CALCIUM OXIDE LUMPS LR

2.1. Substances : CALCIUM NITRATE AR

CAS-No. : 13477-34-4

Substance.

Contains no other components or impurities which will influence the classification of the

product.

3.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Oxidising Solids, H272

Category 3

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

O; Xi; R8

Adverse physicochemical, human health and environmental effects

No additional information available

3.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to

displayExtra classification(s) to display

Symbol(s) : O : Oxidizing

Xi : Irritation.

R Phrase(s) : R8: Contact with combustible material may cause fire.

R36/38: Irritating to eyes and skin.

S Phrase(s) : S17: Keep away from combustible material.

S26: In the case of contact with eyes, rinse immediately with plenty of water and seek

medical advise.

S36: Wear suitable protective clothing.

Hazard pictograms

Signal word : Warning

Hazard statements : H272 - May intensify fire; oxidiser.

Precautionary statements : P220 - Keep/Store away from clothing and other

combustible materials.

3.3. Other hazards

No additional information available

4.1. Description of first aid measures

First-aid measures after inhalation : Assure fresh air breathing. If breathing is difficult,

remove victim to fresh air and keep at rest in a position comfortable for breathing.

First-aid measures after skin contact : Wash with plenty of water/…. Remove affected

clothing and wash all exposed skin area with mild soap and water, followed by warm

water rinse. Get medical advice/attention.

First-aid measures after eye contact : Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Get medical

advice/attention.

First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed

No additional information available

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. 

5.1. Extinguishing media

Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Do not enter fire area without proper protective

equipment, including respiratory protection.

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous

earth as soon as possible. On land, sweep or shovel into suitable containers.

6.4. Reference to other sections

No additional information available

9.1. Information on basic physical and chemical properties

Odour threshold : No data available

pH : 5.5 - 7

Relative evaporation rate (butylacetate=1) : No data available

Melting point : 44 °C

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : No data available

Density : 1.86 g/cm³

Solubility : Water: 121 g/100ml

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : No data available

9.2. Other information

No additional information available

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

pH: 5.5 - 7

Serious eye damage/irritation : Not classified

pH: 5.5 - 7

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

12.1. Toxicity

No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

13.1. Waste treatment methods

No additional information available

15.1. Safety, health and environmental regulations/legislation specific for the

substance or mixture

15.1.1. EU-Regulations

No REACH Annex XVII restrictions

CALCIUM NITRATE TETRAHYDRATE AR/ACS is not on the REACH Candidate

List

CALCIUM NITRATE TETRAHYDRATE AR/ACS is not on the REACH Annex XIV

List

15.1.2. National regulations

Germany

12th Ordinance Implementing the Federal

Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous

Incident Ordinance)

Netherlands

SZW-lijst van kankerverwekkende stoffen : The substance is not listed

SZW-lijst van mutagene stoffen : The substance is not listed

NIET-limitatieve lijst van voor de

voortplanting giftige stoffen – Borstvoeding : The substance is not listed

NIET-limitatieve lijst van voor de

voortplanting giftige stoffen – Vruchtbaarheid : The substance is not listed

NIET-limitatieve lijst van voor de

voortplanting giftige stoffen – Ontwikkeling : The substance is not listed

15.2. Chemical safety assessment

No additional information available

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN

PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,

labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006

Further information : None.

In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation

(CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.