clear, liquid |
| Color | Light yellow |
| Odor | Pungent |
| Melting point/freezing point | Melting point/range: -19 °C - lit. |
| Initial boiling point and boiling range | 82 °C at 31 hPa - lit. |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 11 %(V)
Lower explosion limit: 2,25 %(V)
|
| Flash point | 75 °C - closed cup |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| pH | No data available |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | No data available |
| Partition coefficient: n-octanol/water | No data available |
| Vapor pressure | 0,3 hPa at 20 °C - OECD Test Guideline 104 |
| Density | 0,932 g/cm3 at 25 °C - lit. |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | No data available |
| Reactivity |
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
|
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | Strong heating |
| Incompatible materials | Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents |
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity |
LD50 Oral - Rat - male - 16 mg/kg
Acute toxicity estimate Inhalation - 4 h - 0,6 mg/l - vapor
(Expert judgment)
LD50 Dermal - Rabbit - 15,8 mg/kg
|
| Skin corrosion/irritation | Remarks: No data available |
| Serious eye damage/eye irritation | Remarks: No data available |
| Respiratory or skin sensitization | Remarks: No data available |
| Germ cell mutagenicity |
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
|
| Carcinogenicity | No data available |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Specific target organ toxicity - repeated exposure | No data available |
| Aspiration hazard | No data available |
| Additional Information | |
| Endocrine disrupting properties Product: | |
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
RTECS: EO1925000
drying, cracking of the skin, Skin irritation
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Liver - Irregularities - Based on Human Evidence
|
| Toxicity | |
| Toxicity to fish |
Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 0,22 mg/l
- 96 h
Remarks: (ECHA)
|
|
Toxicity to daphnia
and other aquatic
invertebrates
|
Static test EC50 - Daphnia magna (Water flea) - 0,13 mg/l - 48 h
(OECD Test Guideline 202)
|
| Toxicity to bacteria |
EC50 - Vibrio fischeri - 21 mg/l - 0,25 h
Remarks: (ECHA)
|
| Persistence and degradability | No data available |
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties Product | |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Discharge into the environment must be avoided. |
| Waste Treatment Methods | No data available |
| UN number | ADR/RID: 1541 IMDG: 1541 IATA: 1541 |
| UN proper shipping name |
ADR/RID: ACETONE CYANOHYDRIN, STABILIZED
IMDG: ACETONE CYANOHYDRIN, STABILIZED
IATA: Acetone cyanohydrin, stabilized
Passenger Aircraft: Not permitted for transport
Cargo Aircraft: Not permitted for transport
|
| Transport hazard class(es) | ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 |
| Packaging group | ADR/RID: I IMDG: I IATA: I |
| Environmental hazards | ADR/RID: no IMDG Marine pollutant: no IATA: no |
| Special precautions for user | |
| Tunnel restriction code | (C/D) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
|
National legislation
Seveso III: Directive 2012/18/EU of the
European Parliament and of the Council
on the control of major-accident hazards
involving dangerous substances.
|
H1 ACUTE TOXIC
E1 ENVIRONMENTAL HAZARDS
|
| Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.
|
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
Availability
Acetone Cyanohydrin manufacturer supplier distributor in Mumbai, Kandla, Kolkata, Vizag, Chennai, India, Fujairah, Dubai UAE, Muscat Oman, Kenya Africa. Get the best quality of Acetone Cyanohydrin at a competitive price from us. We have ready stock of Acetone Cyanohydrin in India, UAE Gulf, Oman, Kenya Africa. Contact us for bulk as well as small orders.
