BOILPLEX AT Hardness Control

 Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, GAndhidham, Kolkata, Chennai, Visakhapatnam, Fujairah, Muscat, Nairobi Kenya

Hazardous Components                                   CAS-No.                    Concentration
MORPHOLINE                                                110-91-8                      >=10-<15%
POTASSIUM HYDROXIDE                         1310-58-3                      >=1.5-<5%
INORGANIC SALT                             254504001-5294                      >=1-<1.5%
POTASSIUM COMPOUND                254504001-5137                      >=1-<1.5%
Mixed Polymer : Proprietory Blend

  
DANGER! MAY AFFECT THE CENTRAL NERVOUS SYSTEM CAUSING DIZZINESS,
HEADACHE OR NAUSEA. VAPOR MAY CAUSE TEMPORARY BLURRING OF VISION. MAY
BE HARMFUL. MAY CAUSE SEVERE BURNS OF RESPIRATORY AND DIGESTIVE TRACTS.
HARMFUL IF ABSORBED THROUGH THE SKIN. CAUSES SEVERE BURNS OF THE EYES
AND SKIN.
 
Potential Health Effects
 
Exposure routes
 Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion
 
Eye contact
 Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of
eyes. Can injure the cornea and cause blindness. Additional symptoms of eye exposure may include:
blurred vision halo vision (blurred vision around bright objects)
 
Skin contact Can cause permanent skin damage. Symptoms may include redness, burning, and swelling of skin, burns, and other skin damage. The feeling of irritation or burning may be delayed following skin  contact with potassium hydroxide solutions. Contact with mist or dust may cause multiple small skin burns. Passage of this material into the body through the skin is possible, and skin contact may be
harmful.
 
Ingestion
 Swallowing this material may be harmful or fatal. Symptoms may include severe stomach and
intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing
this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood
pressure and shock may occur as a result of severe tissue injury.
 
Inhalation
Breathing of vapor or mist is possible. Breathing this material may be harmful or fatal.
Symptoms may include severe irritation and burns to the nose, throat, and respiratory tract. Symptoms
are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).
 
Aggravated Medical Condition
 Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure
to this material:, Upper respiratory tract, Skin, lung (for example, asthma-like conditions), Liver, kidney,
eye  Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage
of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea),
thirst, irritation (nose, throat, airways), runny nose, Cough, central nervous system depression
(dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness), Weakness, Abdominal
pain, lung edema (fluid buildup in the lung tissue), kidney damage, liver damage, lung damage
 
Target Organs
 Overexposure to this material (or its components) has been suggested as a cause of the following
effects in laboratory animals:, nasal damage, eye damage, kidney damage, liver damage, lung damage
 
Carcinogenicity
 This material is not listed as a carcinogen by the International Agency for Research on Cancer
(IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration
(OSHA).
Reproductive hazard
 Based on the available information, risk to the fetus from maternal exposure to this material
cannot be assessed.
 
Other information
 Nitrites should not be added to this material because this can result in formation of nitrosamines.
Many nitrosamines cause cancer in laboratory animals.
 

Eyes
 If material gets into the eyes, immediately flush eyes gently with water for at least 15 minutes
while holding eyelids apart. If symptoms develop as a result of vapor exposure, immediately move
individual away from exposure and into fresh air before flushing as recommended above. Seek
immediate medical attention.
 
Skin
 Immediately flush skin with water for at least 15 minutes while removing contaminated clothing
and shoes. Seek immediate medical attention. Wash clothing before reuse and discard contaminated
shoes.
 
Ingestion
 Seek immediate medical attention. Do not induce vomiting. Vomiting will cause further
damage to the mouth and throat. If individual is conscious and alert, immediately rinse mouth with water
and give milk or water to drink. If possible, do not leave individual unattended. Inhalation
 If symptoms develop, immediately move individual away from exposure and into fresh air. Seek
immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial
respiration. If breathing is difficult, administer oxygen.
 
