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Lab Chemical

CYCLOHEXANE AR

Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are precursors to nylon.
Part number
RXSOL-60-6604-388
Category
Lab Chemical
Brand
RXSOL
RXSOL

Overview

Cyclohexane is a non-polar organic colourless solvent. Cyclohexane is a colorless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are precursors to nylon.

Applications

Cyclohexane is a colorless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are precursors to nylon.

Dosage and directions

Most cyclohexane goes into the production of intermediates for nylon, which has a variety of common applications such as clothing, tents and carpets as well as thermoplastics. Cyclohexane is also used as a solvent in chemical and industrial processes and recently has been substituted for benzene in many applications.

Characteristics and notes

On sugars and conformations. Quote from my friend Jon, who is much more knowledgable than myself about these matters:

“In double helices – B–DNA (the classic double helix) basically has sugars with a south pucker. Double-stranded RNA, and also A-DNA (found in other sequences/conditions) basically has sugars with a north pucker.

Interestingly, kinases that are needed to activate nucleoside drugs (AZT and many others) recognize the puckers and so the pucker of a nucleoside can be key to allowing it to be activated as the triphosphate and incorporated into DNA. Victor Marquez of the NCI (NIH) is the authority in this area of nucleoside conformations and their biological activity.”

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product CODE RXSOL-60-6604-388
Product Name CYCLOHEXANE AR

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
Substance / Preparation : Cyclohexane
CAS No :110-82-7
Substance.
Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : F; R11
Xn; R65
R67
Xi; R38
N; R50-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Specific Target Organ Toxicity - Single exposure - Narcotic effects
- Category 3 - Warning (CLP : STOT SE 3) H336
Aspiration hazard - Category 1 - Danger (CLP : Asp. Tox. 1) H304
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225
Environmental hazards : Hazardous to the aquatic environment - Acute hazard -
Category 1 - Warning (CLP : Aquatic Acute 1) H400
Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning(
CLP : Aquatic Chronic 1) H410
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F : Highly flammable
Xn : Harmful
N : Dangerous for the environment
R Phrase(s) : R11 : Highly flammable.
R38 : Irritating to skin.
R65 : Harmful :may cause lung damage if swallowed.
R67 : Vapours may cause drowsiness and dizziness.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
S Phrase(s) : S2 : Keep out of the reach of children.
S9 : Keep container in a well-ventilated place.
S16 : Keep away from sources of ignition - No smoking.
S25 : Avoid contact with eyes.
S33 : Take precautionary measures against static discharges.
S51 : Use only in well-ventilated areas.
S60 : This material and its container must be disposed of as hazardous waste.
S61 : Avoid release to the environment. Refer to special instructions/Safety data
sheets
. S62 : If swallowed, do not induce vomiting : seek medical advice immediately and
show this container or label.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms 
Signal words : Danger
Hazard statements : H225 : Highly flammable liquid and vapour.
H304 : May be fatal if swallowed and enters airways.
H315 : Causes skin irritation.
H336 : May cause drowsiness or dizziness.
H410 : Very toxic to aquatic life with long lasting effects.
Precautionary statements
• General : P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P273: Avoid release to the environment.
P233: Keep container tightly closed.
P264: Wash thoroughly after handling.
• Response : P301+P310: IF SWALLOWED : Immediately call a POISON CENTER or
doctor.
P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P332+P313: If skin irritation occurs : Get medical advice.
P391: Collect spillage.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated
clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P403+P235: Store in well-ventilated place. Keep cool.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor if you feel unwell.
Skin contact : Wash contaminated clothing before reuse. Remove/Take off immediately
all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs
: Specific treatment (see on this label). Get medical advice.
Eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain,
blinking or redness persist.Ingestion : Immediately call a POISON CENTER or doctor. Do NOT induce vomiting.
Rinse mouth.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : May be fatal if swallowed and enters airways.
Causes skin irritation. May cause drowsiness or dizziness.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible)
 
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Highly flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present
. 5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment. 
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area. Avoid breathing dust, fume, gas, mist, vapours, spray.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours are flammable.
Wash thoroughly after handling. Use only outdoors or in a well-ventilated area.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed. Use explosion-proof electrical, ventilating, lighting, …, equipment.
Special precautions : No naked lights. No smoking.
Avoid breathing dust, fume, gas, mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep in
fireproof place. Ground/bond container and receiving equipment. Keep container tightly
closed.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources. 7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Where exposure through inhalation may occur from use
, respiratory protection equipment is recommended. Wear respiratory protection
. • Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available
. pH value : No data available.
Melting point [°C] : 4 - 7 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 260 °C
Flammability (solid, gas) : Highly flammable liquid and vapour. Extremely flammable.
Flash point [°C] : (-18 )°C
Boiling point [°C] : 80.7 °C
Initial boiling point [°C] : N/A
boiling point [°C] : N/A
Evaporation rate : 2,6
Vapour pressure [20°C] : 102.7 hPa at 20°C
Vapour pressure mm/Hg : N/A
Vapour density : N/A
Density [g/cm3] : 0,779
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Insoluble.
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : 9%
Explosion limits - lower [%] : 1%
Oxidising properties : No data available.
 
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
May release flammable gases
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : May be fatal if swallowed and enters airways
• Dermal : Based on available data, the classification criteria are not met
. • Ingestion : May be fatal if swallowed and enters airways
. Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes skin irritation. Sensitization : Based on available data, the classification criteria are not met. Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : May cause drowsiness or dizziness.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : May be fatal if swallowed and enters airways.
12.1. Toxicity
Toxicity information : Very toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soi
l Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment. 
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
Special precautions : Handle empty containers with care because residual vapours are
flammable. Hazardous waste due to toxicity.
14.1. Land transport (ADR-RID)
Proper shipping name : CYCLOHEXANE
UN N° : 1145
H.I. nr : 33
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid
. ADR - Classification code : F1
ADR - Group : II
ADR - Packing instructions : P001 R001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : CYCLOHEXANE
UN N° : 1145
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001 IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-E S-D
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : CYCLOHEXANE
UN N° : 1145
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 353
instruction
- Passenger and Cargo - Maximum : 5 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 364
- Cargo only - Maximum Quantity/ : 60 L
Packing
IATA - Limited Quantites : 1 L
ERG-Nr : 3H
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : Annex XVII With the exception of those listed
below: The components of this product are not subject to restrictions
. REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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