Diethylamine LR 99.5 %

2.1. Substance: DIETHYLAMINE

CAS No : 109- 89- 7

Substance.

Contains no other components or impurities which will influence the classification of the

product.

3.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flammable liquids, H225

Category 2

Acute toxicity (oral), H302

Category 4

Acute toxicity (dermal), H312

Category 4

Acute toxicity (inhal.), H332

Category 4

Skin corrosion/irritation, H314

Category 1 A

Full text of classification categories and H statements : see section 16

Classification according to Directive 67/548/EEC or 1999/45/EC

F; R11

Xn; R20/21/22

C; R35

Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

3.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to

displayExtra classification(s) to display

Symbol(s) : Highly flammable

C: Corrosive

Xn: Harmful

R Phrase(s):R11: Highly flammable.

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.

R35: Cause severe burns.

S Phrase(s) :S3: Keep in a cool place.

S16: Keep away from source of ignition-No smoking.

S26: In the case of contact with eyes, rinse immediately with plenty of water and seek

medical advise.

S29: Do not empty into drains.

S36/37/39 : Wear suitable protective clothing and gloves & eye/face protecting.

S45: In case of accident or if you feel unwell, seek medical advice immediately (show the

label where possible).

Hazard pictograms: 

Signal word: Danger

Hazard statements : H225 - Highly flammable liquid and vapour

H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled

H314 - Causes severe skin burns and eye damage

Precautionary statements:

P210 - Keep away from heat/sparks/open flames/hot

surfaces. - No smoking

P280 - Wear protective gloves/protective clothing/eye protection/face protection

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing

P310 - Immediately call a POISON CENTER or doctor/physician

3.3. Other hazards

No additional information available3

4.1. Description of first aid measures

First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a

position comfortable for breathing.

Immediately call a POISON CENTER or doctor/physician. Specific treatment is

urgent (see ... on this label).

First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off

immediately all contaminated clothing. Immediately call a POISON CENTER or

doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and

water. Wash contaminated clothing before reuse.

First-aid measures after eye contact : Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a

POISON CENTER or doctor/physician.

Specific treatment (see ... on this label).

First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or

doctor/physician if you feel unwell. Do NOT induce vomiting. Immediately call a

POISON CENTER or doctor/physician. Specific treatment (see ... on this label).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries : Causes severe skin burns and eye damage.

Symptoms/injuries after inhalation : Corrosive to the respiratory tract.

Symptoms/injuries after skin contact : Repeated exposure to this material can result in

absorption through skin causing significant health hazard. Harmful in contact with skin.

Symptoms/injuries after eye contact : Causes serious eye damage.

Symptoms/injuries after ingestion : Swallowing a small quantity of this material will

result in serious health hazard.

4.3. Indication of any immediate medical attention and special treatment needed

No additional information available

5.1. Extinguishing media

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Highly flammable liquid and vapour.

Explosion hazard : May form flammable/explosive vapour-air mixture.

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective

equipment.

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Remove ignition sources. Use special care to avoid static electric

charges. No naked lights. No smoking.

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable

containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as

possible.

6.4. Reference to other sections

No additional information available

9.1. Information on basic physical and chemical properties

Odour threshold : No data available

pH : No data available Relative

evaporation rate (butylacetate=1) : 16.9

Melting point : -50 °C Freezing point : No data available

Boiling point : 55 - 58

Flash point : -28 °C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : Flammable

Highly flammable liquid and vapour

Vapour pressure : 195 mm Hg at 20°C

Relative vapour density at 20 °C : 2.5

Relative density : No data available

Density : 0.71 g/cm³

Solubility : Water: Miscible in water

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : 0.018 - 0.101 vol %

9.2.Other information

No additional information available

11.1. Information on toxicological effects

Acute toxicity : Oral: Harmful if swallowed.

Dermal: Harmful in contact with skin.

Inhalation: Harmful if inhaled.

Skin corrosion/irritation : Causes severe skin burns and eye damage.

Serious eye damage/irritation : Serious eye damage, category 1, implicit

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Additional information : Corrosive to the respiratory tract

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

Potential adverse human health effects and symptoms

: Harmful if swallowed. Harmful in contact with skin. 

12.1. Toxicity

No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

13.1. Waste treatment methods

Product/Packaging disposal Recommendations : Dispose of contents/container to ...

Additional information : Handle empty containers with care because residual vapours are

flammable.

15.1. Safety, health and environmental regulations/legislation specific for the

substance or mixture

15.1.1. EU-Regulations

No REACH Annex XVII restrictions

DIETHYLAMINE For Synthesis is not on the REACH Candidate List

DIETHYLAMINE For Synthesis is not on the REACH Annex XIV List

15.1.2. National regulations

Germany

AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to

water (Classification according to VwVwS, Annex 2; WGK No 248)

12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not

subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Denmark

Classification remarks : Emergency management guidelines for the storage of flammable

liquids must be followed

Recommendations Danish Regulation : Young people below the age of 18 years are not

allowed to use the product

Pregnant/breastfeeding women working with the product must not be in direct

contact with the product

15.2. Chemical safety assessment

No additional information available

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.

vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN

PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,

labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006

Further information : None.

In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation

(CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.