Notes to physician
 Hazards: Excessive levels of phosphorus can cause low blood calcium, with tetany and
convulsions.
 Treatment: No information available.
 

 Inhalation
 If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.
 
Notes to physician
 Hazards: Excessive levels of phosphorus can cause low blood calcium, with tetany and
convulsions.
 Treatment: No information available.
 

Personal precautions
 For personal protection see section 8. Persons not wearing protective equipment should be
excluded from area of spill until clean-up has been completed.
 
Environmental precautions
 No data
 
Methods for cleaning upPersons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. Neutralize and mop up solution.

Persons not wearing protective equipment should be excluded from area of spill until clean-up
has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage
tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. Neutralize and mop up solution.

 Exposure Guidelines
 
MORPHOLINE                                                           110-91-8

ACGIH                   time weighted average                     20 ppm
NIOSH                   Recommended exposure
                             limit (REL):                                     20 ppm
NIOSH                  Recommended exposure
                             limit (REL):                                     70 mg/m3
NIOSH                 Short term exposure limit                    30 ppm
NIOSH                 Short term exposure limit                   105 mg/m3
OSHA Z1              Permissible exposure limit                   20 ppm
OSHA Z1              Permissible exposure limit                  70 mg/m3
POTASSIUM HYDROXIDE                                         1310-58-3

ACGIH                 Ceiling Limit Value:                            2 mg/m3
NIOSH                 Recommended exposure
                            limit (REL):                                      2 mg/m3

General advice
 These recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect
exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately
the responsibility of the employer to follow regulatory guidelines established by local authorities.
 
Exposure controls
 Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure
below TLV(s).
 
Eye protection
 Chemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are
advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial
hygienist.) Contact lenses should not be worn.
 
Skin and body protection
 To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Other protective equipment: eyewash station, emergency shower.
Wear resistant gloves such as:
Neoprene
Nitrile rubber
Respiratory protection
 Exposures in the workplace should be monitored if worker exposure to vapor or mists exceeds
the PEL or TLV. Only a NIOSH-approved respirator and cartridge (TC-23C) is to be used. Monitoring
results must be used to assess the proper level of respiratory protection necessary (such as: full face
piece respirator with chemical cartridges or self-contained breathing apparatus { scuba} , etc.). Proper
engineering and/or administrative controls should be used to reduce worker exposure. The facility's
respiratory program must meet the requirements established in 29 CFR 1910.134, which includes a
program for medical evaluation.
 

 Stability
 Stable.
 
Conditions to avoid
 None known.
 
Incompatible productsAcids, halogenated hydrocarbons, Strong oxidizing agents, nitrites and other nitrosating agents, Metals, chlorinated solvents, This product should not be used in conjunction with trimethylol propane or trimethylol propane-derived products. There is a possibility that bicyclic phosphates or phosphites can be produced as a result of the thermal decomposition of this product in combination with trimethylol propane, trimethylol propane-derived products or their corresponding trimethylol propane alkane homologs. Bicyclic phosphates and phosphites are a class of materials with acute neurotoxic properties which produce characteristic convulsive seizures in test animals.
 
Hazardous decomposition products
 carbon dioxide and carbon monoxide, formaldehyde, nitrogen compounds, Oxides of
phosphorus, potassium oxide
 
Hazardous reactions
 Product will not undergo hazardous polymerization.
 
