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Product Name |
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Product Type |
GENTIAN VIOLET ALCOHOLIC SOLUTION |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substance
Not applicable
Substance name Contents CAS No
Methanol El
(Electronic Grade) 99.7% 99% 97-56-1
Gentian Violet AR 1% -5% ----
Substance. Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008
[CLP] Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Flammable liquids, H226
Category 3
Serious eye damage/eye irritation, H319
Category 2
Carcinogenicity, H351
Category 2
Hazardous to the aquatic environment — Chronic Hazard, H412
Category 3
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : Highly flammable
R Phrase(s) : R10: Flammable.
Hazard pictograms
Signal word : Warning
Hazard statements : H226 - Flammable liquid and vapour
H319 - Causes serious eye irritation
H351 - Suspected of causing cancer
H412 - Harmful to aquatic life with long lasting effects
Precautionary statements : P273 - Avoid release to the environment
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
3.3. Other hazards
No additional information available
.
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. Get medical advice/attention.
First-aid measures after skin contact : Gently wash with plenty of soap and water. Wash
contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Get medical advice/attention. Do NOT
induce vomiting
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause cancer.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically
5.1. Extinguishing media
Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. No naked lights. No smoking.
Use special care to avoid static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Harmful to aquatic life with long lasting effects.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable
containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual
vapours are flammable.
Precautions for safe handling : Keep away from sources of ignition - No smoking. No
naked lights. No smoking. Take precautionary measures against static discharge. Avoid
contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before
eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be
followed.
Storage conditions : Keep container tightly closed. Keep in fireproof place.
Incompatible materials : Heat sources.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Where exposure through inhalation may occur from use,
respiratory protection equipment is recommended
9.1. Information on basic physical and chemical properties
Odour threshold : 5100 ppm
pH : No data available
Relative evaporation rate (butylacetate=1) : 1.9
Melting point : -110 °C
Freezing point : No data available
Boiling point : No data available
Flash point : 12.5 °C
Auto-ignition temperature : 385 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Vapour pressure : 12.8 kPa at 20°C
Relative vapour density at 20 °C : 3
Relative density : No data available
Density : < 1 g/cm³
Solubility : Water: Miscible in water
Log Pow : Separates from oil.
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 3.3 - 36.5 vol %
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid Open flame.
Heat. Sparks. Overheating.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
May release flammable gases
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure): Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Log Pow Separates from oil.
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to .
.. Additional information : Handle empty containers with care because residual vapours are
flammable
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1230
UN-No. (IMDG) : 1230
UN-No.(IATA) : 1230
UN-No.(ADN) : Not regulated
UN-No. (RID) : Not regulated
14.2. UN proper shipping name
Proper Shipping Name (ADR) : METHANOL
Proper Shipping Name (IMDG) : METHANOL
Proper Shipping Name (IATA) : METHANOL
Proper Shipping Name (ADN) : Not regulated
Proper Shipping Name (RID) : Not regulated
Transport document description (ADR) : UN 1230 METHANOL, 3 (6.1), II, (D/E)
Transport document description (IMDG) : UN 1230 METHANOL, 3 (6.1), II (12°C c.c.)
Transport document description (IATA) : UN 1230 METHANOL, 3 (6.1), II
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 3 (6.1)
Danger labels (ADR) : 3, 6.1
IMDG- Transport hazard class(es) (IMDG) : 3 (6.1)
Danger labels (IMDG) : 3, 6.1
IATA- Transport hazard class(es) (IATA) : 3 (6.1)
Hazard labels (IATA) : 3, 6.1
ADN- Transport hazard class(es) (ADN) : Not regulated
RID- Transport hazard class(es) (RID) : Not regulated
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not regulated
Packing group (RID) : Not regulated
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user Overland transport- Classification code (ADR) : FT1
Special provision (ADR) : 279
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions (ADR) : T7
Portable tank and bulk container special provisions (ADR) : TP2
Tank code (ADR) : L4BH
Tank special provisions (ADR) : TU15
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28
Special provisions for carriage – Operation (ADR): S2, S19
Hazard identification number (Kemler No.) : 336
Orange plates
: Tunnel restriction code (ADR) : D/E
EAC code : •2WE
APP code : A(fl)
Transport by sea- Special provision (IMDG) : 279
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Flash point (IMDG) : 12°C c.c.
MFAG-No : 131
Air transport- PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 352
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A104, A113
ERG code (IATA) : 3L
Inland waterway transport- Not regulated
Rail transport- Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to
water (Classification according to AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the
storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.