Overview
Bromobenzene,99% is used as solvent in organic synthesis.
It is used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the .
Applications
BROMOBENZENE LR 99%, BROMOBENZENE used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the preparation of benzoic acid by reacting with carbon dioxide.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | BROMOBENZENE LR 99% | ||
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
2.1. Substance : BROMOBENZENE
CAS No : 108-86-1
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, H226
Category 3
Skin corrosion/irritation, H315
Category 2
Hazardous to the aquatic environment — Chronic Hazard, H411
Category 2
Classification according to Directive 67/548/EEC or 1999/45/EC
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : Xi : Irritation
Highly flammable
R Phrase(s) : R10: Flammable.
R38: Irritating to skin.
S Phrase(s) : S61: avoid release to the environment . refer to special instruction/safety
data sheets.
Hazard pictograms
Signal word : Warning
Hazard statements : H226 - Flammable liquid and vapour
H315 - Causes skin irritation
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P273 - Avoid release to the environment
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water. If skin
irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation
persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek
medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after skin contact : Causes skin irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric
charges. No naked lights. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable
containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual
vapours are flammable.
Precautions for safe handling : No naked lights. No smoking. Take precautionary
measures against static discharge. Use only non-sparking tools.
Hygiene measures : Wash ... thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be
followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting/… equipment.
Storage conditions : Keep container tightly closed. Store in original container. Store in a
dry place. Incompatible materials : Heat sources.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -31 °C
Freezing point : No data available
Boiling point : 154 - 155
Flash point : 51 °C
Auto-ignition temperature : 566 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Flammable liquid and vapour
Vapour pressure : 5.3 hPa at 25,0 °C
Relative vapour density at 20 °C : 5.41
Relative density : No data available
Density : 1.5 g/cm³
Solubility : Water: Insoluble
Log Pow : 2.99
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.06 - 0.365 vol %
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Open flame. Overheating. Direct sunlight. Heat. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
May release flammable gases.
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
12.1. Toxicity
Ecology - water : Toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
Persistence and degradability May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Log Pow 2.99
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to ...
Additional information : Handle empty containers with care because residual vapours are
flammable.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2514
UN-No. (IMDG) : 2514
UN-No.(IATA) : 2514
UN-No.(ADN) : 2514
UN-No. (RID) : 2514
14.2. UN proper shipping name
Proper Shipping Name (ADR) : BROMOBENZENE
Proper Shipping Name (IMDG) : BROMOBENZENE
Proper Shipping Name (IATA) : BROMOBENZENE
Proper Shipping Name (ADN) : BROMOBENZENE
Proper Shipping Name (RID) : BROMOBENZENE
Transport document description (ADR) : UN 2514 BROMOBENZENE, 3, III, (D/E),
ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2514 BROMOBENZENE, 3, III,
MARINE POLLUTANT/ENVIRONMENTALLY
HAZARDOUS (51°C c.c.)
Transport document description (IATA) : UN 2514 BROMOBENZENE, 3, III,
ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2514 BROMOBENZENE, 3, III,
ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2514 BROMOBENZENE, 3, III,
ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 3
Danger labels (ADR) : 3
IMDG- Transport hazard class(es) (IMDG) : 3
Danger labels (IMDG) : 3
IATA- Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
ADN- Transport hazard class(es) (ADN) : 3
Danger labels (ADN) : 3
RID- Transport hazard class(es) (RID) : 3
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Limited quantities (ADR) : 5L
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR) : T2
Portable tank and bulk container special
provisions (ADR) : TP1
Tank code (ADR) : LGBF
Vehicle for tank carriage : FL
Transport category (ADR) : 3
Special provisions for carriage – Packages (ADR) : V12
Special provisions for carriage – Operation (ADR) : S2
Hazard identification number (Kemler No.) : 30
Orange plates : Tunnel restriction code (ADR) : D/E
EAC code : 2Y
Transport by sea
Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Flash point (IMDG) : 51°C c.c.
MFAG-No : 130
Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity (IATA) : 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
ERG code (IATA) : 3L
Inland waterway transport
Classification code (ADN) : F1
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 0
Rail transport
Classification code (RID) : F1
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID) : T2
Portable tank and bulk container special
provisions (RID) : TP1
Tank codes for RID tanks (RID) : LGBF
Transport category (RID) : 3
Special provisions for carriage – Packages (RID) : W12
Colis express (express parcels) (RID) : CE4
Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
BROMOBENZENE is not on the REACH Candidate List
BROMOBENZENE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10; Emergency management guidelines for the storage of
flammable liquids must be followed
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
[BROMOBENZENE LR 99] manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
[BROMOBENZENE LR 99] is available in small packing as well as in bulk. Buy premium quality [BROMOBENZENE LR 99] and other lab chemicals from one of the most trusted brands.