Thermal decomposition
 No data
 

 Acute oral toxicity
MORPHOLINE :                                                         no data available
 
POTASSIUM HYDROXIDE :                                       no data available
 
INORGANIC SALT :                                                   LD L0 Rat: 4,640 mg/kg
 
POTASSIUM COMPOUND :                                       no data available
 
 
Acute inhalation toxicity
MORPHOLINE :                                                         LC 50 Rat: 8000 ppm; 8 h
 
POTASSIUM HYDROXIDE :                                       no data available
 
INORGANIC SALT :                                                   no data available
 
POTASSIUM COMPOUND :                                        no data available
Acute dermal toxicity
MORPHOLINE :                                                          LD 50 Rabbit: 500 mg/kg
 
POTASSIUM HYDROXIDE :                                        LD 50 Rabbit: 1,260 mg/kg
 
INORGANIC SALT :                                                   LD 50 Rabbit: > 4,640 mg/kg
 
POTASSIUM COMPOUND :                                        no data available
 

SECTION 12

Biodegradability
MORPHOLINE :                                                                no data available
 
POTASSIUM HYDROXIDE :                                              no data available
 
INORGANIC SALT :                                                         no data available
 
POTASSIUM COMPOUND :                                              Not readily biodegradable.
 
 
Bioaccumulation
MORPHOLINE :                                                               no data available
 
POTASSIUM HYDROXIDE :                                             no data available
 
INORGANIC SALT :                                                         no data available
 
POTASSIUM COMPOUND :                                              no data availableEcotoxicity effects
 
Toxicity to fish
MORPHOLINE :                                                                no data available
 
POTASSIUM HYDROXIDE :                                          96 h LC 50 Western mosquitofish (Gambusia affinis):
80.00 mg/l Method: Static; MortalityINORGANIC SALT :      no data available
 
POTASSIUM COMPOUND :                                              no data available
 
 
Toxicity to daphnia and other aquatic invertebrates.
MORPHOLINE :                                                                no data available
 
POTASSIUM HYDROXIDE :                                              no data available
 
INORGANIC SALT :                                                          no data available
 
POTASSIUM COMPOUND :                                               no data available
 
 
Toxicity to algae
MORPHOLINE :                                                                 no data available
 
POTASSIUM HYDROXIDE :                                               no data available
 
INORGANIC SALT :                                                           no data available
 
POTASSIUM COMPOUND :                                                no data available

Toxicity to bacteria
MORPHOLINE :                                                                 no data available
 
POTASSIUM HYDROXIDE :                                               no data available
 
INORGANIC SALT :                                                           no data available
 
POTASSIUM COMPOUND :                                               no data available
 
 
Biochemical Oxygen Demand (BOD)
MORPHOLINE :                                                                no data available
 
POTASSIUM HYDROXIDE :                                              no data available
 
INORGANIC SALT :                                                          no data available

POTASSIUM COMPOUND :                                               no data available
 
 
Chemical Oxygen Demand (COD)
MORPHOLINE :                                                                 no data available
 
POTASSIUM HYDROXIDE :                                                no data available
 
INORGANIC SALT :                                                          no data available
 
POTASSIUM COMPOUND :                                               no data available
 
 
Additional ecological information
MORPHOLINE :                                                                 no data available
 
POTASSIUM HYDROXIDE :                                               no data available
 
INORGANIC SALT :                                                           no data available
 
POTASSIUM COMPOUND :                                                no data available
 

Waste disposal methods
 Dispose of in accordance with all applicable local, state and federal regulations. 

REGULATION

 U.S. DOT - ROAD

U.S. DOT - RAIL

 U.S. DOT - INLAND WATERWAYS 

 TRANSPORT CANADA - ROAD

 TRANSPORT CANADA - RAIL

TRANSPORT CANADA - INLAND WATERWAYS
 

INTERNATIONAL MARITIME DANGEROUS GOODS
 

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
 

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
 

MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES

*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

 
California Prop. 65
WARNING! This product contains a chemical known to the State            CADMIUM
of California to cause birth defects or other reproductive harm.                 LEAD

 
WARNING! This product contains a chemical known to the State             FORMALDEHYDE
of California to cause cancer.                                                                ARSENIC
                                                                                                          CADMIUM
 16. OTHER INFORMATION:
The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by
Ashland's Environmental Health and Safety Department (1-800-325-3751).

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.