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Product Name |
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Product Type |
NICKEL CARBONATE |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation : NICKEL CARBONATE
CAS No :39430-27-8
Substance.
Contains no other components or impurities which will influence the classification of the
product
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : T; R48/23
Xn; R20/22
Xi; R38
Xn ; R42/43
N; R50-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Specific Target Organ Toxicity - Single exposure - Category 2
- Warning (CLP : STOT SE 2) H371
Specific Target Organ Toxicity - Repeated exposure - Category 1 - Danger (CLP
: STOT RE 1) H372
Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317
Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) H334
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Environmental hazards : Hazardous to the aquatic environment - Acute hazard -
Category 1 - Warning (CLP : Aquatic Acute 1) H400
Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning (
CLP : Aquatic Chronic 1)H410
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : Xn : Harmful
N : Dangerous for the environment
R Phrase(s) : R49 : May cause cancer by inhalation.
R61 : May cause harm to the unborn child.
R20/22 : Harmful by inhalation and if swallowed.
R38 : Irritating to skin.
R42/43 : May cause sensitization by inhalation and skin contact.
R48/23 : Toxic : danger of serious damage to health by prolonged exposure
through inhalation.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R68 : Possible risks of irreversible effects.
S Phrase(s) : S53 : Avoid exposure - obtain special instructions before use.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (show
the label when possible).
S60 : This material and its container must be disposed of as hazardous waste.
S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H302 : Harmful if swallowed.
H315 : Causes skin irritation.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 : May cause an allergic skin reaction.
H332 : Harmful if inhaled.
H372 : Causes damage to organs through prolonged or repeated exposure.
H371 : May cause damage to organs.
H410 : Very toxic to aquatic life with long lasting effects.
Precautionary statements
• Prevention : P285: In case of inadequate ventilation wear respiratory protection.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe dust, fume, gas, mist, vapours, spray.
P273: Avoid release to the environment.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feel
unwell.
P309+P311: IF exposed or if you feel unwell : Call a POISON CENTER or doctor.
P391: Collect spillage.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
P333+P313: If skin irritation or rash occurs : Get medical advice.
P342+P311: If experiencing respiratory symptoms : Call a POISON CENTER or
doctor.
P363: Wash contaminated clothing before reuse.
P314: Get medical advice if you feel unwell.
• Storage : P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : If experiencing respiratory symptoms : Remove to fresh air and keep at rest
in a position comfortable for breathing. Call a POISON CENTER or doctor if you feel
unwell.
Skin contact : Specific treatment (see on this label). Get medical advice. Wash with
plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or
rash occurs :
Eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
Ingestion : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor
if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Causes damage to organs through prolonged or repeated
exposure. Causes skin irritation.May cause allergy or asthma symptoms or breathing
difficulties if inhaled. May cause an allergic skin reaction. May cause damage to organs
. Danger of serious damage to health by prolonged exposure through inhalation.
Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : Highly flammable liquid and vapour.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area. Avoid breathing dust, fume, gas, mist, vapours, spray.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : On land, sweep or shovel into suitable containers. Store away from
other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Personal protection : Wash thoroughly after handling. Do not breathe dust, fume, gas,
mist, vapours, spray. Do not eat, drink or smoke when using this product.
Handling : Avoid breathing dust, fume, gas, mist, vapours, spray. Wash contaminated
clothing before reuse. Contaminated work clothing should not be allowed out of the
workplace. Do not breathe dust, fume, gas, mist, vapours, spray. Use only outdoors
or in a well-ventilated area. Wash thoroughly after handling. Do not eat, drink or
smoke when using this product. Wash thoroughly after handling.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container closed when not in use.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment. Where exposure through inhalation may occur from use, respiratory
protection equipment is recommended.
In case of inadequate ventilation wear respiratory protection.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : Not applicable.
Melting point [°C] : No data available.
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flash point [°C] : N/A
Boiling point [°C] : N/A
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : N/A
Vapour density : N/A
Density [g/cm3] : 2,6
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Soluble in water
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Harmful if inhaled.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Harmful if swallowed.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes skin irritation.
Sensitization : May cause allergy or asthma symptoms or breathing difficulties if
inhaled. May cause an allergic skin reaction.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Causes damage to organ.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated
exposure.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
Persistence and degradability May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
14.1. Land transport (ADR-RID)
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN N° : 3077
H.I. nr : 90
ADR - Class : 9
Labelling - Transport : 9 : Miscellaneous dangerous substances and articles.
ADR - Classification code : M7
ADR - Group : III
ADR - Packing instructions : P002 R001 LP002
ADR - Limited Quantity : 5 KG
ADR - Tunnel code : E : Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN N° : 3077
IMO-IMDG - Class or division : 9 : Miscellaneous dangerous substances and articles.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P002 LP02
IMO-IMDG - Limited quantities : 5 kg
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-A S-F
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN N° : 3077
IATA - Class or division : 9 : Miscellaneous dangerous substances and articles.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 956
instruction
- Passenger and Cargo - Maximum : 400 kg
Quantity/Packing
IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 956
- Cargo only - Maximum Quantity/ : 400 kg
Packing IATA - Limited Quantites : 30 kg
G ERG-Nr : 9L
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.