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Lab Chemical

N BUTYL METHACRYLATE 99% for Synthesis Stabilized

Part number
RXSOL-60-6605-052
Category
Lab Chemical
Brand
RXSOL
RXSOL

Overview

n-Butyl Methacrylate (NBMA) can be used to produce organic glass, synthetic resins, rubbers, and varnishes, 
finishing textile fabrics, and it is also used in adhesive and as a polymeric plasticizer for harder resins.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product Name                N BUTYL METHACRYLATE 99% for Synthesis Stabilized
Part Number   RXSOL-60-6605-052

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
        Chemical name                          CAS-No     .     Formula     Molecular weight        EC-No.
 N BUTYL METHACRYLATE     97-88-1   C8H14O2  142,20 g/mol 202-615-1 

N-chlorosuccinimide

Component  Classification Concentration.

CAS-No.97-88-1

EC-No.202-615-1

Index-No 607-033-00-5                        

Flam. Liq. 3; Skin Irrit. 2;

Eye Irrit. 2; Skin Sens. 1;

STOT SE 3; H226, H315,

H319, H317, H335

<= 100 %

Classification of the substance or mixture

Classification according to Regulation Flammable liquids (Category 3), H226 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Skin sensitization (Category 1), H317 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 For the full text of the H-Statements mentioned in this Section, see Section 16
Signal Word                        warning 
Hazard Statements

H317 May cause an allergic skin reaction

P280 Wear protective gloves.P305 + P351 + P338 Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Precautionary statements - response

none

Supplemental Hazard Statements none
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

  

Description of first-aid measures

General advice Show this material safety data sheet to the doctor in attendance
If inhaled  After inhalation: fresh air.
Eye Contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a lenses 
Skin Contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician 
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion: Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
Notes to Physician Treat symptomatically
If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Most important symptoms and effects, both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 
Indication of any immediate medical attention and special treatment needed No data available 

Extinguishing media

Flammability                                                  May be combustible at high temperature.
Flash Point CLOSED CUP: Higher than 93.3°C (200°F).
Suitable extinguishing media Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given
Special hazards arising from the substance or mixture 

Carbon oxides

Combustible.

Vapors are heavier than air and may spread along floors.

Forms explosive mixtures with air at elevated temperatures

Development of hazardous combustion gases or vapours possible in the event of fire

Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.  
Hazardous combustion
products
Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing
Protective Equipment Use personal protective equipment.
Specific Hazards Arising from the Chemical Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours.
Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution Do not let product enter drains. Risk of explosion
Methods and materials for
containment and cleaning
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.
Reference to other sections For disposal see section 13.

 

Advice on safe handling  Work under hood. Do not inhale substance/mixture.
Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. 
Precautions for safe handling For precautions see section 2.2.
   
Storage conditions Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.
Storage conditions Tightly closed. Dry
Storage class Storage class (TRGS 510): 3: Flammable liquids
Specific end     use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated 
Handling

Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals

Advice on general occupational hygiene Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Control parameters Ingredients with workplace control parameters
  Personal Protection
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Body Protection Flame retardant antistatic protective clothing
Skin protection required
Respiratory protection Recommended Filter type: Filter A-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer These measures have to be properly documented 
Other Protection Measure Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure Do not let product enter drains. 

                                       

        Gloves                       Suit                          

Physical state

liquid 

Colour No data available
Odour No data available
Odor Threshold Not Applicable
pH No data available
Melting Point Melting point/range: -75 °C
Boiling Point 162 - 165 °C - lit.
Flash Point 48,5 °C - closed cup - Regulation (EC) No. 440/2008, Annex A.9
Evaporation Rate Not Applicable
Flammability (solid, gas) No data available
Explosive limits No Data Available
Upper/lower flammability or explosive limits

Upper explosion limit: 8 %(V)

Lower explosion limit: 2 %(V)

