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Product Name |
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Product Type |
Bismuth Metal Powder |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substances
Formula : Bi
Molecular weight : 208.98 g/mol
CAS-No. : 7440-69-9
No components need to be disclosed according to the applicable regulations.
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.1.Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable solids (Category 1), H228
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Danger
Hazard statement(s)
H228 Flammable solid.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P370 + P378 In case of fire: Use dry powder or dry sand to extinguish.
Supplemental Hazard none
Statements
3.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Nature of decomposition products not known.
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.
6.1 Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all
sources of ignition. Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Sweep up and shovel.\'20 Contain spillage, and then collect with an electrically protected vacuum
cleaner or by wet-brushing and place in container for disposal according to local regulations (see section
13). Keep in suitable, closed containers for disposal.\'20 Contain spillage, pick up with an electrically
protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local
regulations (see section 13).
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition -
No smoking.Take measures to prevent the build up of electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510): Flammable solid hazardous materials
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8.1 Control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Body Protection
Flame retardant antistatic protective clothing., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (EN 143) respirator
cartridges as a backup to engineering controls. If th full-face supplied air respirator. Use respirators
and components tested and approved under appropriate government standards such as NIOSH (US)
or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: Dark purple to grey to black
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available No data available
e) Melting point/freezing Melting point/range: 271 °C - lit.
point
f) Initial boiling point and
boiling range 1,560 °C - lit.
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) The substance or mixture is a flammable solid with the category 1
j) Upper/lower No data available
flammability or
explosive limits
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density 9.8 g/mL at 25 °C
n) Water solubility No data available
o) Partition coefficient n- No data available
octanol/water
p) Auto-ignition No data available
temperature
q) Decomposition No data available
temperature
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
Other decomposition products - No data available
Hazardous decomposition products formed under fire conditions. - Nature of decomposition products not
known.
In the event of fire: see section 5
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - 2,000 mg/kg(Bismuth Powder)
(OECD Test Guideline 401)
Skin corrosion/irritation
No data available(Bismuth Powder)
Serious eye damage/eye irritation
No data available(Bismuth Powder)
Respiratory or skin sensitisation
No data available(Bismuth Powder)
Germ cell mutagenicity
No data available(Bismuth Powder)
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available(Bismuth Powder)
Specific target organ toxicity - single exposure
No data available(Bismuth Powder)
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available(Bismuth Powder)
Additional Information
RTECS: EB2600000
12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available(Bismuth Powder)
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
No data available
13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber b highly flammable. Offer
surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14.1 UN number
ADR/RID: 3089 IMDG: 3089 IATA: 3089
14.2 UN proper shipping name
ADR/RID: METAL POWDER, FLAMMABLE, N.O.S. (Bismuth Powder)
IMDG: METAL POWDER, FLAMMABLE, N.O.S. (Bismuth Powder)
IATA: Metal powder, flammable, n.o.s. (Bismuth Powder)
14.3 Transport hazard class(es)
ADR/RID: 4.1 IMDG: 4.1 IATA: 4.1
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
ADR - Packing instructions : P001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and
E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ACETIC ACID,
UN N° : 2789
IMO-IMDG - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-C
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ACETIC ACID
UN N° : 2789
IATA - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 851
instruction
- Passenger and Cargo - Maximum : 1 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 855
- Cargo only - Maximum Quantity/ : 30 L
Packing
IATA - Limited Quantites : 0.5 L
ERG-Nr : 8F
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information in this document is based on the present state of our knowledge and is
applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Central Drug House (P) Ltd and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
www.cdhfinechemical.com for additional terms and conditions
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.