ETHYL IODIDE FOR SYNTHESIS
- Part number
- RXSOL-60-6604-567
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Ethyl iodide is prepared by using red phosphorus, absolute ethanol and iodine. the iodine dissolve in the ethanol where it react with the solid phosphorus to form phosphorus triiodide, which must be formed in situ because it is unstable. During the process the temperature is controlled.
Applications
- Ethyl iodide, clear liquid; boiling at 72.3 C is used as an ethylating agent in organic synthesis for many application, for example, as solvents, intermediates for numerous chemicals, dyes, fumigants, sterilants, X-ray contrast media, antiseptics and pharmaceuticals.
Characteristics and notes
-
A funnel of this volume and shape is not essential but has been found convenient. Even if a globular separatory funnelis used, the liquid flowing through it has been found to wet the walls. -
For larger quantities a flask up to 12 l. in capacitymay be substituted. -
The stopcock from a small, broken, separatory funnel serves the purpose.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | ETHYL IODIDE FOR SYNTHESIS (IODOETHANE) | ||
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : ETHYL IODIDE
CAS No :75-03-6
Substance. Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : Xn; R22
Xi; R36/37/38
Xn ; R42/43
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Specific Target Organ Toxicity - Single exposure - Respiratory tract
irritation - Category 3 - Warning (CLP : STOT SE 3) H335
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317
Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) H334
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : Xn : Harmful
R Phrase(s) : R10: Flammable.
R22 : Harmful if swallowed.
R36/37/38 : Irritating to eyes, respiratory system and skin.
R42/43 : May cause sensitization by inhalation and skin contact.
S Phrase(s) : S23 : Do not breathe the gas, fumes, vapours, spray.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37 : Wear suitable protective clothing and gloves.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H302 : Harmful if swallowed.
H319 : Causes serious eye irritation.
H315 : Causes skin irritation.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 : May cause an allergic skin reaction.
H335 : May cause respiratory irritation.
Precautionary statements
• Prevention : P285: In case of inadequate ventilation wear respiratory protection.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feel unwell.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
P333+P313: If skin irritation or rash occurs : Get medical advice.
P342+P311: If experiencing respiratory symptoms : Call a POISON CENTER or doctor.
P363: Wash contaminated clothing before reuse.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Call a POISON CENTER or doctor if you feel unwell. If experiencing
respiratory symptoms : Remove to fresh air and keep at rest in a position comfortable for
breathing.
Skin contact : Specific treatment (see on this label). Get medical advice. Wash with
plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or
rash occurs :
Eye contact : If eye irritation persists : Get medical advice. Remove contact lenses, if
present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
Ingestion : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting.
Call a POISON CENTER or doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Swallowing a small quantity of this material will result in
serious health hazard. Causes serious eye irritation. Causes skin irritation. May cause
allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic
skin reaction. May cause respiratory irritation.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash thoroughly after handling. Contaminated work clothing should not be
allowed out of the workplace. Use only outdoors or in a well-ventilated area. Avoid
breathing dust, fume, gas, mist, vapours, spray. Wash thoroughly after handling. Wash
contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour.
Special precautions : Avoid breathing dust, fume, gas, mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container tightly closed
. Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : In case of inadequate ventilation wear respiratory protection.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -108 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : Flammable.
Flash point [°C] : 72 °C
Boiling point [°C] : 69 - 73 °C
Initial boiling point [°C] : 69°C
Final boiling point [°C] : 73 °C
Evaporation rate : N/A
Vapour pressure [20°C] : 177 hPa at 25 °C
Vapour pressure mm/Hg : N/A
Vapour density : 5,38
Density [g/cm3] : 1,95
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Partially soluble.
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Harmful if swallowed.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes serious eye irritation.
Causes skin irritation. May cause respiratory irritation.
Sensitization : May cause allergy or asthma symptoms or breathing difficulties if
inhaled. May cause an allergic skin reaction.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met
. Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
14.1. Land transport (ADR-RID)
General information : Not regulated.
14.2. Sea transport (IMDG) [English only]
General information : Not regulated.
14.3. Air transport (ICAO-IATA) [English only]
General information : Not regulated.
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
[ETHYL IODIDE FOR SYNTHESIS] manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
[ETHYL IODIDE FOR SYNTHESIS] is available in small packing as well as in bulk. Buy premium quality [ETHYL IODIDE FOR SYNTHESIS] and other lab chemicals from one of the most trusted brands.
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[PRODUCT NAME] manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
[PRODUCT NAME] is available in small packing as well as in bulk. Buy premium quality [PRODUCT NAME] and other lab chemicals from one of the most trusted brands.
[PRODUCT NAME] manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
[PRODUCT NAME] is available in small packing as well as in bulk. Buy premium quality [PRODUCT NAME] and other lab chemicals from one of the most trusted brands.
