METHYLAMINE SOLUTION 40%
- Part number
- RXSOL-60-6604-978
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Methylamine solution may be used as a LC-MS/MS mobile phase in the perchlorate analysis of milk and yogurt samples. It may be used in the synthesis of the following: 9-fluorenylmethyl N-methylcarbamate and tert-butyl N-methylcarbamate. It has a strong odor similar to fish. Methylamine is used as a building block for the synthesis of numerous other commercially available compounds.
It has a strong odor similar to fish. Methylamine is used as a building block for the synthesis of numerous other commercially available compounds.
It has a strong odor similar to fish. Methylamine is used as a building block for the synthesis of numerous other commercially available compounds.
Applications
Methylamine solution is a 33wt. % solution of methylamine in absolute ethanol. Methylamine is an aliphatic primary amine. It participates in the synthesis of isothiazolium salts. Chemical degradation of methylamine solution of γ-irradiated poly(ε-caprolactone) has been described.
Dosage and directions
Methylamine can irritate the lungs. Repeated exposure may cause bronchitis to develop with cough, phlegm, and/or shortness of breath. * High exposure may affect the liver.
Characteristics and notes
Methylamine must be stored to avoid contact with mercury, flammable materials, and strong oxidizers, (such as chlorine dioxide, or bromine), since violent reactions occur. Store in Tightly closed containers in a cool, well-ventilated area away from heat.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | METHYLAMINE SOLUTION 40% | |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : METHYLAMINE SOLUTION 40%
CAS No :74-89-5
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : F+; R12
Xn; R20
Xi; R37/38-41
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Specific Target Organ Toxicity - Single exposure - Respiratory tract
irritation - Category 3 - Warning (CLP : STOT SE 3) H335
Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318
Physical hazards : Flammable liquids - Category 1 - Danger (CLP: Flam. Liq. 1) H224
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F+ : Extremely flammable
Xn : Harmful
R Phrase(s) : R11 : Highly flammable.
R20/22 : Harmful by inhalation and if swallowed
R34 : Cause burns R37/38 : Irritating to respiratory system and skin.
R41 : Risk of serious damage to eyes.
S Phrase(s) : S3 : Keep in a cool place.
S16 : Keep away from sources of ignition - No smoking.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S29 : Do not empty into drains.
S36/37/39 : Wear suitable protective clothing and gloves & eye/face protecting
S39 : Wear eye/face protection.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible)
. Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H224 : Extremely flammable liquid and vapour.
H318 : Causes serious eye damage.
H315 : Causes skin irritation.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
Precautionary statements
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P233: Keep container tightly closed. P264: Wash thoroughly after handling.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P332+P313: If skin irritation occurs : Get medical advice.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing.
Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P403+P235: Store in well-ventilated place. Keep cool.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Call a POISON CENTER or doctor if you feel unwell. Remove to fresh air
and keep at rest in a position comfortable for breathing.
Skin contact : Wash contaminated clothing before reuse. If skin irritation occurs :
Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and
water. Get medical advice. Specific treatment (see on this label).
Eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Ingestion : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Danger of serious damage to health by prolonged exposure
through inhalation. Causes serious eye damage. Causes skin irritation. May cause
respiratory irritation.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Extremely flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours are flammable.
Wash thoroughly after handling. Wash thoroughly after handling. Use only outdoors or in a
well-ventilated area. Avoid breathing dust, fume, gas, mist, vapours, spray. Wash
thoroughly after handling. Take precautionary measures against static discharge.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed. Use explosion-proof electrical, ventilating, lighting, …, equipment. Use only nonsparking
tools.
Special precautions : No naked lights. No smoking. Avoid breathing dust, fume, gas,
mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
in fireproof place. Ground/bond container and receiving equipment. Keep container
tightly closed.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment. • Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -40 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 430 °C
Flammability (solid, gas) : Flammable.
Extremely flammable liquid and vapour.
Flash point [°C] : -10 °C
Boiling point [°C] : 48 °C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : 371 hPa at 20 °C
Vapour pressure mm/Hg : N/A
Vapour density : 1,07
Density [g/cm3] : 0,9
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : In water, material soluble.
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 14,0 at 100 g/l
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : 26,40%
Explosion limits - lower [%] : 5,20%
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Sparks. Heat.
Overheating. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
May release flammable gases.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Harmful if inhaled.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Causes serious eye damage.
Irritation : Causes skin irritation. May cause respiratory irritation.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
Special precautions : Handle empty containers with care because residual vapours are
flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : METHYLAMINE, AQUEOUS SOLUTION
UN N° : 1235
H.I. nr : 338
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid. 8 : Corrosive substance.
ADR - Classification code : FC
ADR - Group : II
ADR - Packing instructions : P001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : METHYLAMINE, AQUEOUS SOLUTION
UN N° : 1235
IMO-IMDG - Class or division : 3 : Flammable liquid. ( 8 : Corrosive substance. )
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-C
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : METHYLAMINE, AQUEOUS SOLUTION
UN N° : 1235
IATA - Class or division : 3 : Flammable liquid. ( 8 : Corrosive substance. )
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 352
instruction
- Passenger and Cargo - Maximum : 1 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 363
- Cargo only - Maximum Quantity/ : 5 L
Packing
IATA - Limited Quantites : 0.5 L
ERG-Nr : 3CH
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
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