Benzyl Chloride
- Part number
- RXSOL-19-1239-250
- Category
- Solvent Chemicals
- Brand
- RXSOL
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Benzyl Chloride |
| Part Number | RXSOL-19-1239-250 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
Substances
| Formula | C7H7Cl |
| Molecular weight | 126,58 g/mol |
| CAS-No. | 100-44-7 |
| EC-No. | 202-853-6 |
| Index-No. | 602-037-00-3 |
| Component | Classification | Concentration |
| Benzyl chloride | ||
|
CAS-No. 100-44-7
EC-No 202-853-6
Index-No. 602-037-00-3
|
Acute Tox. 4; Acute Tox.
3; Skin Irrit. 2; Eye Dam.
1; Skin Sens. 1; Carc. 1B;
STOT SE 3; STOT RE 2;
H302, H331, H315, H318,
H317, H350, H335, H373
|
<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Acute toxicity, (Category 4) | H302: Harmful if swallowed. |
| Acute toxicity, (Category 3) | H331: Toxic if inhaled. |
| Skin irritation, (Category 2) | H315: Causes skin irritation. |
| Serious eye damage, (Category 1) | H318: Causes serious eye damage. |
| Skin sensitization, (Category 1) | H317: May cause an allergic skin reaction. |
| Carcinogenicity, (Category 1B) | H350: May cause cancer. |
|
Specific target organ toxicity -
single exposure, (Category 3),
Respiratory system
|
H335: May cause respiratory irritation. |
|
Specific target organ toxicity -
repeated exposure, (Category 2),
Heart, forestomach
|
H373: May cause damage to organs
through prolonged or repeated exposure if
swallowed.
|
Label elements
| Signal Word | Danger |
|
Hazard Statements |
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H373 May cause damage to organs (Heart, forestomach) through prolonged or repeated exposure if swallowed.
|
|
Precautionary Statements |
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (<= 125 ml) | |
| Signal Word | Danger |
| Hazard statement(s) |
H331 Toxic if inhaled.
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H318 Causes serious eye damage.
|
| Precautionary statement(s) |
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
Description of first aid measures
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
Extinguishing media
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Hydrogen chloride gas
Combustible.
Fire may cause evolution of:
Hydrogen chloride gas, Phosgene
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
|
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information |
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
|
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Environmental precautions | Do not let product enter drains. |
| Methods and materials for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
|
| Conditions for safe storage, including any incompatibilities | |
| Storage conditions |
Tightly closed and away from sources of ignition and heat. Observe national regulations.
Air and moisture sensitive.
|
| Storage class | Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Chloroprene
Minimum layer thickness: 0,65 mm
Break through time: 480 min
Material tested:KCL 720 Camapren®
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN 16523-1 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Latex gloves
Minimum layer thickness: 0,6 mm
Break through time: 60 min
Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M). |
| Body Protection | Protective clothing |
| Respiratory protection |
Required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type P3
The entre peneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Liquid |
| Colour | Colorless |
| Odor | Stinging |
| Melting point/freezing point | Melting point: -41,2 °C |
| Initial boiling point and boiling range | 179,3 °C at 1.013 hPa |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 14 %(V)
Lower explosion limit: 1,1 %(V)
|
| Flash point | 67 °C - closed cup - c.c. |
| Autoignition temperature |
585 °C
at 1.013 hPa
|
| Decomposition temperature | No data available |
| pH | Not applicable |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | 0,46 g/l at 30 °C |
| Partition coefficient: n-octanol/water | log Pow: 2,3 - (IUCLID), Bioaccumulation is not expected. |
| Vapor pressure | 1,6 hPa at 25 °C |
| Density | 1,10 g/cm3 at 20 °C |
| Relative density | 1,1 at 20 °C |
| Relative vapor density | 4,36 |
| Particle characteristics | No data available |
| Explosive properties | Not classified as explosive |
| Oxidizing properties | None |
| Other safety information | |
| Relative vapor density | 4,36 |
| Reactivity |
Forms explosive mixtures with air on intense heating.
