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Lab Chemical

BISMUTH NITRATE PENTAHYDRATE

Part number
RXSOL-60-6604-072
Category
Lab Chemical
Brand
RXSOL
RXSOL

Overview

Bismuth nitrate pentahydrate is a salt composed of bismuth in its cationic +3 oxidation state and nitrate anions. The most common solid form is the pentahydrate. It is used in the synthesis of other bismuth compounds. It is available commercially.

Bismuth nitrate is a salt. It contains the heavy metal bismuth. People use bismuth nitrate for preventing kidney damage caused by cancer drugs, for preventing bone marrow damage.

Bismuth nitrate is a salt. It contains the heavy metal bismuth. People use bismuth nitrate for preventing kidney damage caused by cancer drugs, for preventing bone marrow damage caused by radiation, and for a digestive tract infection that can lead to ulcers (Helicobacter pylori or H.

Applications

Bismuth nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

Dosage and directions

700 mg of bismuth subnitrate three times daily for 4 weeks has been used. Also, 300 mg of bismuth subnitrate four times daily, 20 mg of omeprazole twice daily, and 500 mg of amoxicillin four times daily for 2 weeks have been used.

Characteristics and notes

Hygroscopic. Moisture sensitive. Incompatible with strong acids, strong reducing agents, strong oxidizing agents, powdered metals and organic materials.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product Name  RXSOL-60-6604-072
Product Type BISMUTH NITRATE (PENTHYDRATE)
Revised date  

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
2.1. Substances: Bismuth Nitrate (Pentahydrate)
CAS-No. : 10035-06-0
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Skin corrosion/irritation, H315
Category 2
Serious eye damage/eye H319
irritation, Category 2
Specific target organ
toxicity — Single H335
exposure, Category 3,
Respiratory tract irritation
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
O; R8
Xi; R36
Xi; R37
Xi; R38
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
display Extra classification(s) to display
Symbol(s) : O : Oxidizing
Xi : Irritation.
R Phrase(s):R8: Contact with combustible material may cause fire.
R36/37/38 Irritating to eyes, respiratory system and skin.
S Phrase(s) :S17: Keep away from combustible material.
S26: In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise.
S37/39 : Wear suitable gloves and eye/face protection.
Hazard pictograms
Signal word : Danger
Hazard statements : H272 - May intensify fire; oxidiser.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H335 - May cause respiratory irritation.
Precautionary statements: P220 - Keep/Store away from clothing, combustible materials.
P261 - Avoid breathing vapours, dust, fume, gas, spray.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated
clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Get medical
advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
 
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4. Reference to other sections
No additional information available. 
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Use only outdoors or in
a well-ventilated area. Do not breathe vapours. Provide good ventilation in process area
to prevent formation of vapour.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before
eating,
drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in a well-ventilated place.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 30 °C
Freezing point : No data available
Boiling point : 75 - 80 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available 
Relative density : No data available
Density : 2.83 g/cm³
Solubility : Water: Slowly decomposes in water to form subnitrate
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Moisture. Air contact. Direct sunlight.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
No additional information available 
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1477
UN-No. (IMDG) : 1477
UN-No. (IATA) : 1477
UN-No. (ADN) : 1477
UN-No. (RID) : 1477
14.2. UN proper shipping name
Proper Shipping Name (ADR) : NITRATES, INORGANIC, N.O.S.
Proper Shipping Name (IMDG) : NITRATES, INORGANIC, N.O.S.
Proper Shipping Name (IATA) : Nitrates, inorganic, n.o.s.
Proper Shipping Name (ADN) : NITRATES, INORGANIC, N.O.S.
Proper Shipping Name (RID) : NITRATES, INORGANIC, N.O.S.
Transport document description (ADR) : UN 1477 NITRATES, INORGANIC, N.O.S.,
5.1, II, (E)
Transport document description (IMDG) : UN 1477 NITRATES, INORGANIC, N.O.S.,
5.1, II
Transport document description (IATA) : UN 1477 Nitrates, inorganic, n.o.s., 5.1, II
Transport document description (ADN) : UN 1477 NITRATES, INORGANIC, N.O.S.,
5.1, II 
Transport document description (RID) : UN 1477 NITRATES, INORGANIC, N.O.S.,
5.1, II
14.3. Transport hazard class(es)
ADR : Transport hazard class(es) (ADR) : 5.1
Danger labels (ADR) : 5.1
IMDG : Transport hazard class(es) (IMDG) : 5.1
Danger labels (IMDG) : 5.1
IATA : Transport hazard class(es) (IATA) : 5.1
Hazard labels (IATA) : 5.1
AND : Transport hazard class(es) (ADN) : 5.1
Danger labels (ADN) : 5.1
RID :Transport hazard class(es) (RID) : 5.1
Danger labels (RID) : 5.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : O2
Special provisions (ADR) : 511
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR) : T3
Portable tank and bulk container special
provisions (ADR) : TP33
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
 Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR) : V11
Special provisions for carriage - Loading,
unloading and handling (ADR) : CV24
Hazard identification number (Kemler No.) : 50
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 1Y
- Transport by sea
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B21, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : A
Segregation (IMDG) : SG38, SG49
Properties and observations (IMDG) : Solids. Solid mixtures with combustible material
are readily ignited and may burn
fiercely. Harmful if swallowed.
MFAG-No : 140
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y544
PCA limited quantity max net quantity
(IATA) : 2.5kg
PCA packing instructions (IATA) : 558
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 562
CAO max net quantity (IATA) : 25kg
Special provisions (IATA) : A3, A803
ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : O2
Special provisions (ADN) : 511
Limited quantities (ADN) : 1 kg
 Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : O2
Special provisions (RID) : 511
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID) : T3
Portable tank and bulk container special
provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID) : W11
Special provisions for carriage - Loading,
unloading and handling (RID) : CW24
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 50
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
ADR - Packing instructions : P001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and
E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ACETIC ACID,
UN N° : 2789
IMO-IMDG - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-C
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ACETIC ACID
UN N° : 2789
IATA - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 851
instruction
- Passenger and Cargo - Maximum : 1 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 855
- Cargo only - Maximum Quantity/ : 30 L
Packing
IATA - Limited Quantites : 0.5 L
ERG-Nr : 8F
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
BISMUTH NITRATE PENTAHYDRATE Extra Pure is not on the REACH Candidate
List
BISMUTH NITRATE PENTAHYDRATE Extra Pure is not on the REACH Annex XIV
List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water
(Classification according to 
AwSV; ID No. 2108)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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