DI Tert BUTYL DI CARBONATE
DI Tert BUTYLDICARBONATE
- Part number
- RXSOL-60-6604-493
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Di-tert-butyl dicarbonate is a reagent widely used in organic synthesis. Since this compound can be regarded formally as the acid anhydride derived from a tert-butoxycarbonyl group, it is commonly referred to as Boc anhydride.
Applications
- Protection of alcohols as Boc derivatives via Lewis acid catalysis.
- Reagent for the introduction of the Boc protecting group.
- Tris-Boc protected hydrazine allows preparation of Fmoc ester in a chromophoric reagent to monitor solid-phase aldehydes.
Dosage and directions
-
inhalation chronic dose was calculated to be 0.178 μg/kg-bw per day for the 0.5–4
Characteristics and notes
-
A gas-inlet tube of smaller diameter or a tube fitted with a fritted-glass outlet tends to become clogged during this preparation and is not recommended.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | DI-tert-BUTYLDICARBONATE | |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
2.1. Substances : DI-tert BUTYLDICARBONATE
CAS-No. : 24424-99-5
Substance.
Contains no other components or impurities which will influence the classification of the
producT
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, H226
Category 3
Acute toxicity (inhal.), H330
Category 2
Skin corrosion/irritation, H315
Category 2
Serious eye damage/eye irritation, H319
Category 2
Skin sensitisation, H317
Category 1
Specific target organ H335
toxicity — Single exposure, Category 3,
Respiratory tract irritation Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : T : Very toxic
Xi : Irritation.
R Phrase(s) : R10: Flammable.
R26: Very toxic by inhalation.
R43: May cause sensitization by skin contact.
R36/38: Irritating to eyes and skin
. S Phrase(s) : S28: After contact with skin, wash immediately with plenty of …(to be
specified by manufacturer)
. S45: In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
S36/37 : Wear suitable protective clothing and gloves.
Hazard pictograms
Signal word : Danger
Hazard statements : H226 - Flammable liquid and vapour.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation. H330 - Fatal if inhaled.
H335 - May cause respiratory irritation.
Precautionary statements : P260 - Do not breathe vapours, spray, dust, fume, gas.
P280 - Wear protective gloves, protective clothing, cold insulating gloves, eye
protection
. P284 - Wear respiratory protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
3.3. Other hazards
No additional information available
.
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Take off immediately all contaminated clothing.
Wash with plenty of water/…. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Get medical
advice/attention .
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation
. Symptoms/effects after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric
charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers
. 6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual
vapours are flammable
. Precautions for safe handling : Do not breathe vapours. Take precautionary measures
against static discharge. Use only non-sparking tools. Keep away from sources of ignition
No smoking. Use only outdoors or in a well-ventilated area. Avoid contact with skin and
eyes.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be
followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment.
Storage conditions : Keep container tightly closed. Keep in fireproof place.
Incompatible materials : Heat sources.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 23 °C
Freezing point : No data available
Boiling point : 56 - 57 °C
Flash point : 37 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammableliquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 0.95 g/cm³
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Open flame. Heat. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
May release flammable gases.
11.1. Information on toxicological effects
Acute toxicity : Inhalation: Fatal if inhaled.
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessmen
t No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation.
Additional information : Handle empty containers with care because residual vapours are
flammable.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2929
UN-No. (IMDG) : 2929
UN-No. (IATA) : 2929
UN-No. (ADN) : 2929
UN-No. (RID) : 2929
14.2. UN proper shipping name
Proper Shipping Name (ADR) : TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Proper Shipping Name (IMDG) : TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S
. Proper Shipping Name (IATA) : Toxic liquid, flammable, organic, n.o.s.
Proper Shipping Name (ADN) : TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S
. Proper Shipping Name (RID) : TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
Transport document description (ADR) : UN 2929 TOXIC LIQUID, FLAMMABLE,
ORGANIC, N.O.S., 6.1 (3), I, (C/D)
Transport document description (IMDG) : UN 2929 TOXIC LIQUID, FLAMMABLE
, ORGANIC, N.O.S., 6.1 (3), I
Transport document description (IATA) : UN 2929 Toxic liquid, flammable,
organic, n.o.s., 6.1, I
Transport document description (ADN) : UN 2929 TOXIC LIQUID, FLAMMABLE,
ORGANIC, N.O.S., 6.1(3), I
Transport document description (RID) : UN 2929 TOXIC LIQUID, FLAMMABLE
, ORGANIC, N.O.S., 6.1 (3), I
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 6.1
(3) Danger labels (ADR) : 6.1, 3
IMDG- Transport hazard class(es) (IMDG) : 6.1
(3) Danger labels (IMDG) : 6.1, 3
IATA-Transport hazard class(es) (IATA) : 6.1
(3) Hazard labels (IATA) : 6.1, 3
ADN- Transport hazard class(es) (ADN) : 6.1
(3) Danger labels (ADN) : 6.1, 3
RID- Transport hazard class(es) (RID) : 6.1
(3) Danger labels (RID) : 6.1, 3
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : TF1
Special provisions (ADR) : 274, 315
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E5
Packing instructions (ADR) : P001
Mixed packing provisions (ADR) : MP8 , MP17
Portable tank and bulk container instructions (ADR) : T14
Portable tank and bulk container special provisions (ADR) : TP2, TP27
Tank code (ADR) : L10CH
Tank special provisions (ADR) : TU14, TU15, TE19, TE21
Vehicle for tank carriage : FL
Transport category (ADR) : 1
Special provisions for carriage - Loading, unloading and handling (ADR) : CV1, CV13,
CV28
Special provisions for carriage – Operation (ADR) : S2, S9, S14
Hazard identification number (Kemler No.) : 663
Orange plates
: Tunnel restriction code (ADR) : C/D
EAC code : •3W
APP code : A(fl
) Transport by sea- Special provisions (IMDG) : 274, 315
Packing instructions (IMDG) : P001
Tank instructions (IMDG) : T14
Tank special provisions (IMDG) : TP2, TP13, TP27
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Properties and observations (IMDG) : Toxic if swallowed, by skin contact or by
inhalation. MFAG-No : 131
Air transport- PCA Excepted quantities (IATA) : E5
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity (IATA) : Forbidden
PCA packing instructions (IATA) : 652
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 658
CAO max net quantity (IATA) : 30L
Special provisions (IATA) : A4, A137
ERG code (IATA) : 6F
Inland waterway transport- Classification code (ADN) : TF1
Special provisions (ADN) : 274, 315, 802
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E5
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, EX, TOX, A
Ventilation (ADN) : VE01, VE02
Number of blue cones/lights (ADN) : 2
Rail transport- Classification code (RID) : TF1
Special provisions (RID) : 274, 315
Limited quantities (RID) : 0
Excepted quantities (RID) : E5
Packing instructions (RID) : P001
Mixed packing provisions (RID) : MP8, MP17
Portable tank and bulk container instructions (RID) : T14
Portable tank and bulk container special provisions (RID) : TP2, TP27
Tank codes for RID tanks (RID) : L10CH
Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22
Transport category (RID) : 1
Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28,
CW31 Hazard identification number (RID) : 663
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
DI-TERT BUTYLDICARBONATE is not on the REACH Candidate List
DI-TERT BUTYLDICARBONATE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10< H226;H315;H317;H319;H330;H335> Emergency
management guidelines for
the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
DI Tert BUTYL DI CARBONATE manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
DI Tert BUTYL DI CARBONATE is available in small packing as well as in bulk. Buy premium quality DI Tert BUTYL DI CARBONATE and other lab chemicals from one of the most trusted brands.
