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Porduct Name |
Methyl ester of acrylic acid (methyl acrylate) |
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Part Number |
RXSOL-19-1213-240 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.com |
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Chemical Name |
Cas No |
EC No |
Whight |
Formula |
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Methyl acrylate (stabilised with hydroquinone monomethyl ether) for synthesis |
96-33-3 |
202-500-6 |
86,09 g/mol |
C4H6O2 |
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Signal Word |
Danger |
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Hazard Statements |
H300 + H310 Fatal if swallowed or in contact with skin. |
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Precautionary statements |
P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/ protective clothing. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P302 + P352 + P310 IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
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Inhalation |
Fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
May be combustible at high temperature. |
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Suitable extinguishing media |
Carbon dioxide (CO2) Foam Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Carbon oxides Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. |
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Further information |
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
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Enviromental Precaution |
Do not let product enter drains. Risk of explosion. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
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Reference to other sections |
For disposal see section 13. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
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Conditions for safe storage, including any incompatibilities |
Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Moisture sensitive. |
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Storage conditions |
Protected from light.Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label. |
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Storage class |
Storage class (TRGS 510): 3: Flammable liquids |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Exposure controls |
No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
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Body Protection |
Flame retardant antistatic protective clothing. |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 30 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) |
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Respiratory protection |
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. Risk of explosion. |
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Physical state |
Liquid |
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Colour |
Colorless |
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Odour |
pungent |
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Odor Threshold |
Not Applicable |
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pH |
at 20 °C |
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Melting Point |
-76,5 °C |
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Boiling Point |
80,1 °C at 1.013 hPa |
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Flash Point |
-2,8 °C - closed cup |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
Upper explosion limit: 25 %(V) Lower explosion limit: 2,8 %(V) |
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Autoignition temperature |
468 °C at 1.013,25 hPa |
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Decomposition temperature |
No data available |
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Vapour pressure |
90 hPa at 20,2 °C 150 hPa at 30,8 °C |
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Viscosity |
Viscosity, kinematic: 10 mm2/s at 23 °C Viscosity, dynamic: 0,472 mPa.s at 25 °C |
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Density |
0,96 g/cm3 at 20 °C |
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Relative Density |
0,95 at 20 °C |
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Specific Gravity |
No data available |
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Partition coefficient |
log Pow: 0,74 at 25 °C |
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Explosive properties |
No data available |
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Solubility |
ca.60 g/l at 20 °C |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Vapors may form explosive mixture with air. |
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Chemical stability |
The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): hydroquinone monomethyl ether (0,01 %) |
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Possibility of hazardous reactions |
Risk of explosion with: Peroxides Strong oxidizing agents Strong acids strong alkalis Activated charcoal |
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Conditions to avoid |
Heat. May polymerize on exposure to light. Warming. |
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Incompatible materials |
Strong acids, Strong bases, Strong oxidizing agents, Strong reducing agents
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
Acute toxicity estimate Oral - 768,08 mg/kg (Calculation method) LD50 Oral - Rat - male - 768 mg/kg (OECD Test Guideline 401) Symptoms: Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract. Acute toxicity estimate Inhalation - 4 h - 3 mg/l - vapor(Calculation method) LC50 Inhalation - Rat - male and female - 4 h - 6,5 mg/l - vapor (OECD Test Guideline 403) Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract Acute toxicity estimate Dermal - 1.251 mg/kg (Calculation method) LD50 Dermal - Rabbit - 1.250 mg/kg Remarks: (ECHA) |
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Skin corrosion/irritation |
Skin - Rabbit Result: irritating - 4 h (OECD Test Guideline 404) |
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Serious eye damage/irritation |
Eyes - Rabbit Result: Eye irritation Remarks: (IUCLID) |
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Respiratory or skin sensitization |
Local lymph node assay (LLNA) - Mouse Result: positive (OECD Test Guideline 429) |
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Carcinogenicity |
No data available |
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Germ cell mutagenicity |
Test Type: Ames test Result: Not mutagenic in Ames Test. Remarks: (IUCLID) |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
No data available
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Additional Information |
RTECS: UF9625000 Lung irritation, Cyanosis, Central nervous system depression To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
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Persistence and degradability |
No data available |
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Toxicity to fish |
Flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 3,4 mg/l - 96 h (OECD Test Guideline 203) |
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Toxicity to daphnia and other aquatic invertebrates |
flow-through test EC50 - Daphnia magna (Water flea) - 2,6 mg/l - 48 h (OECD Test Guideline 202) |
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Toxicity |
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h |
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Toxicity to bacteria |
static test EC10 - activated sludge - > 100 mg/l - 72 h Remarks: (ECHA) |
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Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 74,35 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No data available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
No data available |
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Other adverse effects |
No data available . |
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Product |
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID:1919 IMDG:1919 IATA:1919 |
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UN proper shipping name |
ADR/RID:METHYL ACRYLATE, STABILIZED IMDG:METHYL ACRYLATE, STABILIZED IATA:METHYL ACRYLATE, STABILIZED |
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Transport hazard class(es) |
ADR/RID: 3 IMDG: 3 IATA:3 |
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Packaging group |
ADR/RID: II IMDG: II IATA:II |
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Environmental hazards |
ADR/RID: No IMDG: No IATA: No |
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Special precautions for user |
No data available |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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