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Product Name |
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Product Type |
DIMETHYL SULPHATE |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substance : DIMETHYL SULPHATE
CAS No : 77-78-1
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), H301
Category 3
Acute toxicity (inhal.), H330
Category 2
Skin corrosion/irritation, H314
Category 1B
Sensitisation — Skin, H317
category 1
Germ cell mutagenicity, H341
Category 2
Carcinogenicity, H35
Category 01B
Classification according to Directive 67/548/EEC or 1999/45/EC
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : T : Very toxic
R Phrase(s) : R25: Toxic if swallowed.
R26: Very toxic by inhalation.
R34: Cause burns.
R45: May cause cancer.
S Phrase(s) : S26: In the case of contact with eyes, rinse immediately with plenty of
water and seek medical advise.
S27: Take off immediately all contaminated clothing.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
S53: Avoid exposure – obtain special instruction before use.
Hazard pictograms :
Signal word : Danger
Hazard statements : H301 - Toxic if swallowed
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H330 - Fatal if inhaled
H341 - Suspected of causing genetic defects
H350 - May cause cancer
Precautionary statements : P201 - Obtain special instructions before use
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
3.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
4.1. Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or
doctor/physician. Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical advice/attention. Specific treatment (see ... on this label). Wash
contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER
or doctor/physician. Specific treatment (see ... on this label). Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage. Suspected of causing
genetic defects. May cause cancer.
Symptoms/injuries after inhalation : May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage.
Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of
this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable
containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray. Avoid
breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Use
personal protective equipment as required. Do not handle until all safety precautions
have been read and understood.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ...
thoroughly after handling. Wash contaminated clothing before reuse. Contaminated work
clothing should not be allowed out of the workplace.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Store in original container. Keep container tightly closed. Store in a
dry place. Protect from moisture.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : -32 °C
Freezing point : No data available
Boiling point : 188 °C
Flash point : 830 °C
Auto-ignition temperature : 1880 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 0.5 mm Hg at 200C
Relative vapour density at 20 °C : 4.35
Relative density : No data available
Density : 1.3283 g/cm³
Solubility : Water: 2.8 g/100ml @180C
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Heat. Open flame. Overheating. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed. Inhalation: Fatal if inhaled.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : May cause cancer.
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure): Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1595
UN-No. (IMDG) : 1595
UN-No.(IATA) : 1595
UN-No.(ADN) : 1595
UN-No. (RID) : 1595
14.2. UN proper shipping name
Proper Shipping Name (ADR) : DIMETHYL SULPHATE
Proper Shipping Name (IMDG) : DIMETHYL SULPHATE
Proper Shipping Name (IATA) : DIMETHYL SULPHATE
Proper Shipping Name (ADN) : DIMETHYL SULPHATE
Proper Shipping Name (RID) : DIMETHYL SULPHATE
Transport document description (ADR) : UN 1595 DIMETHYL SULPHATE, 6.1 (8), I,
(C/D)
Transport document description (IMDG) : UN 1595 DIMETHYL SULPHATE, 6.1 (8), I
Transport document description (IATA) : UN 1595 DIMETHYL SULPHATE, 6.1, I
Transport document description (ADN) : UN 1595 DIMETHYL SULPHATE, 6.1 (8), I
Transport document description (RID) : UN 1595 DIMETHYL SULPHATE, 6.1 (8), I
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 6.1
(8) Danger labels (ADR) : 6.1,
8 IMDG- Transport hazard class(es) (IMDG) : 6.1
(8) Danger labels (IMDG) : 6.1,
8 IATA- Transport hazard class(es) (IATA) : 6.1
(8) Hazard labels (IATA) : 6.1,
8 ADN- Transport hazard class(es) (ADN) : 6.1
(8) Danger labels (ADN) : 6.1,
8 RID- Transport hazard class(es) (RID) : 6.1
(8) Danger labels (RID) : 6.1,
8 14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : TC1
Special provision (ADR) : 354
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P602
Mixed packing provisions (ADR) : MP8, MP17
Portable tank and bulk container instructions (ADR) : T20
Portable tank and bulk container special provisions (ADR) : TP2, TP35
Tank code (ADR) : L10CH
Tank special provisions (ADR) : TU14, TU15, TE19, TE21
Vehicle for tank carriage : AT
Transport category (ADR) : 1
Special provisions for carriage - Loading, unloading and handling (ADR) : CV1, CV13,
CV28
Special provisions for carriage – Operation (ADR) : S9, S14
Hazard identification number (Kemler No.) : 668
Orange plates :
Tunnel restriction code (ADR) : C/D
EAC code : •3XE
APP code : B
Transport by sea- Special provision (IMDG) : 354
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P602
Tank instructions (IMDG) : T20
Tank special provisions (IMDG) : TP2, TP13, TP35
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : D
Stowage and handling (IMDG) : SW2
MFAG-No : 156
Air transport- PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity (IATA) : Forbidden
PCA packing instructions (IATA) : Forbidden
PCA max net quantity (IATA) : Forbidden
CAO packing instructions (IATA) : Forbidden
CAO max net quantity (IATA) : Forbidden
ERG code (IATA) : 6C
Inland waterway transport- Classification code (ADN) : TC1
Special provisions (ADN) : 354, 802
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, TOX, A
Ventilation (ADN) : VE02
Number of blue cones/lights (ADN) : 2
Rail transport- Classification code (RID) : TC1
Special provision (RID) : 354
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P602
Mixed packing provisions (RID) : MP8, MP17
Portable tank and bulk container instructions (RID) : T20
Portable tank and bulk container special provisions (RID) : TP2, TP35
Tank codes for RID tanks (RID) : L10CH
Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22
Transport category (RID) : 1
Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31
Hazard identification number (RID) : 668
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Dimethyl sulphate is on the REACH Candidate List
DIMETHYL SULPHATE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to
water (KBwS-Beschluss; WGK No 734)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.