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Product Name |
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Product Type |
MERCURIC CHLORIDE |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation : mercury dichloride; mercuric chloride
CAS No :7487-94-7
Substance.
Substance name Contents CAS No
mercury dichloride; mercuric : 100 % 7487-94-7
Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : Muta. Cat. 3; R68 Repr. Cat. 3; R62 T+; R28 T; R48/24/25 C; R34 N; R50-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Germ cell mutagenicity - Category 2 - Warning (CLP : Muta. 2) H341
Reproductive toxicity - Fertility - Category 2 - Warning (CLP : Repr. 2) H361
Specific Target Organ Toxicity - Repeated exposure - Category 1 - Danger (CLP : STOT RE 1) H372
Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318
Acute toxicity, Oral - Category 1 - Danger (CLP : Acute Tox. 1) H300
Skin corrosion - Category 1B - Danger (CLP : Skin Corr. 1B) H314
Environmental hazards : Hazardous to the aquatic environment
- Acute hazard - Category 1 - Warning (CLP : Aquatic Acute 1) H400
Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning ( CLP : Aquatic Chronic 1) H410
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : T+ : Very toxic N : Dangerous for the environment
R Phrase(s) : R28 : Very toxic if swallowed. R34 : Causes burns.
R48/24/25 : Toxic : danger of serious damage to health by prolonged exposure in contact with skin and if swallowed.
R62 : Possible risk of impaired fertility. R68 : Possible risks of irreversible effects.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase(s) : S1/2 : Keep locked up and out of reach of children.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S
36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible).
S60 : This material and its container must be disposed of as hazardous waste. S
61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H300 : Fatal if swallowed.
H314 : Causes severe skin burns and eye damage.
H341 : Suspected of causing genetic defects.
H361f : Suspected of damaging fertility.
H372 : Causes damage to organs through prolonged or repeated exposure.
H410 : Very toxic to aquatic life with long lasting effects. Precautionary statements
• General : P102: Keep out of reach of children. P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
P201: Obtain special instructions before use.
• Prevention : P280: Wear protective gloves, protective clothing, eye protection, face protection.
P260: Do not breathe dust, fume, gas, mist, vapours, spray. P273: Avoid release to the environment.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P301+P330+P331: IF SWALLOWED : Rinse mouth. Do NOT induce vomiting.
P308+P313: If exposed or concerned : get medical advice. P391: Collect spillage.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P314: Get medical advice if you feel unwell.
• Storage : P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor.
Skin contact : Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
Immediately call a POISON CENTER or doctor.
Eye contact : Immediately call a POISON CENTER or doctor. Remove contact lenses,
if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
Ingestion : Specific treatment (see on this label). Rinse mouth.
Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Suspected of causing genetic defects.
Causes damage to organs through prolonged or repeated exposure.
Fatal if swallowed. Causes severe skin burns and eye damage.
Causes serious eye damage. Suspected of damaging fertility.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If exposed or concerned : get medical advice.
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
Thermal decomposition generates : Corrosive vapours.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection. Special procedures : Exercise caution when fighting
any chemical fire. Avoid (reject) fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters.
Notify authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : On land, sweep or shovel into suitable containers.
Minimize generation of dust. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash thoroughly after handling. Do not eat, drink or smoke
when using this product. Wash contaminated clothing before reuse.
Do not breathe dust, fume, gas, mist, vapours, spray.
Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use personal protective equipment as required.
Obtain special instructions before use.
Technical protective measures : Provide good ventilation in process area to prevent formation of vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place.
Keep container closed when not in use. Storage regulation : Comply with applicable
regulations. Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or face shield.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : Not applicable.
Melting point [°C] : 277 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flash point [°C] : N/A
Boiling point [°C] : 302 °C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : 1 mm Hg @ 136.20C
Vapour density : 8,7
Density [g/cm3] : 5,4
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : 7.4g in 100g of wate
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 3.2
(0.2 M solution)
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases
. 10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide.
Carbon dioxide. Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Fatal if swallowed. Corrosion : Causes severe skin burns and eye damage.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Suspected of causing genetic defects. Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Suspected of damaging fertility.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Very toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance
does not fulfil the criteria to be identified as PBT substance
or vPvB substance according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance
with local/national regulations. Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or international regulation.
Special precautions : Hazardous waste due to toxicity.
14.1. Land transport (ADR-RID)
Proper shipping name : MERCURIC CHLORIDE
UN N° : 1624
H.I. nr : 60
ADR - Class : 6.1
Labelling - Transport : 6.1 : Toxic substances.
ADR - Classification code : T5
ADR - Group : II
ADR - Packing instructions : P002
ADR - Limited Quantity : 500
G ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of category D and E.
Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : MERCURIC CHLORIDE
UN N° : 1624
IMO-IMDG - Class or division : 6.1 : Toxic substances.
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P002
IMO-IMDG - Limited quantities : 500 g
IMO-IMDG - Marine pollution : Yes EMS-Nr : F-A S-A
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : MERCURIC CHLORIDE UN N° : 1624
IATA - Class or division : 6.1 : Toxic substances.
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED -
Passenger and Cargo - Packing : 669
instruction - Passenger and Cargo - Maximum : 25 kg
Quantity/Packing
IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 676 -
Cargo only - Maximum Quantity/ : 100 kg
Packing
IATA - Limited Quantites : 1 kg
ERG-Nr : 6L
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS
was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied
, regarding its correctness. The conditions or methods of handling,storage, use or disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or
expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is
to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.