CARBOLIC ACID
Phenol is organic colourless to white solid compound
- Part number
- RXSOL-19-1910-225
- Category
- Paint and Cleaning solvent
- Brand
- RXSOL
Overview
Phenol is stable chemical substance and appears as colourless white crystals with charcterstic, distinct aromatic odour. It is reactive and incomapatible with strong oxidizing agent, strong base, strong acid, alkalis and calcium hypochlorite. phenol is flammable and may colour with light.
Technical specifications
Physical Properties:
| Melting Point | 40-42 °C(lit.) |
| Boiling Point | 182 °C(lit.) |
| Density | 1.071 g/mL at 25 °C(lit.) |
| Vapour density | 3.24 (vs air) |
| Vapour pressure | 0.09 psi ( 55 °C) |
| Refractive index |
n |
| Flash point | 175 °F |
| Storage temprature | 2-8°C |
| Solublity | H2O: 50 mg/mL at 20 °C, clear, colorless |
| Form | Liquid |
| pKa | 9.89(at 20℃) |
| Specific gravity | 1.071 |
| Colour | Faintly yellow |
| PH | 6.47(1 mM solution);5.99(10 mM solution);5.49(100 mM solution); |
| Odour | Sweet mediclinal odour detectable at 0.006 ppm |
| Explosive limt | 1.3-9.5%(V) |
| Sensitive | Air and light sensitve |
| Water solublity | 8 g/100 mL |
| 2-8°C |
Applications
phenol is used in the manufacture or production of explosive, fertilizer, cokes,illuminating gas,lamblack,paints, paint remover, rubber, perfumes,asbestos goods, wood preservative, synthetic resin, textiles, drug and pharmaceutical prepration.It is also extensively used as a disinfectant in the petroelum,leather, paper, soap, toy, tunning, dye and agricultural industries.
Characteristics and notes
Applications:
- The predominant use of phenol today is for phenolic resins.it is a powerful bactericide,phenol can be found in numerous consumer products includingmouthwashes,antiseptic ointments,throat lozenges,air fresheners,eardrops,and lipbalms.
- Phenol continues to be a primary chemical used to make thermoset resins.These resinsare made by combining phenol with aldehydes such as formaldehyde.More than 4 billionpounds of phenolic resins are used annually in the United States.Phenolic resins findtheir widest use in the construction industry.
- They are used as binding agents and fillers inwood products such as plywood,particleboard,furniture, and paneling.Phenolic resins areimpregnated into paper,which,after hardening,produces sheets that can be glued togetherto form laminates for use in wall paneling and countertops.Decking in boats and docksare made from phenolic resin composites.
- Phenolic resins are used as sealing agents andfor insulation. Because phenolic resins have high heat resistance and are good insulators,they are used in cookware handles.Because they are also good electrical insulators,they areused in electrical switches,wall plates, and for various other electrical applications.In theautomotive industry,phenolic resins are used for parts such as drive pulleys,water pumphousings, brakes,and body parts.
- In addition to the construction industry,phenol has many other applications.It isused in pharmaceuticals,in herbicides and pesticides,and as a germicide in paints
- .It can beused to produce caprolactam,which is the monomer used in the production of nylon 6.Another important industrial compound produced from phenol is bisphenol A,which ismade from phenol and acetone.
- Bisphenol A is used in the manufacture ofpolycarbonateresins.Polycarbonate resins are manufactured into structural parts used in the manufactureof various products such as automobile parts,electrical products,and consumer appliances.Items such as compact discs, reading glasses,sunglasses,and water bottles are made frompolycarbonates.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Porduct Name | CARBOLIC ACID |
| Part Number | RXSOL-19-1910-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Chemical Name | Cas No | EC No | Whight | Formula |
| Hydroxybenzene | 108-95-2 | 203-632-7 | 94,11 g/mol | C6H6O |
| Component | Classification | Concentration |
| Phenol | ||
|
CAS-No. 108-95-2
EC-No. 203-632-7
Index-No. 604-001-00-2
|
Acute Tox. 3; Skin Corr.