Autoignition temperature No data available
Decomposition temperature  No data available
Density 0,894 g/cm3 at 25 °C - lit.
Vapour Density 3 hPa at 20 °C
Partition coefficient log Pow: 3,01
Explosive properties None
 Water Solubility 429 g/l at 20 °C - OECD Test Guideline 105 
Ignition temperature No information available.
Surface tension 70,7 mN/m at 20 °C
Other safety information No data available
Reactivity                        Vapor/air-mixtures are explosive at intense warming
Stability The product is chemically stable under standard ambient conditions (room temperature) 
Possibility of hazardous reactions Risk of explosion with: Water Alcohols Amines Ammonia anilines Hydrazine hydrate iron/iron-containing compounds
Conditions to avoid no information available
Incompatible materials no information available
Hazardous Polymerization In the event of fire: see section 5

Information on toxicological effects

Acute toxicity  LD50 Oral - Rat - 16.000 mg/kg Inhalation: No data available
Skin corrosion/irritation Remarks: No data available
Serious eye damage/eye       irritation  Remarks: Causes serious eye damage. The GHS classification specified by the authority (ECHA)
Respiratory or skin              sensitization  Maximization Test - Guinea pig Result: May cause sensitization by skin contact (OECD Test Guideline 406)
Serious eye damage/eye       irritation Remarks: Mixture causes serious eye damage.
Rout Of Entry Inhalation. Ingestion.
Toxicity to Animal WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat].
Toxic Effects on Human May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Germ cell mutagenicity  No data available
Reproductive toxicity  No data available
Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation
Special Remarks on other Toxi  Effects on Humans:                      

Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.

Additional Information Endocrine disrupting properties
Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher
Endocrine disrupting           properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: DK2625000 burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Stomach - Irregularities - Based on Human Evidenc
   
Skin corrosion/irritation Skin - Rabbit Result: Skin irritation - 4 h (OECD Test Guideline 404)
Respiratory or skin sensitization Buehler Test - Guinea pig Result: negative (US-EPA) 
Germ cell mutagenicity  Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Result: negative
Specific target organ toxicity - single exposure No data available
Endocrine disrupting properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: SS7700000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Nausea, Dizziness, Headache, Dermatitis, Pulmonary edema. Effects may be delayed., Discoloration of the skin. After absorption: Risk of methaemoglobin formation with headache, cardiac dysrhythmia, drop in blood pressure, dyspnoea and spasms, principal symptom: cyanosis (blue discolouration of the blood). 
Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 2 % - Not readily biodegradable. (OECD Test Guideline 301D) 
Toxicity Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna Straus (Water flea) - 0,26 mg/l - 24 h Remarks: (ECHA) 
Toxicity to fish  LC50 - Oryzias latipes (Orange-red killifish) - 5,57 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 32 mg/l - 48 h
Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 57 mg/l - 96 h
Eco Toxicity Not Available
COD and BOD 5 Not Available
Products Biodegradation: The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil No Information available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
Endocrine disrupting       properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects Biological effects: Disinfectant effect. Further information on ecology Discharge into the environment must be avoided.

 

Waste treatment      Method No data available
UN number  ADR/RID:     3261            IMDG:    3261                IATA:    3261   
UN proper shipping name 

ADR/RID: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (N-chlorosuccinimide)

IMDG: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (N-chlorosuccinimide)

IATA: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (N-chlorosuccinimide)

Transport hazard class(es)     

ADR/RID: 8

IMDG: 8

IATA: 8

Packaging group

ADR/RID: II

IMDG: II

ATA: II

Environmental hazards

ADR/RID: yes

IMDG Marine pollutant: yes

IATA: no

Special precautions for user  
Tunnel restriction code  (D/E)
Further information Not classified as dangerous in the meaning of transport regulations.
Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation Seveso III: Directive 2012/18/EU of the European : ENVIRONMENTAL HAZARDS Parliament and of the Council on the control of major-accident hazards involving dangerous substances.  
DSCL (EEC)                        R8- Contact with combustible material may cause fire. R20/22- Harmful by inhalation and if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin. R42/43- May cause sensitization by inhalation and skin contact. S22- Do not breathe dust. S24- Avoid contact with skin. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37- Wear suitable gloves.
Other regulations Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out
Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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