N-METHYLANILINE FOR SYNTHESIS 98%
- Part number
- RXSOL-60-6605-116
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
N-METHYLANILINE FOR SYNTHESIS 98% used as a latent and coupling solvent and is also used as an intermediate for dyes, Agrochemicals and other organic products manufacturing. NMA is toxic and exposure can cause damage to the central nervous system and can also cause liver and kidney failure
Applications
N-Methylaniline (NMA) is an aniline derivative. It is an organic compound with the chemical formula C6H5NH(CH3). The substance is a colorless viscous liquid, Samples turn brown when exposed to air. The chemical is insoluble in water.
Characteristics and notes
N-Methylaniline is a principal component of NMA (monomethylaniline), a non-traditional antiknock agent increasingly used by petroleum refiners and fuel distributors around the world to increase the octane number of gasoline petrol.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Porduct Name | N-METHYLANILINE FOR SYNTHESIS 98% |
| Part Number | RXSOL-60-6605-116 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Product name | Cas No | EC No | Weight | Formula |
| N-Methylaniline for synthesis | 100-61-8 | 202-870-9 | 107,16 g/mol | C7H9N |
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H319 Causes serious eye irritation. H373 May cause damage to organs (Liver, spleen, Bone marrow) through prolonged or repeated exposure if swallowed. H410 Very toxic to aquatic life with long lasting effects. |
| Precautionary statements | P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P314 Get medical advice/ attention if you feel unwell. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance |
| If inhaled | fresh air. |
| Eye Contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| Swallowed | After swallowing immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture | Carbon oxides Nitrogen oxides (NOx) Combustible. Fire may cause evolution of nitrogen oxides Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | No data available |
| Hygiene measures | No data available |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Conditions for safe storage including any incompatibilities |
No data available |
| Storage conditions | Protected from light. Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.Tightly closed. Keep in a wellventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Protective Clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
| Respiratory protection |
Recommended Filter type Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented
|
| Other Protection Measure | No data available |
| Physical state | Liquid |
| Colour | Yellow |
| Odour | Weak characteristic odour |
| Odor Threshold | No data available |
| pH | 7,6 at 1 g/l |
| Melting Point | -57 °C |
| Boiling Point | 192 - 197 °C at 1.013 hPa |
| Flash Point | 85 °C - closed cup |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No data available |
| Viscosity | No data available |
| Density | 0,989 g/cm3 at 20 °C |
| Relative Density | No data available |
| Specific Gravity | No data available |
| Partition coefficient | Log Pow 0,81 |
| Explosive properties | No data available |
| Solubility | ca.30 g/l |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibilityof hazardous reactions | Violent reactions possible with: Oxidizing agents Strong acids Acid chlorides Acid anhydrides |
| Conditions to avoid | Strong heating |
| Incompatible materials |
Various plastics, Copper, copper compounds
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | Acute toxicity estimate Oral - 100,1 mg/kg (Expert judgment) Acute toxicity estimate Oral - Expert judgment - 100,1 mg/kg Symptoms Nausea, Vomiting Oral: Rapid absorption. Acute toxicity estimate Inhalation - Expert judgment - 4 h - 3,1 mg/l - vapor Acute toxicity estimate Dermal - Expert judgment - 300,1 mg/kg |
| Skin corrosion/irritation | Skin - Rabbit No skin irritation - 4 h (External MSDS |
| Serious eye damage/irritation | Eyes - Chicken eye Causes serious eye irritation. - 10 s (OECD Test Guideline 438) |
| Respiratory or skin sensitization | Local lymph node assay (LLNA) - Mouse negative (OECD Test Guideline 429) |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Test Type Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative Remarks: (ECHA) Test Type Mutagenicity (mammal cell test): chromosome aberration. Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Result: positive Remarks: (ECHA) Test Type: Micronucleus test Species: Mouse Cell type: Red blood cells (erythrocytes) Application Route Oral Method: OECD Test Guideline 475 Result: positiv |
| Reproductive toxicity | Possible risk of congenital malformation in the fetus. Exposure to excessive amounts of iodine during pregnancy is capable of producing fetal hypothyroidism. Iodine-containing drugs have been associated with fetal goiter |
| Specific target organ toxicity - single exposure |
No data available
|
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Cough, Shortness of breath, Headache, Nausea, Vomiting, Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Systemic effects: After absorption confusion Dizziness somnolence Methaemoglobinemia Coma Absorption can result in damage to: Liver Kidney Central nervous system Effect potentiated by: ethanol Danger of cumulative effects. The following applies to aromatic amines in general: systemic effect: methaemoglobinaemia with headache, cardiac dysrhythmia, drop in blood pressure, dyspnoea, and spasms, principal symptom: cyanosis (blue discolouration of the blood). Handle in accordance with good industrial hygiene and safety practice. |
| Persistence and degradability | Biodegradability aerobic - Exposure time 28 d Result: 92 % - Inherently biodegradable. (ECHA) |
| Toxicity to fish | No data available |
| Toxicity to daphnia and other aquatic invertebrates | LC50 - Daphnia magna (Water flea) - 0,15 mg/l - 48 h (ECOTOX Database) |
| Toxicity | No data available |
| Toxicity to bacteria | EC50 - activated sludge - 1,5 mg/l - 30 min (ISO 8192) |
| Toxicity to algae | No data available |
| Bioaccumulation potential | Bioaccumulation Cyprinodontidae - 48 h - 250 µg/l(N-Methylaniline) Bioconcentration factor (BCF): 2,6 |
| Mobility in soil | No data availalble |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Other adverse effects | No data available |
| Product | No data available |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number |
ADR/RID:2294 IMDG:2294 IATA:2294 |
| UN proper shipping name | ADR/RID:N-METHYLANILINE IMDG:N-METHYLANILINE IATA:N-METHYLANILINE |
| Transport hazard class(es) | ADR/RID:6.1 IMDG:6.1 IATA:6.1 |
| Packaging group | ADR/RID:lll IMDG:lll IATA:lll |
| Environmental hazards | ADR/RID:Yes IMDG Marine pollutant:Yes IATA:No |
| Special precautions for user | Tunnel restriction code (E) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment was not carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if RX Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
Availability
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