A range from approx. 15 Kelvin below the flash point is to be rated as critical.
|
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions |
Violent reactions possible with:
Strong oxidizing agents
amides
substances with a catalytic effect
numerous inorganic and/or organic compounds
Risk of explosion with:
polymerisation initiators
Acids
A risk of explosion and/or of toxic gas formation exists with the following substances:
Alkali metals
Alkaline earth metals
Metals
Exothermic reaction with:
Water
Release of:
Hydrogen chloride gas
|
| Conditions to avoid | Strong heating. |
| Incompatible materials |
No data available
|
| Hazardous decomposition products | In the event of fire: see section 5 |
Information on toxicological effects
| Acute toxicity |
LD50 Oral - Rat - male and female - 560 mg/kg
(OECD Test Guideline 401)
Symptoms: Possible damages:, Bloody vomiting
Acute toxicity estimate Oral - 560 mg/kg
(ATE value derived from LD50/LC50 value)
Acute toxicity estimate Inhalation - 4 h - 5 mg/l - vapor
(Expert judgment)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Symptoms: Cough, Shortness of breath, mucosal irritations, Possible damages:, damage of
respiratory tract, Lung edema, Symptoms may be delayed.
Dermal: No data available
|
| Skin corrosion/irritation |
Remarks: Causes skin irritation.
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Serious eye damage/eye irritation |
Remarks: Lacrimal irritation due to vapours.
Remarks: Causes serious eye damage.
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Respiratory or skin sensitization |
Local lymph node assay (LLNA) - Mouse
Result: positive
(OECD Test Guideline 429)
|
| Germ cell mutagenicity |
Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: positive
|
| Carcinogenicity | Presumed to have carcinogenic potential for humans |
| Reproductive toxicity |
No data available
|
| Specific target organ toxicity - single exposure |
Inhalation - May cause respiratory irritation. - Respiratory system
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Specific target organ toxicity - repeated exposure |
Oral - May cause damage to organs through prolonged or repeated exposure.
- Heart, forestomach
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Aspiration hazard | No data available |
| Additional Information | |
|
Endocrine disrupting properties
Product
|
|
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
RTECS: NC3675000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
|
| Toxicity | |
| Toxicity to fish |
Semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 1,78 mg/l - 96 h
(OECD Test Guideline 203)
|
|
Toxicity to daphnia
and other aquatic
invertebrates
|
Semi-static test EC50 - Daphnia magna (Water flea) - 1,1 mg/l - 48 h
(OECD Test Guideline 202)
|
| Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata - 0,21 mg/l - 72 h
(OECD Test Guideline 201)
Static test EC10 - Raphidocelis subcapitata (freshwater green alga) - 0,075 mg/l - 72 h
(OECD Test Guideline 201)
|
| Persistence and degradability | The methods for determining biodegradability are not applicable to inorganic substances. |
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available . |
| Waste treatment Method | No data available |
| UN number | ADR/RID:1738 IMDG:1738 IATA: 1738 |
| UN proper shipping name |
ADR/RID: BENZYL CHLORIDE
IMDG: BENZYL CHLORIDE
IATA: Benzyl chloride
|
| Transport hazard class(es) | ADR/RID: 6.1 (8) IMDG: 6.1 (8) IATA:6.1 (8) |
| Packaging group | ADR/RID: lI IMDG: II IATA:II |
| Environmental hazards | ADR/RID: no IMDG Marine pollutant: no IATA: no |
| Special precautions for user | |
| Tunnel restriction code | (D/E) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Authorisations and/or restrictions on use | |
|
National legislation
Seveso III: Directive 2012/18/EU of the
European Parliament and of the Council
on the control of major-accident hazards
involving dangerous substances.
|
E1 ENVIRONMENTAL HAZARDS |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