1B; Eye Dam. 1; Muta. 2;
STOT RE 2; Aquatic
Chronic 2; H301, H331,
H311, H314, H318, H341,
H373, H411
Concentration limits:
>= 3 %: Skin Corr. 1B,
H314; 1 - < 3 %: Skin
Irrit. 2, H315; 1 - < 3 %:
Eye Irrit. 2, H319;
|
<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Classification according to Regulation (EC) No 1272/2008 |
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Sub-category 1B), H314
Serious eye damage (Category 1), H318
Germ cell mutagenicity (Category 2), H341
Specific target organ toxicity - repeated exposure (Category 2), Nervous system, Kidney,
Liver, Skin, H373
Long-term (chronic) aquatic hazard (Category 2), H411
For the full text of the H-Statements mentioned in this Section, see Section 16.
|
Labelling according Regulation (EC) No 1272/2008
| Signal Word | Danger |
| Hazard Statements |
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H341 Suspected of causing genetic defects.
H373 May cause damage to organs (Nervous system, Kidney, Liver,
Skin) through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
|
| Precautionary Statements |
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
|
| Supplemental Hazard Statements | None |
Reduced Labeling (<= 125 ml)
| Signal Word | Danger |
| Hazard Statements |
H341 Suspected of causing genetic defects.
H314 Causes severe skin burns and eye damage.
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
|
| Precautionary Statements |
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Vesicant., Rapidly absorbed through skin.
|
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| In case of skin contact | After contact with skin: rinse out with polyethylene glycol 400 or a mixture of polyethylene glycol 300/ethanol 2:1 and wash with plenty of water. If neither is available wash with plenty of water. Immediately take off contaminated clothing. Call a physician immediately. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| If swallowed | If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air on intense heating.
Development of hazardous combustion gases or vapours possible in the event of fire.
|
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
| Methods and materials for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Storage conditions | Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. |
| Storage stability |
Recommended storage temperature
2 - 8 °C
Handle and store under inert gas. Light sensitive.
|
| Storage class | Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Ingredients with workplace control parameters
Derived No Effect Level (DNEL)
| Application Area | Routes of exposure | Health effect | Value |
|
Worker DNEL,
longterm
|
inhalation |
Systemic effects | 8 mg/m3 |
|
Worker DNEL,
longterm
|
dermal | Systemic effects |
Predicted No Effect Concentration (PNEC)
| Compartment | Value |
| Fresh water | 0,0077 mg/l |
| Sea water | 0,00077 mg/l |
| Fresh water sediment | 0,0915 mg/kg |
| Sea sediment | 0,00915 mg/kg |
| Soil | 0,136 mg/kg |
| Sewage treatment plant | 2,1 mg/l |
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Viton®
Minimum layer thickness: 0,7 mm
Break through time: 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Viton®
Minimum layer thickness: 0,7 mm
Break through time: 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
|
| Body Protection | Flame retardant antistatic protective clothing. |
| Respiratory protection |
Recommended Filter type: Filter A-(P3)
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. |
| Physical state | Solid |
| Colour | No data available |
| Odour | Stinging |
| Melting point/freezing point | Melting point/range: 38 - 43 °C |
| Initial boiling point and boiling range | 181,8 °C at 1.013 hPa |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 9,5 %(V)
Lower explosion limit: 1,3 %(V)
|
| Flash point | 79,0 °C - closed cup |
| Autoignition temperature |
715 °C
at 1.013 hPa
|
| Decomposition temperature | No data available |
| pH | 6,0 |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: 3,437 Pas at 50,00 °C
|
| Water solubility | 87 g/l at 25 °C |
| Partition coefficient: n-octanol/water | log Pow: 1,47 at 30 °C - (ECHA), Bioaccumulation is not expected. |
| Vapor pressure | 0,53 hPa at 20,0 °C |
| Density | 1,13 g/cm3 at 25 °C - DIN 51757 |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | No data available |
| Reactivity | Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed. |
| Chemical stability |
The product is chemically stable under standard ambient conditions (room temperature) .
Contains the following stabilizer(s):
Hypophosphorous acid (0,15 %)
|
| Possibility of hazardous reactions |
Exothermic reaction with:
Aluminum
Aldehydes
halogens
hydrogen peroxide
iron(III) compounds
Oxidizing agents
Strong acids
Strong bases
formaldehyde
Risk of explosion with:
nitrites
nitrates
salts of oxyhalogenic acids
peroxi compounds
|
| Conditions to avoid | Strong heating. |
| Incompatible materials |
Rubber, various plastics, various alloys, various metals
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity |
Acute toxicity estimate Oral - 100,1 mg/kg
(Calculation method)
Acute toxicity estimate Oral - 100,1 mg/kg
(Expert judgment)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Acute toxicity estimate Inhalation - 4 h - 0,51 mg/l - dust/mist(Calculation method)
Acute toxicity estimate Inhalation - 4 h - 0,51 mg/l - dust/mist
(Expert judgment)
Symptoms: Irritation, Lung edema
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Acute toxicity estimate Dermal - 660 mg/kg
(Calculation method)
LD50 Dermal - Rat - female - 660 mg/kg
(OECD Test Guideline 402)
Acute toxicity estimate Dermal - 660 mg/kg
(Calculation method)
|
| Skin corrosion/irritation |
Skin - In vitro study
Result: Causes burns.
