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Product Name |
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Product Type |
GENTIAN VIOLET AR |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substances : GENTIAN VIOLET AR
CAS-No. : 548-62-9
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), H302
Category 4
Serious eye damage/eye irritation, H318
Category 1
Carcinogenicity, H351
Category 2
Hazardous to the aquatic environment — Chronic Hazard, H410
Category 1
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : T : Very toxic
N : Dangerous for the environment
R Phrase(s) : R22: Harmful if swallowed.
R40: Possible risk of very serious irreversible effects.
R41: Risk of serious damage to eyes.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effect in the
aquatic environment.
S Phrase(s) : S22: Do not breath dust.
S26: In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise.
S61: Avoid release to the environment . refer to special instruction/safety data sheets.
S36/37/39 : Wear suitable protective clothing and gloves & eye/face protecting.
Hazard pictograms
Signal word : Danger
Hazard statements : H302 - Harmful if swallowed.
H318 - Causes serious eye damage.
H351 - Suspected of causing cancer.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements : P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P501 - Dispose of contents/container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation
3.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated
clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes
. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you
feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye damage.
Symptoms/effects after ingestion : Harmful if swallowed.
Chronic symptoms : Suspected carcinogen.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Use only outdoors or in
a well-ventilated area. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in a well-ventilated place.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 173 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity: Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.
12.1. Toxicity
Ecology - water : May cause long lasting harmful effects to aquatic life.
12.2. Persistence and degradability
Persistence and degradability May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3077
UN-No. (IMDG) : 3077
UN-No. (IATA) : 3077
UN-No. (ADN) : 3077
UN-No. (RID) : 3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) : Environmentally hazardous substance, solid, n.o.s.
Proper Shipping Name (ADN) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Proper Shipping Name (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
Transport document description (ADR) : UN 3077 ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III,
(-)
Transport document description (IMDG) : UN 3077 ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III,
MARINE POLLUTANT
Transport document description (IATA) : UN 3077 Environmentally hazardous
substance, solid, n.o.s., 9, III
Transport document description (ADN) : UN 3077 ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (RID) : UN 3077 ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 9
Danger labels (ADR) : 9
IMDG- Transport hazard class(es) (IMDG) : 9
Danger labels (IMDG) : 9
IATA- Transport hazard class(es) (IATA) : 9
Hazard labels (IATA) : 9
ADN- Transport hazard class(es) (ADN) : 9
Danger labels (ADN) : 9
RID- Transport hazard class(es) (RID) : 9
Danger labels (RID) : 9
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : M7
Special provisions (ADR) : 274, 335, 375, 601
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : PP12, B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T1, BK1, BK2, BK3
Portable tank and bulk container special provisions (ADR) : TP33
Tank code (ADR) : SGAV, LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage – Packages (ADR) : V13
Special provisions for carriage – Bulk (ADR) : VC1, VC2
Special provisions for carriage - Loading, unloading and handling (ADR) : CV13
Hazard identification number (Kemler No.) : 90
Orange plates :
Tunnel restriction code (ADR) : -
EAC code : 2Z
Transport by sea- Special provisions (IMDG) : 274, 335, 966, 967, 969
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : LP02, P002
Special packing provisions (IMDG) : PP12
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : BK1, BK2, BK3, T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW23
MFAG-No : 171
Air transport- PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y956
PCA limited quantity max net quantity (IATA): 30kgG
PCA packing instructions (IATA) : 956
PCA max net quantity (IATA) : 400kg
CAO packing instructions (IATA) : 956
CAO max net quantity (IATA) : 400kg
Special provisions (IATA) : A97, A158, A179, A197
ERG code (IATA) : 9L
Inland waterway transport- Classification code (ADN) : M7
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T* B**
Equipment required (ADN) : PP, A
Number of blue cones/lights (ADN) : 0
Additional requirements/Remarks (ADN) : * Only in the molten state. ** For carriage in
bulk see also 7.1.4.1. ** * Only in the
case of transport in bulk.
Rail transport- Classification code (RID) : M7
Special provisions (RID) : 274, 335, 375, 601
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : PP12, B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container instructions (RID) : T1, BK1, BK2, BK3
Portable tank and bulk container special provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAV, LGBV Transport category (RID) : 3
Special provisions for carriage – Packages (RID) : W13
Special provisions for carriage – Bulk (RID): VC1, VC2
Special provisions for carriage - Loading, unloading and handling (RID): CW13, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
[4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1-
ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with ≥
0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] is
on the REACH Candidate List
CRYSTAL VIOLET AR/ACS FOR MICROSCOPY is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification
according to AwSV; ID No. 8394)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : CRYSTAL VIOLET AR/ACS FOR
MICROSCOPY is listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen –
Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.