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Lab Chemical

ISOPHTHALIC ACID 99%

Part number
RXSOL-60-6604-751
Category
Lab Chemical
Brand
RXSOL
RXSOL

Overview

Isophthalic acid, 99% Cas 121-91-5 - used as an intermediate primarily for unsaturated polyester resins and alkyd and polyester coating resins; other applications include use in aramid fibers, as a component of copolyester resins and in high-temperature polymers.

Applications

Purified isophthalic acid (PIA) is mainly used as an intermediate in the production of unsaturated polyester resins, followed by polyester and alkyd resins (mainly for surface coatings) and inks, reinforced plastics and packaging applications.

Dosage and directions

a crystalline diacid C6H4(COOH)2 isomeric with phthalic acid made usually by oxidation of meta- xylene and used in making synthetic resins and esters for use as plasticizers; meta- benzene-dicarboxylic acid.

Characteristics and notes

Isophthalic acid is produced on the billion kilogram per year scale by oxidizing meta-xylene using oxygen. The process employs a cobalt-manganese catalyst. The world's largest producer of isophthalic acid is Lotte Chemical Corporation.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product Name               ISOPHTHALIC ACID 99%
Part Number   RXSOL-60-6604-751

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
Website www.rxmraine.com
Chemical  Name                            CAS                    EC number          Weight                  Formula                     
Isophthalic acid 121-91-5 204-506-4 <= 100 % C8H6O4 
Signal Word  Danger
Hazard Statements H251 Self-heating; may catch fire. H314 Causes severe skin burns and eye damage.
P280 Wear    protective gloves.P305 + P351 + P338 Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Precautionary statements   P235 Keep cool. P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard      Statements EUH014 Reacts violently with water.
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 
General advice First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled  If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Eye Contact Flush eyes with water as a precaution.
Swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water.
Skin Contact Wash off with soap and plenty of water.
Inhalation Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. 
Ingestion Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed  No data available
Flammability                                                  May be combustible at high temperature.
Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media Foam Water
Special hazards arising from the substance or mixture  Carbon oxides
Further information No data available
Hazardous combustion
products
Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.
Protective Equipment Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Specific Hazards Arising from the Chemical Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours.
Personal precautions, protective equipment and emergency procedures Avoid dust formation. Avoid breathing vapors, mist or gas. For personal protection see section 8.
Spillage Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution No special environmental precautions required.
Methods and materials for
containment and cleaning
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Advice on safe handling  Keep workplace dry. Do not allow product to come into contact with water.
Advice on protection against fire and explosion Provide appropriate exhaust ventilation at places where dust is formed.
Incompatible materials  Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. 
Hygiene measures General industrial hygiene practice. For precautions see section 2.2.
Precautions for     safe handling For precautions see section 2.2. 
Conditions for safe storage, including any incompatibilities  Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
Storage conditions Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Storage class Storage class (TRGS 510): 13: Non Combustible Solids
Specific end     use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage  Keep in cool and store under shade. 
Exposure controls  No specific additional engineering controls are required. Provide good natural or artificial ventilation. 
Engineering Control Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. 
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Respiratory protection Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Other Protection      Measure Handle in accordance with good industrial hygiene and safety practice.
Control of    environmental exposure No special environmental precautions required.

                                                                                                   

                                                                      Gloves                       Suit                          

Physical state Powder
Colour Beige
Odour No data available 
Odor Threshold Not Applicable
pH No data available 
Melting Point 341 - 343 °C - lit.
Boiling Point No data available 
Flash Point No data available
Evaporation Rate Not Applicable
Flammability (solid, gas) No data available
Explosive limits No Data Available
Lower flammability or explosive limits No data available )
Viscosity, kinematic/dynamic No data available 
Autoignition temperature No data available 
Decomposition temperature  No data available
Vapour pressure No data available  
Density 1,53 g/cm3 at 25 °C
Vapour Density No Data Available
Freezing point  No data available 
Specific Gravity No data available 
Partition coefficient log Pow: 0,005 at 22 °C  
Explosive properties No data available 
Solubility ca.0,12 g/l at 25 °C
Ignition temperature No information available.
Particle characteristics No data available 
Reactivity                        No data available
Stability Stable under recommended storage conditions.
Possibility of hazardous reactions No data available
Conditions to avoid No data available
Incompatible materials Strong oxidizing agents, Strong bases
Hazardous Polymerization In the event of fire: see section 5
Acute toxicity  LD50 Oral - Rat - male and female - > 5.000 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - male and female - 4 h - > 11.370 mg/m3 - dust/mist (OECD Test Guideline 403) LD50 Dermal - Rabbit - male and female - > 2.000 mg/kg (OECD Test Guideline 402)
Skin corrosion/irritation Skin - Rabbit Result: No skin irritation - 4 h (OECD Test Guideline 404)
Serious eye      damage/eye       irritation  Eyes - Rabbit Result: No eye irritation - 2 s (OECD Test Guideline 405)
Respiratory or skin    sensitization  Maximization Test - Guinea pig Result: Does not cause skin sensitization. (OECD Test Guideline 406)
Toxicity to Animal WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat].
Toxic Effects on         Human May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Carcinogenicity No data available
Germ cell        mutagenicity  Test Type: Hamster Test system: ovary Metabolic activation: with and without metabolic activation Result: negative
Specific target organ toxicity - single      exposure No data available
Special Remarks on other Toxi  Effects on Humans Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Additional Information RTECS: NT2007000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Persistence and degradability Biodegradability aerobic - Exposure time 14 d Result: 85 % - Readily biodegradable. (OECD Test Guideline 301B)
Toxicity to fish  Static test LC50 - Leuciscus idus melanotus - > 907 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates Static test EC50 - Daphnia magna (Water flea) - > 952 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae Static test ErC50 - Desmodesmus subspicatus (green algae) - > 1.000 mg/l - 96 h (OECD Test Guideline 201)
Bioaccumulative potential Does not bioaccumulate.
Mobility in soil No Information available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects No data available
Disposal methods The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging Dispose of as unused product.
Waste treatment      Method Offer surplus and non-recyclable solutions to a licensed disposal company.
UN number ADR/RID:      IMDG:      IATA:   
UN proper shipping name  ADR/RID:      IMDG:      IATA:   
Transport hazard class(es)      ADR/RID:             IMDG:         IATA:  
Packaging group ADR/RID:             IMDG:        IATA:  
Environmental hazards ADR/RID: No   IMDG: No       IATA: No
Special precautions for user Tunnel restriction code : (C/E) 
Further information Not classified as dangerous in the meaning of transport regulations.
Transport in bulk according to IMOinstruments No data available
Inventory status Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. 
Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations specific for the product in question European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed.
National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : OTHER HAZARDS
Other regulations Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out
Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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Availability

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