Latex Emulsion PRIMER

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Non-hazardous:
Pigmented Latex emulsion coating comprised of water, pigments, fillers, additives,
and latex emulsion resin.

Hazardous:
Chemical Name           CAS No.         Percent           Exposure Limits

1 - Titanium dioxide  13463-67-7        < 25.0                ACGIH TLV
                                                                                         10 mg/m3 as Dust
                                                                                                OSHA PEL
                                                                                  10 mg/m3 as Total Dust
                                                                                  5 mg/m3 Respirable Fraction
2 - Ethylene glycol   107-21-1          < 5.0                    OSHA PEL
                                                                 50 ppm
Note: Normal application procedures pose no hazard since titanium dioxide is wetted and encapsulated, but grinding or sanding dried films of this product may yield respirable titanium dioxide dust. Control exposures to less than 0.1 mg/m3 using NIOSH/MSHA-approved dust filter respirators.
 

Note: Per 29CFR 1910.1200 (g) (2) (1) (C) (2), only hazardous substances present in excess of 1.0% by weight (or 0.1% for carcinogens) must be listed on an MSDS.

Emergency Overview:

Product Description: This product is a pigmented liquid.

Health Hazards:

Eyes: May cause slight irritation.

Skin: Substance may cause slight skin irritation.

Inhalation: May cause irritation of respiratory tract.

Ingestion: Ingestion may cause gastrointestinal irritation, nausea, and vomitting.

Flammability Hazards: This product is not flammable. If this product is involved in a fire, the decomposition products generated will include irritating vapors and gases and some carbon monoxide.

Reactivity Hazards: This product is not reactive.

Environmental Hazards: Although release of this product to the environment is not expected to cause significant adverse effect, all releases should be avoided.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and consult physician.

Skin: Wash skin thoroughly with soap and water. If drenched with product, remove and wash clothing before reuse.

Ingestion: Ingestion If victim is conscious give 2 glasses of water. Call a physician.

Inhalation: N/A

Product is non-combustible.

Flash point:                 Autoignition Temperature:
F: Not flammable         F: Not Established
C: Not flammable         C: Not Established

Extinguishing Media:

Use extinguishing media appropriate for surrounding fire

Water Spray:OK
Carbon Dioxide :OK
Foam : OK
Dry Chemical : OK
Halon : OK
Other :Any “ABC” Class

Accidental Release Measures:

Personal Precautions: Do not get in eyes. Do not take internally. Avoid skin contact. Prevent prolonged or repeated breathing of vapor or spray mists. Keep unnecessary people away. Floor may be slippery, use care to avoid falling. Ventilate the area. Remove with inert absorbent.

Environmental Precautions: Keep spills and cleaning run-offs out of municipal sewers and open bodies of water. Comply with local, state and national regulations.

Handling and Storage:

Storage: Store in a cool, dry place

Keep closure tight and containers upright to prevent leakage.

Precautionary labeling: “KEEP FROM FREEZING”.

Precautions: Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using.

This coating may contain materials classified as nuisance particulates (listed “as Dust” in Section 2) which may be present at hazardous levels only during the sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/ m3 (respirable fraction), OSHA PEL 10 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

Work Hygienic Practices: Avoid contact with skin. Do not get in eyes. Do not take internally. Avoid breathing vapors or spray mists.

Ventilation: Use in well-ventilated areas. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits.

Refer to OSHA Standards 1910.94, 1910.107, 1910.108.

Respiratory Protection: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying  paint, or the abrasive.

Eye Protection: Use approved safety eyewear including side shields, chemical goggles or face shields.

Skin Protection: Wear neoprene or rubber gloves to prevent skin contact if prolonged skin contact is likely. Wash hands before eating, smoking or using the wash room.

Stability: Stable

Incompatibility: (Material to Avoid): Avoid contact with strong oxidizing agents (e.g. nitric acid, permanganates), etc.

Hazardous Decomposition or By-Products: Some carbon monoxide.

Hazardous Polymerization: Will not occur. 

Toxicological Information: Chronic Health Hazards IARC’s Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, “No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint.”

Toxicology Data

Chemical Name                                         CAS No.                                    LD50

Titanium dioxide                                   13463-67-7 Oral:                  >24000 mg/kg (Rat)

                                                                                                          Dermal: >10000 mg/m3 (rabbit)

                                                                                                          Inhalation (Dust): >6.82 mg/L (Rat, 4hr.)

Ethylene glycol                                      107 -21-1                             Oral: 8.54 g/kg (Rat)

Ecological Information:

Well-diluted product will have no environmental consequences. Less than 5% Ethylene glycol present in this product yields the following environmental considerations: Ethylene glycol is 100% volatile. Once volatilized it will react in the atmosphere with hydroxyl radicals with a half-life on about 1 day. For accidental spills, note that Ethylene glycol in typical river water at 20°C was found to completely degrade in 3 days. At temperatures of 8°C, degradation occurred in 7 days. Toxicity to fish: LD50 Carrasisus auratus (goldfish) greater than 5,000 gl/L/24 hour. Modified ASTM D 1345. Algea:(Chlorella pyrenoidosa) 180,000 mg/L toxic.

Waste Disposal Method:

Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. If incinerating, do so in an approved facility, and do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

U.S. Department of Transportation

Proper Shipping Name: Non-Hazardous Water-Based Paint

Hazard Class: “Not Regulated”

Label Statement: “Keep From Freezing”

Class 55 Non-Hazardous Water-Based Paint

Canada (TDG)

Not Regulated for Transportation.

IMO

Not Regulated for Transportation.

