HYDROXYLAMINE SULPHATE LR
- Part number
- RXSOL-60-6604-705
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Hydroxylamine Sulfate is a colorless to white, crystalline (sand-like) solid or powder. It is used in photography, leather tanning, and polymer manufacturing.
Applications
Hydroxylammonium sulfate is used in the production of anti-skinning agents, pharmaceuticals, rubber, textiles, plastics and detergents. It is a radical scavenger that terminates radical polymerization reactions and serves as an antioxidant in natural rubber.
Dosage and directions
Its many properties, including selective reactivity to textile fiber functional groups, make it useful for applications such as dye improvers, textile discoloration inhibitors, and modifiers for acrylic fibers and cellulose. Other uses include resin improvers, UV stabilizers, and polymerization catalysts.
Characteristics and notes
Although hydroxylamine is a product of normal cell metabolism, it is nevertheless mod- erately toxic to man, animals, and even plants. However, their toxic reactions become manifest only at concentrations substantially greater than those resulting from normal cell metabolism.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | HYDROXYLAMINE HYDROCHLORIDE AR | |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : bis(hydroxylammonium) sulphate
CAS No :10039-54-0
Substance.
Substance name Contents CAS No
bis(hydroxylammonium) sulphate : 100 % 10039-54-0
Contains no other components or impurities which will influence the classification of the product
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : E; R2
Carc. Cat. 3; R40
Xn; R21/22-48/22
Xi; R36/38
R43
N; R50
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351
Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP
: STOT RE 2) H373 Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317
Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312
Physical hazards : Explosives - Division 1.3 - Danger (CLP : Expl. 1.3) H203
Environmental hazards : Hazardous to the aquatic environment - Acute hazard
- Category 1 - Warning (CLP : Aquatic Acute 1) H400
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : E : Explosive.
Xn : Harmful
N : Dangerous for the environment.
R Phrase(s) : R2 : Risk of explosion by shock, friction, fire or other sources of ignition.
R21/22 : Harmful in contact with skin and if swallowed.
R36/38 : Irritating to eyes and skin.
R40 : Limited evidence of a carcinogenic effect.
R43 : May cause sensitization by skin contact.
R48/22 : Harmful : danger of serious damage to health by prolonged exposure if
swallowed.
R50 : Very toxic to aquatic organisms.
S Phrase(s) : S2 : Keep out of the reach of children.
S22 : Do not breath dust.
S24 : Avoid contact with skin.
S36/37 : Wear suitable protective clothing and gloves.
S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements :
H203 : Explosive; fire, blast or projection hazard.
H351 : Suspected of causing cancer.
H302 : Harmful if swallowed.
H312 : Harmful in contact with skin.
H319 : Causes serious eye irritation.
H315 : Causes skin irritation.
H317 : May cause an allergic skin reaction.
H373 : May cause damage to organs through prolonged or repeated exposure.
H400 : Very toxic to aquatic life.
Precautionary statements • General :
P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand
P201: Obtain special instructions before use
. • Prevention : P240: Ground/bond container and receiving equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P260: Do not breathe dust, fume, gas, mist, vapours, spray
. P273: Avoid release to the environment.
P230: Keep wetted with : (See information supplied by the manufacturer)
P250: Do not subject to grinding, shock, …, friction.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace
. • Response : P370+P380: In case of fire : Evacuate area.
P372: Explosion risk in case of fire.
P373: DO NOT fight fire when fire reaches explosives.
P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feel
unwell.
P308+P313: If exposed or concerned : get medical advice.
P391: Collect spillage.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P333+P313: If skin irritation or rash occurs : Get medical advice.
P363: Wash contaminated clothing before reuse.
P314: Get medical advice if you feel unwell.
• Storage : P401: Store in accordance with local, regional, national or international
regulation. P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to beidentified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest.
Skin contact : Immediately call a POISON CENTER or doctor. Specific treatment (see
on this label). Wash with plenty of soap and water. Wash contaminated clothing before
reuse. Get medical advice. If skin irritation or rash occurs
: Eye contact : Get medical advice. If eye irritation persists : Remove contact lenses, if
present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
Ingestion : Obtain emergency medical attention. Call a POISON CENTER or doctor if
you feel unwell. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Suspected of causing cancer.
Causes damage to organ. Repeated exposure to this material can result in absorption
through skin causing significant health hazard. Causes serious eye irritation. Causes skin
irritation. May cause an allergic skin reaction. Swallowing a small quantity of this
material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Explosive.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present. May form flammable/explosive vapour-air mixture.
5.3. Advice for fire-fighters Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment. Evacuate area. DO NOT fight fire when fire
reaches explosives.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : On land, sweep or shovel into suitable containers. Minimize
generation of dust. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Contaminated work clothing should not be allowed out of the workplace. Do
not eat, drink or smoke when using this product. Avoid breathing dust, fume, gas, mist,
vapours, spray. Wash thoroughly after handling. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Do not subject to grinding, shock, …,
friction. Obtain special instructions before use.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed.
Special precautions : Avoid breathing dust, fume, gas, mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container closed when not in use. Store in accordance with local, regional, national or
international regulation. Ground/bond container and receiving equipment.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure
. • Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or face shield.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : Not applicable.
Melting point [°C] : 170 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flash point [°C] : N/A
Boiling point [°C] : N/A
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : N/A
Vapour density : N/A
Density [g/cm3] : 1,9
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Freely soluble
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 3.6
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : Explosive; fire, blast or projection hazard.
N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Heat. Sparks.
Open flame. Direct sunlight. Overheating.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Harmful in contact with skin.
• Ingestion : Harmful if swallowed.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met
12.1. Toxicity
Toxicity information : Very toxic to aquatic life.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Hazardous waste due to potential risk of explosion.
Dispose of this material and its container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international regulation.
14.1. Land transport (ADR-RID)
Proper shipping name : HYDROXYLAMINE SULPHATE
UN N° : 2865
H.I. nr : 80
ADR - Class : 8
Labelling - Transport : 8 : Corrosive substance
. ADR - Classification code : C2
ADR - Group : III
ADR - Packing instructions : P002 R001 LP002
ADR - Limited Quantity : 5 KG
ADR - Tunnel code: E : Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : HYDROXYLAMINE SULPHATE
UN N° : 2865
IMO-IMDG - Class or division : 8
: Corrosive substance. IMO-IMDG -
Packing group : III
IMO- IMDG - Packing instructions : P002 LP02
IMO-IMDG - Limited quantities : 5 kg
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-A S-B
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : HYDROXYLAMINE SULPHATE
UN N° : 2865
IATA - Class or division : 8 : Corrosive substance.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 860
instruction - Passenger and Cargo - Maximum : 25 kg
Quantity/Packing IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 864
- Cargo only - Maximum Quantity/ : 100 kg
Packing IATA - Limited Quantites : 5 kg
ERG-Nr : 8L
5.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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