HexaMethyleneDiamine
- Part number
- RXSOL-19-3254-010
- Category
- Solvent Chemicals
- Brand
- RXSOL
Overview
Hexamethylenediamine formally hexane 1 6 diamine is a colorless low melting solid with an important industrial use It and
Applications
Hexamethylenediamine or hexane-1,6-diamine, is the organic compound with the formula H2N(CH2)6NH2. The molecule is a diamine, consisting of a hexamethylene hydrocarbon chain terminated with amine functional groups. The colorless solid (yellowish for some commercial samples) has a strong amine odor.
Dosage and directions
The colorless solid (yellowish for some commercial samples) has a strong amine odor.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Porduct Name | Hexamethylenediamine |
| Part Number | RXSOL-19-3254-010 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Name of substance | Hexamethylene diamine |
| Molecular formula | C₆H₁₆N₂ |
| Molar mass | 116,2 g /mol |
| CAS No | 124-09-4 |
| EC No | 204-679-6 |
| Index No (GB CLP) | 612-104-00-9 |
Substance, Specific Conc. Limits, M-factors, ATE
| Specific Conc. Limits | M-Factors | ATE | Exposure route |
|
1.160 mg/kg 1.900 mg/kg |
oral dermal |
| Hazard class | Category | Hazard class and category | Hazard statement |
| Acute toxicity (oral) | 4 | Acute Tox. 4 | H302 |
| Acute toxicity (dermal) | 4 | Acute Tox. 4 | H12 |
| Skin corrosion/irritation | 18 | Skin Corr. 1B | H14 |
| Serious eye damage/eye irritation | 1 | Eye Dam. 1 | H18 |
| Specific target organ toxicity - single exposure (respiratory tract irritation) | 3 | STOT SE 3 | H335 |
| Signal word |
Danger |
| Hazard statements | H302+H312 Harmful if swallowed or in contact with skin |
| H314 Causes severe skin burns and eye damage | |
| H335 May cause respiratory irritation | |
| Precautionary statements - prevention | P260 Do not breathe dust |
| P270 Do not eat, drink or smoke when using this product | |
| P280 Wear protective gloves/eye protection | |
| Precautionary statements - response | P302+P352 IF ON SKIN: Wash with plenty of water |
| P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing | |
| P310 Immediately call a POISON CENTER/doctor |
Other hazards
This material is combustible, but will not ignite readily.
| General notes | Take off immediately all contaminated clothing. Self-protection of the first aider. |
| Inhalation | Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. |
| Skin contact | After contact with skin, wash immediately with plenty of water. Immediate medical treatment required because corrosive injuries that are not treated are hard to cure. |
| Eye contact | In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. Protect uninjured eye. |
| Ingestion | Rinse mouth immediately and drink plenty of water. Rinse mouth with water (only if the person is conscious). Call a physician immediately. If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects). Call a doctor. |
Most important symptoms and effects, both acute and delayed
Corrosion, Vomiting, Risk of blindness, Gastric perforation, Risk of serious damage to eyes, Irritation, Cough, Dyspnoea
| Extinguishing media | |
| Suitable extinguishing media | Co-ordinate firefighting measures to the fire surroundings! water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder |
| Unsuitable extinguishing media | water jet |
| Special hazards arising from the substance or mixture | Combustible. Vapours are heavier than air, spread along floors and form explosive mixtures with air. |
| Hazardous combustion products | In case of fire may be liberated: Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO₂) |
| Advice for firefighters | In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing. |
| Personal precautions | Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not breathe dust. |
| Environmental precautions | Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. |
| Methods and material for containment and cleaning up |
Advice on how to contain a spill Covering of drains. Take up mechanically. Advice on how to clean up a spill Take up mechanically. Control of dust. Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. |
| Reference to other sections | Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13. |
| Precautions for safe handling |
Provision of sufficient ventilation. Handle and open container with care. Avoid dust formation. Clear contaminated areas thoroughly Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. |
