Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
3.1. Substance : LEAD CHROMATE AR
Substance. Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
R Phrase(s) :R61: May cause harm to unborn child.
R33: Danger of cumulative effects.
R40 : Possible risk of very serious irreversible effects.
long-term adverse effect in the aquatic environment.
R62: Possible risk of impaired fertility.
S Phrase(s) : S53 : Avoid exposure – obtain special instruction before use.
advice immediately (show the label where possible).
S60: This material and its container must be disposed of as hazardous waste.
S61 : Avoid release to the environment . refer to special instruction/safety data sheets.
Hazard pictograms Signal word : Danger. Hazard statements : H350 -
Very toxic to aquatic life with long lasting effects Precautionary statements : P201 - O
Do not handle until all safety precautions have been read and understood P273 -
Wear protective gloves/protective clothing/eye protection/face protection P308+P313 -
IF exposed or concerned: Get medical advice/attention P391 - Collect spillage P405 -
Store locked up P501 - Dispose of contents/container to ...
3.3. Other hazards This substance/mixture
substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
4.1. Description of first aid measures
First-aid measures general : IF exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
Give oxygen or artificial respiration if necessary.
If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes.
If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause cancer. Suspected of damaging fertility.
May damage the unborn child. There are potential chronic health effects to consider.
4.3. Indication of any immediate medical attention and special treatment needed
51. Extinguishing media
Suitable extinguishing media : Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
No additional information available
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
No additional information available
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Hygiene measures : Wash hands and other exposed areas with mild soap
and water before eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
No additional information available
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate
(butylacetate=1) : No data available
Melting point : 844 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 6.3 g/cm³
Solubility : Water: Negligible
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
No additional information available
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer. Reproductive
toxicity : May damage the unborn child.
Suspected of damaging fertility. Specific
target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Additional information : There are potential chronic health effects
to consider Aspiration hazard : Not classified
12.1. Toxicity
Ecology - water : Very toxic to
aquatic life with long lasting effects.
12.2. Persistence and degradability
Persistence and degradability May
cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
This substance/mixture does not meet the PBT
criteria of REACH regulation, annex XIII This substance/mixture
does not meet the vPvB criteria of REACH regulation, annex XIII
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods Product/Packaging
disposal recommendations : Dispose of contents/container to ...
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3077
UN-No. (IMDG) : 3077
UN-No.(IATA) : 3077
UN-No.(ADN) : 3077
UN-No. (RID) : 3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (ADN) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) : UN 3077
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III, (E)
Transport document description (IMDG) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III,
MARINE POLLUTANT Transport document description (IATA) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (ADN) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (RID) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
14.3. Transport hazard class(es)
ADR: Transport hazard class(es) (ADR) : 9
Danger labels (ADR) : 9
IMDG : Transport hazard class(es) (IMDG) : 9
Danger labels (IMDG) : 9
IATA: Transport hazard class(es) (IATA) : 9
Hazard labels (IATA) : 9
AND: Transport hazard class(es) (ADN) : 9
Danger labels (ADN) : 9
RID: Transport hazard class(es) (RID) : 9
Danger labels (RID) : 9
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes Other information : No supplementary information available
14.6. Special precautions for user
Overland transport-Classification code (ADR) : M7
Special provision (ADR) : 274, 335, 601, 375
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : PP12, B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T1, BK1, BK2
Portable tank and bulk container special provisions (ADR) : TP33
Tank code (ADR) : SGAV, LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3
Special provisions for carriage – Packages (ADR) : V13
Special provisions for carriage – Bulk (ADR) : VC1, VC2
Special provisions for carriage - Loading,
unloading and handling (ADR) : CV13
Hazard identification number (Kemler No.) : 90
Orange plates : Tunnel restriction code (ADR) : E EAC
code : 2Z Transport by sea- Special provision
(IMDG) : 274, 335, 966, 967, 969
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002, LP02
Packing provisions (IMDG) : PP12 IBC
packing instructions (IMDG) : IBC08 IBC
special provisions (IMDG) : B3
Tank instructions (IMDG) : T1, BK1, BK2, BK3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW23
MFAG-No : 171
Air transport--
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y956
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 956
PCA max net quantity (IATA) : 400kg
CAO packing instructions (IATA) : 956
CAO max net quantity (IATA) : 400kg
Special provision (IATA) : A97, A158,
A179, A197 ERG code (IATA) : 9L
Inland waterway transport-
Classification code (ADN) : M7
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T* B**
Equipment required (ADN) : PP, A
Number of blue cones/lights (ADN) : 0
Rail transport-
Classification code (RID) : M7
Special provision (RID) : 274, 335, 375, 601
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : PP12, B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container instructions (RID): T1, BK1, BK2
Portable tank and bulk container special provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAV, LGBV Transport category (RID) : 3
Special provisions for carriage – Packages (RID): W13
Special provisions for carriage – Bulk (RID) : VC1, VC2
Special provisions for carriage – Loading and unloading (RID): CW13, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations No REACH Annex XVII restrictions Lead chromate is on the REACH Candidate List
Lead chromate is on the REACH Annex XIV List: Authorisation number Sunset date
REACH authorization exemptions 21/05/2015
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK No 7885)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed
to use the product Pregnant/breastfeeding women working with the product must not be in direct
contact with the product The requirements from the Danish Working Environment Authorities
regarding work with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.