(OECD Test Guideline 431)
|
| Serious eye damage/irritation |
Eyes - Rabbit
Result: Corrosive
(OECD Test Guideline 405)
Remarks: Causes serious eye damage.
Risk of blindness!
|
| Respiratory or skin sensitization |
Sensitisation test: - Guinea pig
Result: negative
Remarks: (IUCLID)
|
| Carcinogenicity | This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. |
| Germ cell mutagenicity |
Suspected of causing genetic defects.
Test Type: Mutagenicity (mammal cell test): chromosome aberration.
Test system: Chinese hamster ovary cells
Metabolic activation: Metabolic activation
Method: OECD Test Guideline 473
Result: positive
Test Type: Mutagenicity (mammal cell test): micronucleus.
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 487
Result: positive
|
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Specific target organ toxicity - repeated exposure | May cause damage to organs through prolonged or repeated exposure. - Nervous system, Kidney, Liver, Skin Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Aspiration hazard | No data available |
| Additional Information |
Product:
Assessment : The substance/mixture does not contain
components considered to have endocrine
disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU)
2018/605 at levels of 0.1% or higher.
Material is extremely destructive to tissue of the mucous membranes and upper respiratory
tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation
and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough,
wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Circulatory
collapse, tachypnea, paralysis, Convulsions, Coma., necrosis of mouth and G.I. Tract,
Jaundice, respiratory failure, cardiac arrest
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
|
Toxicity
| Toxicity to fish | Flow-through test LC50 - Onchorhynchus clarki - 8,9 mg/l - 96 h (US-EPA) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Ceriodaphnia dubia (water flea) - 3,1 mg/l - 48 h (US-EPA) |
| Toxicity to algae | Static test EC50 - Pseudokirchneriella subcapitata (algae) - 61,1 mg/l - 96 h (US-EPA) |
| Toxicity to bacteria | Static test IC50 - microorganisms - 21 mg/l - 24 h Remarks: (ECHA) |
| Toxicity to fish(Chronic toxicity) | Semi-static test NOEC - Fish - 0,077 mg/l - 60 d Remarks: (ECHA) |
| Toxicity to daphnia and other aquatic invertebrates(Chronic toxicity) | Semi-static test NOEC - Daphnia magna (Water flea) - 0,16 mg/l - 16 d Remarks: (ECHA) |
| Persistence and degradability |
Biodegradability aerobic - Exposure time 100 h
Result: 62 % - Readily biodegradable.
(OECD Test Guideline 301C)
|
| Bioaccumulative potential |
Bioaccumulation Danio rerio (zebra fish) - 5 h
at 25 °C - 2 mg/l(Phenol)
Bioconcentration factor (BCF): 17,5
(OECD Test Guideline 305)
Remarks: Does not bioaccumulate.
|
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties |
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission
Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
| Other adverse effects | No data available |
| Waste treatment Methods |
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
|
| UN number | ADR/RID: 1671 IMDG: 1671 IATA: 1671 |
| UN proper shipping name | ADR/RID: PHENOL, SOLID IMDG:PHENOL, SOLID IATA:PHENOL, SOLID |
| Transport hazard class(es) | ADR/RID: 6.1 IMDG: 6.1 IATA:6.1 |
| Packaging group | ADR/RID: II IMDG: II IATA : II |
| Environmental hazards | ADR/RID: Yes IMDG Marine pollutant : Yes IATA: No |
| Special precautions for user |
Tunnel restriction code : (D/E)
Further information : No data available
|
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| National legislation |
Seveso III: Directive 2012/18/EU of the European : ACUTE TOXIC
Parliament and of the Council on the control of
major-accident hazards involving dangerous
substances.
: ENVIRONMENTAL HAZARDS
|
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment has been carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if RX Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