| Conditions for safe storage, including any incompatibilities |
Store in a dry place. Keep container tightly closed. Hygroscopic. Incompatible substances or mixtures Protect against external exposure, such as humidity Recommended storage temperature: 15 – 25 °C |
| Specific end use(s) | No information available. |
Control parameters
National limit values
Relevant DNELs and other threshold levels
| Endpoint | Threshold level | Protection goal, route of exposure | Used in | Exposure time |
| DNEL | 0,54 mg/m³ | human, inhalatory | worker (industry) | chronic - local effects |
| DNEL | 1,62 mg/m³ | human, inhalatory | worker (industry) | acute - local effects |
Relevant PNECs and other threshold levels
| Endpoint | Threshold level | Organism | Environmental compartment | Exposure time |
| PNEC | 0,42 mg/l | aquatic organisms | freshwater | short-term (single instance) |
| PNEC | 0,04 mg/l | aquatic organisms | marine water | short-term (single instance) |
| PNEC | 29,1 mg/l | aquatic organisms | sewage treatment plant (STP) | short-term (single instance) |
| PNEC | 65,35 mg/kg | aquatic organisms | freshwater sediment | short-term (single instance) |
| PNEC | 6,54 mg/kg | aquatic organisms | marine sediment | short-term (single instance) |
| PNEC | 3,52 mg/kg | terrestrial organisms | soil | short-term (single instance) |
Exposure controls
Individual protection measures (personal protective equipment)
| Eyes | Use safety goggle with side protection. Wear face protection. |
| Skin | Wear appropriate gloves to prevent skin exposure. |
| Hand protection | Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effective layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred to substance mixtures, they may only be considered as a guide. |
| other protection measures | Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. |
| Respiratory protection | Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). Type: A-P2 (combined filters against particles and organic gases and vapours, colour code: Brown/White). |
| Environmental exposure controls | Keep away from drains, surface and ground water. |
| Physical State | Solid |
| Form | Solidified melt |
| Colour | White |
| Odour | like: - amine |
| Melting point/freezing point | 38 – 42 °C |
| Boiling point or initial boiling point and boiling range | 199 – 204 °C at 1.013 hPa |
| Flammability | This material is combustible, but will not ignite readily |
| Lower and upper explosion limit | 0,9 vol% (LEL) - 7,6 vol% (UEL) |
| Flash point | 85 °C at 1.024 hPa (ECHA) |
| Auto-ignition | Temperature not determined |
| Water solubility | 637 g /l at 20 °C (ECHA) |
| Partition coefficient n-octanol/water | (log value): 0,02 (25 °C) (OECD 107) |
| Vapour pressure | 10 hPa at 78,47 °C |
| Density | 0,83 g /cm³ at 20 °C |
| Relative vapour density | 3,8 (air = 1) |
| Particle characteristics | No data available. |
| Oxidising properties | none |
| Information with regard to physical hazard classes: | Hazard classes acc. to GHS (physical hazards): not relevant |
| Surface tension | 71,5 mN/m (20 °C) (ECHA) |
| Reactivity | The product in the delivered form is not dust explosion capable; the enrichment of fine dust however leads to the danger of dust explosion. |
| Chemical stability | The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. |
| Possibility of hazardous reactions | Possibility of hazardous reactions Violent reaction with: strong oxidiser, Strong acid |
| Conditions to avoid | Humidity. |
| Incompatible materials | Aluminium, copper, zinc |
| Hazardous decomposition products | Hazardous combustion products: see section 5. |
Information on toxicological effects
Acute toxicity
Harmful if swallowed. Harmful in contact with skin.
| Exposure route | Endpoint | Value | Species | Source |
| oral | LD50 | 1.160 mg/kg | rat | ECHA |
| dermal | LD50 | 1.900 mg/kg | rat | ECHA |
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics
| If swallowed | If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects) |
| If in eyes | causes burns, Causes serious eye damage, risk of blindness |
| If inhaled | Irritation to respiratory tract, cough, Dyspnoea |
| If on skin | causes severe burns, causes poorly healing wounds |
| Other information | none |
Endocrine disrupting properties
Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.
Information on other hazards
There is no additional information.
Toxicity
Shall not be classified as hazardous to the aquatic environment.
Aquatic toxicity (acute)
| Endpoint | Value | Species | Source | Exposure time |
| LC50 | 1.825 mg/l | fish | ECHA | 96 h |
| EC50 | 23,4 mg/l | aquatic invertebrates | ECHA | 48 h |
Aquatic toxicity (acute)
| Endpoint | Value | Species | Source | Exposure time |
| ErC50 | >100 mg/l | algae | ECHA | 72 h |
Aquatic toxicity (chronic)
| Endpoint | Value | Species | Source | Exposure time |
| ErC50 | 1.558 mg/l | microorganisms | ECHA |
3 h |
Persistence and degradability
Theoretical Oxygen Demand (without nitrification): 2,34 mg/mg
Theoretical Oxygen Demand (with nitrification): 2,926 mg/mg
Theoretical Carbon Dioxide: 2,272 mg/mg
Biodegradation
The substance is readily biodegradable.
Bioaccumulative potential
Does not significantly accumulate in organisms.
Mobility in soil
Data are not available.
Results of PBT and vPvB assessment
Data are not available.
Endocrine disrupting properties
Does not contain an endocrine disruptor (ED) at a concentration of ≥ 0,1%.
Other adverse effects
Data are not available.
Waste treatment methods
This material and its container must be disposed of as hazardous waste. Dispose of contents/container in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Handle contaminated packages in the same way as the substance itself. Completely emptied packages can be recycled.
Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process.
Remarks
Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities. Please consider the relevant national or regional provisions. Non-contaminated packages may be recycled.
UN number or ID number
| ADRRID | UN 2280 |
| IMDG-Code | UN 2280 |
| ICAO-TI | UN 2280 |
UN proper shipping name
| ADRRID | HEXAMETHYLENEDIAMINE, SOLID |
| IMDG-Code | HEXAMETHYLENEDIAMINE, SOLID |
| ICAO-TI | Hexamethylenediamine, solid |
Transport hazard class(es)
| ADRRID | 8 |
| IMDG-Code | 8 |
| ICAO-TI | 8 |
Packing group
| ADRRID | III |
| IMDG-Code | III |
| ICAO-TI | III |
| Environmental hazards | non-environmentally hazardous acc. to the dangerous goods regulations |
Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.
Information for each of the UN Model Regulations
Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)Additional information
| Proper shipping name |
HEXAMETHYLENEDIAMINE, SOLID |
| Particulars in the transport document | UN2280, HEXAMETHYLENEDIAMINE, SOLID, 8, III, (E) |
| Classification code | C8 |
| Danger label(s | 8 |
| Excepted quantities (EQ) | E1 |
| Limited quantities (LQ) | 5 kg |
| Transport category (TC) | 3 |
| Hazard identification No | 80 |
International Maritime Dangerous Goods Code (IMDG) - Additional information
| Proper shipping name | HEXAMETHYLENEDIAMINE, SOLID |
| Particulars in the shipper's declaration | UN2280, HEXAMETHYLENEDIAMINE, SOLID, 8, III |
| Marine pollutant | - |
| Danger label(s) | 8 |
| Excepted quantities (EQ) | E1 |
| Limited quantities (LQ) | 5 kg |
| EmS | F-A, S-B |
| Stowage category | A |
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
| Proper shipping name | Hexamethylenediamine, solid |
| Particulars in the shipper's declaration | UN2280, Hexamethylenediamine, solid, 8, III |
| Danger label(s) | 8 |
| Excepted quantities (EQ) | E1 |
| Limited quantities (LQ) | 5 kg |
Safety, health and environmental regulations/legislation specific for the substance or mixture Relevant provisions of the European Union (EU)
Seveso Directive
2012/18/EU (Seveso III)
| Dangerous substance/hazard categories | Qualifying quantity (tonnes) for the application of lower and upper-tier requirements |
| not assigned |
Deco-Paint Directive
VOC content 100 %
VOC content 830 g /l
Industrial Emissions Directive (IED)
VOC content 100 %
VOC content 830 g /l
Directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS)
not listed
Regulation concerning the establishment of a European Pollutant Release and Transfer Register (PRTR)
not listed
Regulation on the marketing and use of explosives precursors
not listed
Regulation on drug precursors not listed Regulation on substances that deplete the ozone layer (ODS)
not listed
Regulation concerning the export and import of hazardous chemicals (PIC)
not listed
Regulation on persistent organic pollutants (POP)
not listed
National regulations(GB) List of substances subject to authorisation (GB REACH, Annex 14) / SVHC - candidate list
not listed
Restrictions according to GB REACH, Annex 17
not listed
Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Chemical safety assessment
No Chemical Safety Assessment has been carried out for this substance.
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
| No information available |
| No information available |
| No information available |
| No information available |
