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Product Name |
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Product Type |
DIETHYL CARBONATE FOR SYNTHESIS 99% |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
3.1. Substances: DIETHYL CARBONATE FOR SYNTHESIS
CAS-No. : 105-58-8
Substance. Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, H226
Category 3
Serious eye damage/eye irritation, H319
Category 2
Skin corrosion/irritation, H315
Category 2
Specific target organ toxicity — Single exposure, H335
Category 3,
Respiratory tract irritation Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Adverse physicochemical, human health and environmental effects
No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Extra labelling to displayExtra classification(s) to display
Symbol(s) : Xi : Irritation Highly flammable.
R Phrase(s) : R36/37/38: Irritating to eyes,
respiratory system and skin. R10: Flammable.
Hazard pictograms :
Signal word :Warning
Hazard statements : H226 -
Flammable liquid and vapour. H315 -
Causes skin irritation. H319 -
Causes serious eye irritation. H335 -
May cause respiratory irritation.
Precautionary statements : P261 -
Avoid breathing vapours, spray, dust, fume, gas.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
3.3. Other hazards
No additional information available
.
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/….
Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after
eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges.
No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care
because residual vapours are flammable. Precautions for safe
handling : Avoid contact with skin and eyes. Take precautionary measures
against static discharge. Use only non-sparking tools. Keep away from sources
of ignition – No smoking. Use only outdoors or in a well-ventilated area.
Do not breathe vapours. Hygiene measures : Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment. Storage conditions : Keep container tightly closed. Store in a well-ventilated place.
Incompatible materials : Heat sources.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate
(butylacetate=1) : No data available
Melting point : -43 °C
Freezing point : No data available
Boiling point : 126 °C
Flash point : 25 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Flammable liquid and vapour.
Vapour pressure : 1.4
kPa (at 25°C) Relative vapour density at 20 °C : 4.07
Relative density : No data available
Density : 0.9752 g/cm³
Solubility : Water: Insoluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Open flame. Heat. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous
decomposition products May release flammable gases.
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes
skin irritation. Serious eye damage/irritation : Causes serious
eye irritation. Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : May cause respirator
y irritation. STOT-repeated exposure : Not classifie
d Aspiration hazard : Not classified
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to
hazardous or special waste collection point, in accordance with local, regional,
national and/or international regulation. Additional information : Handle empty
containers with care because residual vapours are flammable.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2366
UN-No. (IMDG) : 2366
UN-No. (IATA) : 2366
UN-No. (ADN) : 2366
UN-No. (RID) : 2366
14.2. UN proper shipping name
Proper Shipping Name (ADR) : DIETHYL CARBONATE Proper Shipping Name
(IMDG) : DIETHYL CARBONATE Proper Shipping Name (IATA) : Diethyl carbonate Proper Shipping Name
(ADN) : DIETHYL CARBONATE Proper Shipping Name (RID) : DIETHYL CARBONATE Transport document description
(ADR) : UN 2366 DIETHYL CARBONATE, 3, III, (D/E)
Transport document description (IMDG) : UN 2366
DIETHYL CARBONATE, 3, III
(25°C c.c.) Transport document description (IATA) : UN 2366 Diethyl carbonate, 3, III
Transport document description (ADN) : UN 2366 DIETHYL CARBONATE, 3, III
Transport document description (RID) : UN 2366 DIETHYL CARBONATE, 3, III
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 3
Danger labels (ADR) : 3
IMDG- Transport hazard class(es) (IMDG) : 3
Danger labels (IMDG) : 3
IATA- Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
ADN- Transport hazard class(es) (ADN) : 3
Danger labels (ADN) : 3
RID- Transport hazard class(es) (RID) : 3
Danger labels (RID) : 3
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No Other information : No
supplementary information available
14.6. Special precautions for user
Overland transport-
Classification code (ADR) : F1
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions (ADR) : T2
Portable tank and bulk container special provisions (ADR) : TP1
Tank code (ADR) : LGBF Vehicle for tank carriage : FL
Transport category (ADR) : 3
Special provisions for carriage – Packages (ADR) : V12
Special provisions for carriage – Operation (ADR) : S2
Hazard identification number (Kemler No.) : 30
Orange plates : Tunnel restriction code (ADR) : D/E
EAC code : 3Y
Transport by sea-
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Flash point (IMDG) : 25°C to 31°C c.c.
Properties and observations (IMDG) : Colourless liquid.
Flashpoint: 25°C to 31°C c.c.
Vapour much heavier than air (4.1).
Immiscible with water. Irritating to skin,
eyes and mucous membranes.
MFAG-No : 128
Air transport-
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity (IATA) : 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
ERG code (IATA) : 3L
Inland waterway transport-
Classification code (ADN) : F1
Limited quantities (ADN) : 5L
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 0
Rail transport-
Classification code (RID) : F1
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions (RID) : T2
Portable tank and bulk container special provisions (RID) : TP1
Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 3
Special provisions for carriage – Packages (RID) : W12
Colis express (express parcels) (RID) : CE4
Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions DIETHYL CARBONATE FOR SYNTHESIS is not on the
REACH Candidate List DIETHYL CARBONATE FOR SYNTHESIS is not on the
REACH Annex XIV List
15.1.2. National regulations
Germany Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV; ID No. 2559)
12th Ordinance Implementing the Federal
Immission
Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5
liter Classification remarks : R10 ; Emergency management guidelines
for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young
people below the age of 18 years are not allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.