|
Product Name |
RXSOL-60-6604-039 |
|
Product Type |
BENZENE AR |
|
Revised date |
|
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation :
Substance name Contents CAS No Benzene 100% 71-43-2 Substance.
Contains no other components or impurities which will influence the classification of the
product.
2.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : F; R11
Carc. Cat. 1; R45
Muta. Cat. 2; R46
T; R48/23/24/25
Xn; R65
Xi; R36/38
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Carcinogenicity - Category 1A - Danger (CLP : Carc. 1A) H350
Specific Target Organ Toxicity - Repeated exposure - Category 1 - Danger (CLP : STOT RE 1) H372
Aspiration hazard - Category 1 - Danger (CLP : Asp. Tox. 1) H304
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Germ cell mutagenicity - Category 1B - Danger (CLP : Muta. 1B) H340
Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319
Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225
2.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F : Highly flammable
T : Toxic
R Phrase(s) : R45 : May cause cancer.
R46 : May cause heritable genetic damage.
R11 : Highly flammable.
R36/38 : Irritating to eyes and skin.
R48/23/24/25 : Toxic : danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R65 : Harmful : may cause lung damage if swallowed.
S Phrase(s) : S53 : Avoid exposure - obtain special instructions before use.
S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible).
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms

Signal words : Danger
Hazard statements : H225 : Highly flammable liquid and vapour.
H304 : May be fatal if swallowed and enters airways.
H350 : May cause cancer. H340 : May cause genetic defects.
H319 : Causes serious eye irritation.
H315 : Causes skin irritation.
H372 : Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
• General : P201: Obtain special instructions before use.
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P260: Do not breathe dust, fume, gas, mist, vapours, spray.
P233: Keep container tightly closed. P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P301+P310: IF SWALLOWED : Immediately call a POISON CENTER or doctor.
P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P308+P313: If exposed or concerned : get medical advice.
P332+P313: If skin irritation occurs : Get medical advice.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P314: Get medical advice if you feel unwell.
P370+P378: In case of fire: Use for extinction.
•Storage : P403+P235: Store in well-ventilated place. Keep cool.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or international regulation.
Special labelling : Restricted to professional users. (Substances which appear in Part 3 of
Annex VI to Regulation (EC) No 1272/2008)
2.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest.
Skin contact : Wash contaminated clothing before reuse.
If skin irritation occurs : Get medical advice. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
Eye contact : Get medical advice. If eye irritation persists : Remove contact lenses, if
present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
Ingestion : Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : May cause cancer. May cause genetic defects.
Causes damage to organs through prolonged or repeated exposure. May be fatal if swallowed
and enters airways. Causes serious eye irritation. Causes skin irritation.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Highly flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection.
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours are flammable.
Wash thoroughly after handling. Obtain special instructions before use.
Eliminate all ignition sources if safe to do so. Do not eat, drink or smoke when using this product.
Wash thoroughly after handling. Do not breathe dust, fume, gas, mist, vapours, spray.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour.Proper grounding procedures to avoid static electricity should be followed.
Use explosion-proof electrical, ventilating, lighting, …, equipment. Special precautions : No naked lights. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep in fireproof place. Keep
container tightly closed. Ground/bond container and receiving equipment.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear respiratory protection.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available
.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour : Characteristic.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : No data available.
Decomposition point [°C] : No data available.
Critical temperature [°C] : No data available.
Auto-ignition temperature [°C] : No data available.
Flammability (solid, gas) : Highly flammable liquid and vapour.
Flash point [°C] : No data available.
Initial boiling point [°C] : No data available.
Final boiling point [°C] : No data available.
Evaporation rate : No data available.
Vapour pressure [20°C] : No data available.
Vapour density : No data available.
Density [g/cm3] : No data available.
Relative density, liquid (water=1) : No data available.
Solubility in water : No data available.
Log Pow octanol / water at 20°C : No data available.
Viscosity at 40°C [mm2/s] : No data available.
9.2. Other information
Explosive properties : No data available.
Explosion limits - upper [%] : No data available.
Explosion limits - lower [%] : No data available.
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
May release flammable gases.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : May be fatal if swallowed and enters airways.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : May be fatal if swallowed and enters airways.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes serious eye irritation. Causes skin irritation.
Sensitization : Based on available data, the classification criteria are not met
Mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : May be fatal if swallowed and enters airways.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations.
Dispose of this material and its container to hazardous or special waste collection point, in accordance with local
, regional, national and/or international regulation. Special precautions : Handle empty containers with care because
residual vapours are flammable. Hazardous waste due to toxicity.
14.1. Land transport (ADR-RID)
Proper shipping name : BENZENE
UN N° : 1114
H.I. nr : 33
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid.
ADR - Classification code : F1
ADR - Group : II
ADR - Packing instructions : P001 R001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of c
ategory D and E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : BENZENE
UN N° : 1114
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-D
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : BENZENE
UN N° : 1114
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 353
instruction
- Passenger and Cargo - Maximum : 5 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 364
- Cargo only - Maximum Quantity/ : 60 L
Packing IATA - Limited Quantites : 1 L ERG-Nr : 3H
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : With the exception of those listed below: Annex XVII The components of this product are not subject to restrictions.
REACH Authorisation - Annex XIV :The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.