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Product Name |
HYDRXYLAMINE HYDROCHLORIDE |
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Part Number |
RXSOL-60-6173-500 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.comA |
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Chemical Name |
CAS |
EC numbe |
Weight |
Formula |
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Hydroxylamine hydrochloride |
5470-11-1 |
226-798-2 |
<= 100 % |
H2NOH.HCl |
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Signal Word |
Warning |
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Hazard Statements |
H290 May be corrosive to metals. H302 + H312 Harmful if swallowed or in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H373 May cause damage to organs (spleen) through prolonged or repeated exposure if swallowed. H410 Very toxic to aquatic life with long lasting effects. |
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Precautionary statements |
P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None. |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air. Call in physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Not flammable or combustible. |
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Flash Point |
Dry powder Dry sand |
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Suitable extinguishing media |
Water Foam Carbon dioxide (CO2) Dry powder Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Nitrogen oxides (NOx) Hydrogen chloride gas Nitrogen oxides (NOx) Hydrogen chloride gas Container explosion may occur under fire conditions. Combustible. Risk of dust explosion. In the event of decomposition: danger of explosion! Avoid shock and friction. Not combustible. Development of hazardous combustion gases or vapours possible in the event of fire. Ambient fire may liberate hazardous vapours. |
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Further information |
May explode when heated.Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx) |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.. |
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Precautions for safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
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Storage conditions |
No metal containers. Tightly closed and away from sources of ignition and heat. Observe national regulations. Air and moisture sensitive. |
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Storage class |
Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materialsStorage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
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Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Control parameters |
Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
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Skin Protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
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Body Protection |
Protective clothing |
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Respiratory protection |
Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Hygiene measures |
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. |
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Control of environmental exposure |
Do not let product enter drains. |
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Physical state |
Crystalline |
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Colour |
White |
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Odour |
Slight chlorine |
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Odor Threshold |
Not Applicable |
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pH |
2,5 - 3,5 at 50 g/l at 20 °C |
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Melting Point |
155 - 157 °C - dec. |
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Boiling Point |
No data available |
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Flash Point |
No data available |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
> 150 °C Heating may cause an explosion. |
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Vapour pressure |
0,001 hPa at 50 °C |
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Density |
1,67 g/cm3 at 25 °C - lit. |
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Relative Vapour Density |
No data available |
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Freezing point |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
No data available |
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Solubility |
470 g/l at 20 °C |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Sensitive to shock Risk of dust explosion. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed. |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
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Possibility of hazardous reactions |
Violent reactions possible with: alkaline substances Possible formation of: hydroxylamine Risk of explosion with: fire-promoting substances Oxidizing agents |
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Conditions to avoid |
Air Exposure to moisture. May be unstable at temperatures above: 75° C Heating (decomposition).no information available |
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Incompatible materials |
Aluminum, Copper, Zinc, Tin, Metals |
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - male and female - 642 mg/kg (OECD Test Guideline 401) Acute toxicity estimate Oral - 642 mg/kg (ATE value derived from LD50/LC50 value) Inhalation: No data available Acute toxicity estimate Dermal - 1.100,1 mg/kg (Expert judgment) Remarks: (Regulation (EC) No 1272/2008, Annex VI) |
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Skin corrosion/irritation |
Skin - In vitro study Result: Irritating to skin. - 42 min (OECD Test Guideline 439) |
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Serious eye damage/eye irritation |
Eyes - In vitro study Result: Eye irritation - 6 h |
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Respiratory or skin sensitization |
Maximization Test - Guinea pig Result: positive (OECD Test Guideline 406) |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
Presumed to have carcinogenic potential for humans |
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Germ cell mutagenicity |
Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells Metabolic activation: with and without metabolic activation Result: negative Remarks: (ECHA) Test Type: Rat Test system: Embryo Remarks: Morphological transformation. Test Type: Hamster Test system: Lungs Remarks: Sister chromatid exchange Test Type: Mutagenicity (mammal cell test): micronucleus. Species: Mouse Cell type: Red blood cells (erythrocytes) Application Route: Oral Method: OECD Test Guideline 474 Result: negative |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
No data available |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: NC3675000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Liver - Irregularities - Based on Human Evidence. |
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Bioaccumulative potential |
Bioaccumulation Cyprinus carpio (Carp) - 28 d - 0,1 mg/l(2-Toluidine) Bioconcentration factor (BCF): < 1,3 |
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Persistence and degradability |
Biodegradability aerobic - Exposure time 28 d Result: 88 - 90 % - Readily biodegradable. (OECD Test Guideline 301A) |
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Toxicity to fish |
Semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 1,78 mg/l - 96 h (OECD Test Guideline 203) |
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Toxicity to daphnia and other aquatic invertebrates |
Semi-static test EC50 - Daphnia magna (Water flea) - 1,1 mg/l - 48 h (OECD Test Guideline 202) |
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Toxicity to algae |
Static test EC50 - Pseudokirchneriella subcapitata - 0,21 mg/l - 72 h (OECD Test Guideline 201) |
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Toxicity to bacteria |
Static test EC10 - activated sludge - 1,7 mg/l - 3 h (OECD Test Guideline 209) |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
No data available |
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Disposal methods |
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
No data available |
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UN number |
ADR/RID: 3260 IMDG: 3260 IATA: 3260 |
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UN proper shipping name |
ADR/RID:CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Hydroxylammonium chloride)
IMDG: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Hydroxylammonium chloride)
IATA: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Hydroxylammonium chloride)
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Transport hazard class(es) |
ADR/RID: 8 IMDG: 8 IATA: 8 |
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Packaging group |
ADR/RID: III IMDG: III IATA: III |
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Environmental hazards |
ADR/RID: yes IMDG: yes IATA: NO |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Authorisations and/or restrictions on use |
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : 2-Toluidine REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles (Annex XVII) : 2-Toluidine |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. E1 ENVIRONMENTAL HAZARDS |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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