DI BUTYL PHTHALATE FOR SYNTHESIS 99% DBP

2.1. Substances : DIBUTYL PHTHALATE FOR SYNTHESIS

CAS-No. : 84-74-2

Substance. Contains no other components or impurities which will influence the classification of the product.  

3.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Reproductive toxicity, H360Df Category 1A Hazardous to the aquatic environment — Acute Hazard,H400

Category 1

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Adverse physicochemical, human health and environmental effects

No additional information available

3.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Extra labelling to displayExtra classification(s) to display

Symbol(s) : T : Very toxic 

N : Dangerous for the environment     

R Phrase(s) : R50:  Very toxic to aquatic organisms.

R61: May cause harm to unborn child.

R62: Possible risk of impaired fertility. 

S Phrase(s) : S45: In case of accident or if you feel unwell,

seek medical advice immediately (show the label where possible).

S53:  Avoid exposure – obtain special instruction before use.

S61:  avoid release to the environment .

refer to special instruction/safety data sheets.   

Hazard pictograms  :   Signal word

  : Danger Hazard statements  : H360Df -

May damage the unborn child. Suspected of damaging fertility. H400 -

Very toxic to aquatic life. Precautionary statements : P201 -

Obtain special instructions before use. P273 -

Avoid release to the environment. P308+P313 -

IF exposed or concerned: Get medical advice/attention.

3.3. Other hazards This substance/mixture does not meet the PBT

criteria of REACH regulation, annex XIII This substance/mixture

does not meet the vPvB criteria of REACH regulation, annex XIII 

4.1. Description of first aid measures

First-aid measures general : IF exposed or concerned: Get medical advice/attention.

First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.

First-aid measures after skin contact : Wash with plenty of water/…. Get immediate medical advice/attention.

First-aid measures after eye contact : Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.

First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/effects : Suspected of damaging fertility. May damage the unborn child. 

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. 

5.1. Extinguishing media

Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Do not enter fire area without proper

protective equipment, including respiratory protection. 

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.

6.4. Reference to other sections

No additional information available 

9.1. Information on basic physical and chemical properties

Odour threshold : No data available

pH : No data available

Relative evaporation rate

(butylacetate=1) : No data available

Melting point : -35 °C

Freezing point : No data available

Boiling point : 340 °C

Flash point : 171 °C

Auto-ignition temperature : 402 °C

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : < 0.01 @20°C

Relative vapour density at 20 °C : 9.6

Relative density : No data available

Density : 1.05 g/cm³

Solubility : Water: Insoluble in water

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : ≥ 0.0047 vol %

9.2. Other information

No additional information available 

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : May damage the unborn child.

Suspected of damaging fertility.

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified 

12.1. Toxicity

Ecology - water : Very toxic to aquatic life.

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

This substance/mixture does not meet the PBT criteria

of REACH regulation, annex XIII This substance/mixture

does not meet the vPvB criteria of REACH regulation, annex XIII

12.6. Other adverse effects

No additional information available 

13.1. Waste treatment methods

Product/Packaging disposal Recommendations : Dispose of

contents/container to hazardous or special waste collection

point, in accordance with local, regional, national and/or international regulation. 

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations No

REACH Annex XVII restrictions Dibutyl phthalate (DBP) is on the REACH Candidate List

Dibutyl phthalate (DBP) is on the REACH Annex XIV List:

Authorisation number Sunset date REACH authorisation exemptions 21/01/2015

15.1.2. National regulations

Germany Reference to AwSV : Water hazard class (WGK) 3,

severe hazard to water (Classification according to AwSV; ID No. 186)

12th Ordinance Implementing the Federal

Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Netherlands

SZW-lijst van kankerverwekkende stoffen : The substance is not listed

SZW-lijst van mutagene stoffen : The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding : The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid : DIBUTYL PHTHALATE FOR SYNTHESIS is listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling : DIBUTYL PHTHALATE FOR SYNTHESIS is  listed

Denmark

Recommendations Danish Regulation : Young people below the age of 18 years are not allowed

to use the product Pregnant/breastfeeding women working with the product must not be in direct

contact with the product The requirements from the Danish Working Environment Authorities regarding

work with carcinogens must be followed during use and disposal

15.2. Chemical safety assessment

No additional information available 

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.