DI METHYL FORMAMIDE LR
DIMETHYLFORMAMIDE LR Formdimethylamide
- Part number
- RXSOL-60-6604-477
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
dimethylformamide is (CH3)2NC(O)H and is abbreviated as DMF. It is a colorless liquid which dissolves in water and most of the organic chemicals. In its purest form it is odorless and with contamination or impurities it develops a fishy odor.
Applications
The primary use of DMF is as a solvent with low evaporation rate. DMF is used in the production of acrylic fibers and plastics. It is also used as a solvent in peptide coupling for pharmaceuticals, in the development and production of pesticides, and in the manufacture of adhesives, synthetic leathers, fibers, films, and surface coatings.
Dosage and directions
In acute and repeated-dose toxicity studies, DMF has been consistently hepatotoxic, inducing effects on the liver at lowest concentrations or doses.
Characteristics and notes
The dimethylformamide-dimethyl sulfate complex prepared above is transferred to the dropping funnel and added slowly.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | DIMETHYLFORMAMIDE | ||
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
2.1. Substance : DIMETHYLFORMAMIDE
CAS No : 68-12-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, H226
Category 3
Acute toxicity (dermal), H312
Category 4
Acute toxicity (inhal.), H332
Category 4
Serious eye damage/eye irritation, H319
Category 2
Reproductive toxicity, H360D
Category 1B
Classification according to Directive 67/548/EEC or 1999/45/EC
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : T : Very toxic
Xi : Irritation.
Xn: Harmful
R Phrase(s) : R20/21: Harmful by inhalation and in contact with skin.
R61: May cause harm to unborn child.
R36: Irritating to eyes.
S Phrase(s) : S53: Avoid exposure – obtain special instruction before use.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
Hazard pictograms
Signal word : Danger
Hazard statements : H226 - Flammable liquid and vapour
H312+H332 - Harmful in contact with skin or if inhaled
H319 - Causes serious eye irritation
H360D - May damage the unborn child
Precautionary statements : P201 - Obtain special instructions before use
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P308+P313 - IF exposed or concerned: Get medical advice/attention
3.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
4.1. Description of first aid measures
First-aid measures general : IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice.
First-aid measures after skin contact : Immediately call a POISON CENTER or
doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and
water. Wash contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek
medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May damage the unborn child.
Symptoms/injuries after skin contact : Repeated exposure to this material can result in
absorption through skin causing significant health hazard. Harmful in contact with skin.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until
all safety precautions
have been read and understood.
Hygiene measures : Wash ... thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in original container. Keep container tightly closed. Store in a
dry place.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : 6.7
Relative evaporation rate (butylacetate=1) : 0.17
Melting point : -61 °C
Freezing point : No data available
Boiling point : 153 °C
Flash point : 580 °C
Auto-ignition temperature : 4450 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Vapour pressure : 2.7 at 20C
Relative vapour density at 20 °C : 2.52
Relative density : No data available
Density : 0.949 g/cm³
Solubility : Water:
Complete Log Pow : 1.01
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.022 - 0.152 vol %
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity: Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
Skin corrosion/irritation : Not classified
pH: 6.7
Serious eye damage/irritation : Causes serious eye irritation.
pH: 6.7
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : May damage the unborn child.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful in contact with skin.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Log Pow 1.01
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to ...
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2265
UN-No. (IMDG) : 2265
UN-No.(IATA) : 2265
UN-No.(ADN) : 2265
UN-No. (RID) : 2265
14.2. UN proper shipping name
Proper Shipping Name (ADR) : DIMETHYLFORMAMIDE
Proper Shipping Name (IMDG) : DIMETHYLFORMAMIDE
Proper Shipping Name (IATA) : DIMETHYLFORMAMIDE
Proper Shipping Name (ADN) : DIMETHYLFORMAMIDE
Proper Shipping Name (RID) : DIMETHYLFORMAMIDE
Transport document description (ADR) : UN 2265 DIMETHYLFORMAMIDE, 3, III,
(D/E)
Transport document description (IMDG) : UN 2265 DIMETHYLFORMAMIDE, 3, III
(58°C c.c.)
Transport document description (IATA) : UN 2265 DIMETHYLFORMAMIDE, 3, III
Transport document description (ADN) : UN 2265 DIMETHYLFORMAMIDE, 3, III
Transport document description (RID) : UN 2265 DIMETHYLFORMAMIDE, 3, III
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 3
Danger labels (ADR) : 3
IMDG- Transport hazard class(es) (IMDG) : 3
Danger labels (IMDG) : 3
IATA- Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
ADN- Transport hazard class(es) (ADN) : 3
Danger labels (ADN) : 3
RID- Transport hazard class(es) (RID) : 3
Danger labels (RID) : 3
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : F1
Limited quantities (ADR) : 5L
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions (ADR) : T2
Portable tank and bulk container special provisions (ADR) : TP2
Tank code (ADR) : LGBF Vehicle for tank carriage : FL
Transport category (ADR) : 3
Special provisions for carriage – Packages (ADR) : V12
Special provisions for carriage – Operation (ADR) : S2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2Y
Transport by sea- Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Flash point (IMDG) : 58°C c.c.
MFAG-No : 129
Air transport- PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity (IATA) : 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
ERG code (IATA) : 3L
Inland waterway transport- Classification code (ADN) : F1
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 0
Rail transport- Classification code (RID) : F1
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions (RID) : T2
Portable tank and bulk container special provisions (RID) : TP2
Tank codes for RID tanks (RID) : LGBF
Transport category (RID) : 3
Special provisions for carriage – Packages (RID) : W12
Colis express (express parcels) (RID) : CE4
Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
N,N-dimethylformamide is on the REACH Candidate List
DIMETHYLFORMAMIDE For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water
(KBwS-Beschluss; WGK No 83)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
DI METHYL FORMAMIDE LR manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
DI METHYL FORMAMIDE LR is available in small packing as well as in bulk. Buy premium quality DI METHYL FORMAMIDE LR and other lab chemicals from one of the most trusted brands.
