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Product Name |
RXSOL-60-6604-056 |
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Product Type |
BENZYL BENZOATE (Confirming to BP) |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1 Substances: Benzyl Benzoate
CAS-No. : 120-51-4
Substance name Contents CAS No
Benzyl benzoate <= 100 % 120-51-4
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Chronic aquatic toxicity (Category 2), H411
For the full text of the H-Statements mentioned in this Section, see Section
16. 2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Symbol(s) : Xn: Harmful
N : Dangerous for the environment
R Phrase(s) : R22: Harmful if swallowed.
R51/53 : Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S Phrase(s) : S2: Keep out of reach of children.
S25 : Avoid contact with eyes.
S46: If swallowed seek medical advice immediately and show this container or label.
S61: avoid release to the environment .
refer to special instruction/safety data sheets.
Labelling according Regulation (EC) No 1272/2008
Hazard pictograms
Signal word : Warning
Hazard statement(s)
H302 Harmful if swallowed.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P273 Avoid release to the environment.
Supplemental Hazard Statements None
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very
bioaccumulative (vPvB) at levels of 0.1% or higher.
4.1 Description of first aid measures
• General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
• If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
•In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
•In case of eye contact
Flush eyes with water as a precaution.
•If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in
the labelling (see section 2.2) and/or in section
11 4.3 Indication of any immediate medical attention and special treatment needed
No data available
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas.
Ensure adequate ventilation. For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to
prevent leakage. Storage class (TRGS 510): Combustible liquids
7.3 Specific end use(s)
Apart from the uses mentioned in section
1.2 no other specific uses are stipulated
8.1 Control parameters
8.2 Exposure controls
•Appropriate engineering controls
Handle in accordance with good industrial hygiene
and safety practice. Wash hands before breaks and at the end of workday.
•Personal protective equipment
•Eye/face protection
Face shield and safety glasses
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
•Skin protection
Handle with gloves.Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. If used in solution, or mixed with other substances, and under conditions which differ
from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must
be evaluated by an industria situation of anticipated use by our customers. It should not be construed as
offering an approval for any specific use scenario.
• Body Protection
Complete suit protecting against chemicals, The type of protective equipment must
be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
• Respiratory protection
Where risk assessment shows air-purifying respirators
are appropriate use (US) or type ABEK (EN 14387) respirator cartridges as a backup
to enginee protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
• Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains. Discharge into the environment must be avoided.
9.1 Information on basic physical and chemical properties
Odour Threshold: No data available
pH: No data available
Melting point/freezing point
Melting point/range: 17 - 20 °C - lit.
Initial boiling point and boiling range:323 - 324 °C - lit.
Flash point 158 °C - closed cup
Evaporation rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits : No data available
Vapour pressure 1 mmHg at 125 °C
Vapour density : No data available
Relative density :1.118 g/cm3 at 20 °C
Water solubility No data available
Partition coefficient: noctanol/ Water :log Pow: 4
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity: No data available
Explosive properties: No data available
Oxidizing properties: No data available
9.2 Other safety information
No data available
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides Other
decomposition products - No data available
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicity LD50 Oral - Rabbit - 1,680 mg/kg(Benzyl benzoate)
LD50 Dermal - Rabbit - 4,000 mg/kg(Benzyl benzoate)
•Skin corrosion/irritation
No data available(Benzyl benzoate)
•Serious eye damage/eye irritation
No data available(Benzyl benzoate)
•Respiratory or skin sensitisation
No data available(Benzyl benzoate)
• Germ cell mutagenicity
No data available(Benzyl benzoate)
• Carcinogenicit
IARC: No component of this product present at levels greater
than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
• Reproductive toxicity
No data available(Benzyl benzoate)
• Specific target organ toxicity - single exposure
No data available(Benzyl benzoate)
• Specific target organ toxicity - repeated exposure
No data available
• Aspiration hazard
No data available(Benzyl benzoate)
• Additional Information
RTECS: DG4200000
Cardiovascular effects.,
Muscle cramps/spasms., Ataxia.(Benzyl benzoate) To the best of our knowledge,
the chemical, physical, and toxicological properties have not been thoroughly investigated.
(Benzyl benzoate)
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available(Benzyl benzoate)
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to
be either persistent, bioaccumulative and toxic (PBT), or very
persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Toxic to aquatic life with long lasting effects.
13.1 Waste treatment methods
•Product
Offer surplus and non-recyclable
solutions to a licensed disposal company.
•Contaminated packaging
Dispose of as unused product.
14.1 UN number
ADR/RID: 3082 IMDG: 3082 IATA: 3082
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Benzyl benzoate) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Benzyl benzoate) IATA: Environmentally hazardous substance, liquid, n.o.s.
(Benzyl benzoate)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: no IATA: yes
14.6 Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and
combination packagings containing inner packagings with Dangerous Goods > 5L for
liquids or > 5kg for solids.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.