N BUTYL METHACRYLATE 99% for Synthesis Stabilized
- Part number
- RXSOL-60-6605-052
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | N BUTYL METHACRYLATE 99% for Synthesis Stabilized |
| Part Number | RXSOL-60-6605-052 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
| Chemical name | CAS-No . | Formula | Molecular weight | EC-No. |
| N BUTYL METHACRYLATE | 97-88-1 | C8H14O2 | 142,20 g/mol | 202-615-1 |
N-chlorosuccinimide
| Component | Classification | Concentration. |
|
CAS-No.97-88-1 EC-No.202-615-1 Index-No 607-033-00-5 |
Flam. Liq. 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1; STOT SE 3; H226, H315, H319, H317, H335 |
<= 100 % |
Classification of the substance or mixture
| Classification according to Regulation | Flammable liquids (Category 3), H226 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Skin sensitization (Category 1), H317 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 For the full text of the H-Statements mentioned in this Section, see Section 16 |
| Signal Word | warning |
| Hazard Statements |
H317 May cause an allergic skin reaction |
| P280 Wear protective gloves.P305 + P351 + P338 | Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Precautionary statements - response |
none |
| Supplemental Hazard Statements | none |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher |
Description of first-aid measures
| General advice | Show this material safety data sheet to the doctor in attendance |
| If inhaled | After inhalation: fresh air. |
| Eye Contact |
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
| swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a lenses |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician |
| Inhalation: | Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
| Ingestion: | Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. |
| Notes to Physician | Treat symptomatically |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
Extinguishing media
| Flammability | May be combustible at high temperature. |
| Flash Point | CLOSED CUP: Higher than 93.3°C (200°F). |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture |
Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures Development of hazardous combustion gases or vapours possible in the event of fire |
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | For precautions see section 2.2. |
| Storage conditions | Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. |
| Storage conditions | Tightly closed. Dry |
| Storage class | Storage class (TRGS 510): 3: Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Control parameters | Ingredients with workplace control parameters |
| Personal Protection | |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Body Protection | Flame retardant antistatic protective clothing |
| Skin protection | required |
| Respiratory protection |
Recommended Filter type: Filter A-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer These measures have to be properly documented |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. |
Gloves Suit
| Physical state |
liquid |
| Colour | No data available |
| Odour | No data available |
| Odor Threshold | Not Applicable |
| pH | No data available |
| Melting Point | Melting point/range: -75 °C |
| Boiling Point | 162 - 165 °C - lit. |
| Flash Point | 48,5 °C - closed cup - Regulation (EC) No. 440/2008, Annex A.9 |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 8 %(V) Lower explosion limit: 2 %(V) |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Density | 0,894 g/cm3 at 25 °C - lit. |
| Vapour Density | 3 hPa at 20 °C |
| Partition coefficient | log Pow: 3,01 |
| Explosive properties | None |
| Water Solubility | 429 g/l at 20 °C - OECD Test Guideline 105 |
| Ignition temperature | No information available. |
| Surface tension | 70,7 mN/m at 20 °C |
| Other safety information | No data available |
| Reactivity | Vapor/air-mixtures are explosive at intense warming |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions | Risk of explosion with: Water Alcohols Amines Ammonia anilines Hydrazine hydrate iron/iron-containing compounds |
| Conditions to avoid | no information available |
| Incompatible materials | no information available |
| Hazardous Polymerization | In the event of fire: see section 5 |
Information on toxicological effects
| Acute toxicity | LD50 Oral - Rat - 16.000 mg/kg Inhalation: No data available |
| Skin corrosion/irritation | Remarks: No data available |
| Serious eye damage/eye irritation | Remarks: Causes serious eye damage. The GHS classification specified by the authority (ECHA) |
| Respiratory or skin sensitization | Maximization Test - Guinea pig Result: May cause sensitization by skin contact (OECD Test Guideline 406) |
| Serious eye damage/eye irritation | Remarks: Mixture causes serious eye damage. |
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat]. |
| Toxic Effects on Human | May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
| Germ cell mutagenicity | No data available |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | Inhalation - May cause respiratory irritation |
| Special Remarks on other Toxi Effects on Humans: |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Additional Information | Endocrine disrupting properties |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: DK2625000 burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Stomach - Irregularities - Based on Human Evidenc |
| Skin corrosion/irritation | Skin - Rabbit Result: Skin irritation - 4 h (OECD Test Guideline 404) |
| Respiratory or skin sensitization | Buehler Test - Guinea pig Result: negative (US-EPA) |
| Germ cell mutagenicity | Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Result: negative |
| Specific target organ toxicity - single exposure | No data available |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: SS7700000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Nausea, Dizziness, Headache, Dermatitis, Pulmonary edema. Effects may be delayed., Discoloration of the skin. After absorption: Risk of methaemoglobin formation with headache, cardiac dysrhythmia, drop in blood pressure, dyspnoea and spasms, principal symptom: cyanosis (blue discolouration of the blood). |
| Persistence and degradability | Biodegradability aerobic - Exposure time 28 d Result: 2 % - Not readily biodegradable. (OECD Test Guideline 301D) |
| Toxicity | Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna Straus (Water flea) - 0,26 mg/l - 24 h Remarks: (ECHA) |
| Toxicity to fish | LC50 - Oryzias latipes (Orange-red killifish) - 5,57 mg/l - 96 h (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | EC50 - Daphnia magna (Water flea) - 32 mg/l - 48 h |
| Toxicity to algae | EC50 - Pseudokirchneriella subcapitata (green algae) - 57 mg/l - 96 h |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | The methods for determining the biological degradability are not applicable to inorganic substances. |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Biological effects: Disinfectant effect. Further information on ecology Discharge into the environment must be avoided. |
| Waste treatment Method | No data available |
| UN number | ADR/RID: 3261 IMDG: 3261 IATA: 3261 |
| UN proper shipping name |
ADR/RID: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (N-chlorosuccinimide) IMDG: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (N-chlorosuccinimide) IATA: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (N-chlorosuccinimide) |
| Transport hazard class(es) |
ADR/RID: 8 IMDG: 8 IATA: 8 |
| Packaging group |
ADR/RID: II IMDG: II ATA: II |
| Environmental hazards |
ADR/RID: yes IMDG Marine pollutant: yes IATA: no |
| Special precautions for user | |
| Tunnel restriction code | (D/E) |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| National legislation | Seveso III: Directive 2012/18/EU of the European : ENVIRONMENTAL HAZARDS Parliament and of the Council on the control of major-accident hazards involving dangerous substances. |
| DSCL (EEC) | R8- Contact with combustible material may cause fire. R20/22- Harmful by inhalation and if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin. R42/43- May cause sensitization by inhalation and skin contact. S22- Do not breathe dust. S24- Avoid contact with skin. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37- Wear suitable gloves. |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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