U.S. Federal Regulations:

TSCA (TOXIC SUBSTANCE CONTROL ACT): All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Non-hazardous:
Pigmented Latex emulsion coating comprised of water, pigments, fillers, additives,
and latex emulsion resin.

Hazardous:
Chemical Name           CAS No.         Percent           Exposure Limits

1 - Titanium dioxide  13463-67-7        < 25.0                ACGIH TLV
                                                                                         10 mg/m3 as Dust
                                                                                                OSHA PEL
                                                                                  10 mg/m3 as Total Dust
                                                                                  5 mg/m3 Respirable Fraction
2 - Ethylene glycol   107-21-1          < 5.0                    OSHA PEL
                                                                 50 ppm
Note: Normal application procedures pose no hazard since titanium dioxide is wetted and encapsulated, but grinding or sanding dried films of this product may yield respirable titanium dioxide dust. Control exposures to less than 0.1 mg/m3 using NIOSH/MSHA-approved dust filter respirators.
 

Note: Per 29CFR 1910.1200 (g) (2) (1) (C) (2), only hazardous substances present in excess of 1.0% by weight (or 0.1% for carcinogens) must be listed on an MSDS.

Emergency Overview:

Product Description: This product is a pigmented liquid.

Health Hazards:

Eyes: May cause slight irritation.

Skin: Substance may cause slight skin irritation.

Inhalation: May cause irritation of respiratory tract.

Ingestion: Ingestion may cause gastrointestinal irritation, nausea, and vomitting.

Flammability Hazards: This product is not flammable. If this product is involved in a fire, the decomposition products generated will include irritating vapors and gases and some carbon monoxide.

Reactivity Hazards: This product is not reactive.

Environmental Hazards: Although release of this product to the environment is not expected to cause significant adverse effect, all releases should be avoided.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes and consult physician.

Skin: Wash skin thoroughly with soap and water. If drenched with product, remove and wash clothing before reuse.

Ingestion: Ingestion If victim is conscious give 2 glasses of water. Call a physician.

Inhalation: N/A

Product is non-combustible.

Flash point:                 Autoignition Temperature:
F: Not flammable         F: Not Established
C: Not flammable         C: Not Established

Extinguishing Media:

Use extinguishing media appropriate for surrounding fire

Water Spray:OK
Carbon Dioxide :OK
Foam : OK
Dry Chemical : OK
Halon : OK
Other :Any “ABC” Class

Accidental Release Measures:

Personal Precautions: Do not get in eyes. Do not take internally. Avoid skin contact. Prevent prolonged or repeated breathing of vapor or spray mists. Keep unnecessary people away. Floor may be slippery, use care to avoid falling. Ventilate the area. Remove with inert absorbent.

Environmental Precautions: Keep spills and cleaning run-offs out of municipal sewers and open bodies of water. Comply with local, state and national regulations.

Handling and Storage:

Storage: Store in a cool, dry place

Keep closure tight and containers upright to prevent leakage.

Precautionary labeling: “KEEP FROM FREEZING”.

Precautions: Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using.

This coating may contain materials classified as nuisance particulates (listed “as Dust” in Section 2) which may be present at hazardous levels only during the sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/ m3 (respirable fraction), OSHA PEL 10 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

Work Hygienic Practices: Avoid contact with skin. Do not get in eyes. Do not take internally. Avoid breathing vapors or spray mists.

Ventilation: Use in well-ventilated areas. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits.

Refer to OSHA Standards 1910.94, 1910.107, 1910.108.

Respiratory Protection: If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying  paint, or the abrasive.

Eye Protection: Use approved safety eyewear including side shields, chemical goggles or face shields.

Skin Protection: Wear neoprene or rubber gloves to prevent skin contact if prolonged skin contact is likely. Wash hands before eating, smoking or using the wash room.

Stability: Stable

Incompatibility: (Material to Avoid): Avoid contact with strong oxidizing agents (e.g. nitric acid, permanganates), etc.

Hazardous Decomposition or By-Products: Some carbon monoxide.

Hazardous Polymerization: Will not occur. 

Toxicological Information: Chronic Health Hazards IARC’s Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, “No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint.”

Toxicology Data

Chemical Name                                         CAS No.                                    LD50

Titanium dioxide                                   13463-67-7 Oral:                  >24000 mg/kg (Rat)

                                                                                                          Dermal: >10000 mg/m3 (rabbit)

                                                                                                          Inhalation (Dust): >6.82 mg/L (Rat, 4hr.)

Ethylene glycol                                      107 -21-1                             Oral: 8.54 g/kg (Rat)

Ecological Information:

Well-diluted product will have no environmental consequences. Less than 5% Ethylene glycol present in this product yields the following environmental considerations: Ethylene glycol is 100% volatile. Once volatilized it will react in the atmosphere with hydroxyl radicals with a half-life on about 1 day. For accidental spills, note that Ethylene glycol in typical river water at 20°C was found to completely degrade in 3 days. At temperatures of 8°C, degradation occurred in 7 days. Toxicity to fish: LD50 Carrasisus auratus (goldfish) greater than 5,000 gl/L/24 hour. Modified ASTM D 1345. Algea:(Chlorella pyrenoidosa) 180,000 mg/L toxic.

Waste Disposal Method:

Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. If incinerating, do so in an approved facility, and do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

U.S. Department of Transportation

Proper Shipping Name: Non-Hazardous Water-Based Paint

Hazard Class: “Not Regulated”

Label Statement: “Keep From Freezing”

Class 55 Non-Hazardous Water-Based Paint

Canada (TDG)

Not Regulated for Transportation.

IMO

Not Regulated for Transportation.

U.S. Federal Regulations:

TSCA (TOXIC SUBSTANCE CONTROL ACT): All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY