ISO-BUTYL ACETATE FOR SYNTHESIS
- Part number
- RXSOL-60-6604-748
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
A common method for preparing isobutyl acetate is Fischer esterification, where precursors isobutyl alcohol and acetic acid are heated in the presence of a strong acid. Isobutyl acetate has three isomers: n-butyl acetate, tert-butyl acetate, and sec-butyl acetate, which are also common solvents.
Applications
Isobutyl Acetate is a clear, colorless liquid with a pleasant, fruity odor. It is used as a solvent and in perfumes and artificial fruit-flavoring agents.
Dosage and directions
butyl ethanoate, is an ester that is a colorless, flammable liquid at room temperature. It is found in many types of fruit, where along with other chemicals, it imparts characteristic flavors and has a sweet smell of banana or apple.
Characteristics and notes
A common method for preparing isobutyl acetate is Fischer esterification, where precursors isobutyl alcohol and acetic acid are heated in the presence of a strong acid.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | iso-BUTYL ACETATE FOR SYNTHESIS | |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : ISO BUTYL ACETATE
CAS No :110-19-0
Substance. Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : F; R11 R66
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Physical hazards : Flammable liquids - Category 2 - Danger (CLP : Flam. Liq. 2) H225
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F : Highly flammable
R Phrase(s) : R11 : Highly flammable.
R66 : Repeated exposure may cause skin dryness or cracking.
S Phrase(s) : S16 : Keep away from sources of ignition - No smoking.
S23 : Do not breathe the gas, fumes, vapours, spray.
S25 : Avoid contact with eyes.
S29 : Do not empty into drains.
S33 : Take precautionary measures against static discharges.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H225 : Highly flammable liquid and vapour.
Precautionary statements
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P233: Keep container tightly closed.
• Response : P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing.
Rinse skin with water/shower. P370+P378: In case of fire: Use for extinction.
• Storage : P403+P235: Store in well-ventilated place. Keep cool.
• Disposal considerations : P501: Dispose of this material and its container
to hazardous or special waste collection point, in accordance with
local, regional, national and/or international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest.
Skin contact : Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing.
Eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain,
blinking or redness persist. Ingestion : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Repeated exposure may cause skin dryness or cracking.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If you feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Highly flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights.
No smoking. For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters.
Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash hands and other exposed areas with mild soap
and water before eat, drink or smoke and when leaving work.
Handle empty containers with care because residual vapours are flammable.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be followed.
Use explosion-proof electrical, ventilating, lighting, …, equipment.
Special precautions : No naked lights. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place.
Keep in fireproof place. Keep container tightly closed. Ground/bond container
and receiving equipment. Storage - away from : Strong bases. Strong acids.
Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -78 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 421 °C
Flammability (solid, gas) : Highly flammable liquid and vapour.
Flammable. Flash point [°C] : 23 °C
Boiling point [°C] : 124 - 126 °C
Initial boiling point [°C] : 124°C
Final boiling point [°C] : 126 °C
Evaporation rate : 1,5
Vapour pressure [20°C] : 20 hPa at 20 °C
Vapour pressure mm/Hg : N/A
Vapour density : 4 Density [g/cm3] : 0,871
Relative density, gas (air=1) : 4,01
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Partially soluble.
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 7 Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : 7,60%
Explosion limits - lower [%] : 1,70%
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under
recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight.
Extremely high or low temperatures.
Open flame. 10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes.
Carbon monoxide. Carbon dioxide. May release flammable gases.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Repeated exposure may cause skin dryness or cracking.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance
does not fulfil the criteria to be identified as PBT substance
or vPvB substance according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in
a safe manner in accordance with local/national regulations.
Dispose of this material and its container to hazardous or special
waste collection point, in accordance with local, regional, national
and/or international regulation. Special precautions : Handle empty
containers with care because residual vapours are flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : ISOBUTYL ACETATE
UN N° : 1213
H.I. nr : 33
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid.
ADR - Classification code : F1
ADR - Group : II
ADR - Packing instructions : P001 R001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank
carriage: Passage forbidden through tunnels of category D and E.
Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ISOBUTYL ACETATE
UN N° : 1213
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No EMS-Nr : F-E S-D
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ISOBUTYL ACETATE
UN N° : 1213
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED -
Passenger and Cargo - Packing : 353
instruction - Passenger and Cargo - Maximum : 5 L
Quantity/Packing IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 364 -
Cargo only - Maximum Quantity/ : 60 L
Packing IATA - Limited Quantites : 1 L
ERG-Nr : 3L
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Safety,
health and environmental : Ensure all national/local regulations are observed. regulations/legislation
specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS
was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied,
regarding its correctness. The conditions or methods of handling,storage, use or disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or
expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is
to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
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