NICKEL CHLORIDE LR

3.1. Classification of the substance or mixture

Classification EC 67/548 or EC 1999/45

Classification: T; R23/25-R48/23

Xi; R38Xn ; R42/43N; R50-53

Hazard Class and Category Code(s), Regulation (EC) No 1272/2008

(CLP)Health hazards: Specific Target Organ

Toxicity-Single exposure-Category 2-Warning (CLP :STOT SE 2) H371

Specific Target Organ Toxicity-Repeated

exposure-Category 1-Danger (CLP :STOT RE 1) H372

Respiratory sensitization-Category 1-Danger (CLP : Resp. Sens. 1) H334

Skin sensitisation-Category 1-Warning (CLP : Skin Sens. 1) H317

Skin irritation-Category 2-Warning (CLP : Skin Corr. 2) H315

Acute toxicity, Inhalation-Category 3-Danger (CLP : Acute Tox. 3) H331

Acute toxicity, Oral-Category 3-Danger (CLP : Acute Tox. 3) H301

Environmental hazards: Hazardous to the aquatic

environment-Acute hazard-Category 1-Warning (CLP: Aquatic Acute 1) H400

Hazardous to the aquatic environment-Chronic hazard-Category 1-Warning

(CLP :Aquatic Chronic 1) H410

3.2. Label elements

Labelling  EC 67/548 or  EC 1999/45 2 of 10

Symbol(s) :  T : 

Toxic N :  Dangerous  for  the  environment

R Phrase(s) :  R49 :  May  cause  cancer  by  inhalation.

R61 :  May  cause  harm  to the  unborn child.

R23/25 :  Toxic  by  inhalation and i f  swallowed.

R38 :  Irritating  to skin.

R42/43 :  May  cause  sensitization by  inhalation and skin contact.

R48/23 :  Toxic  :  danger  of  serious  damage  to health by  prolonged  exposure inhalation.

R50/53 :  Very  toxic  to aquatic  organisms, may  cause  longt through erm  adverse  effects  in the  aquatic  environment.

R68 :  Possible  risks  of  irreversible  effects.

S  Phrase(s) : S24 :  Avoid contact  with shin.

S37 :  Wear  suitable  gloves.

S53 :  Avoid exposureobtain special  instructions  before  use.

S45 :  In case  of  accident or  if  you  feel  unwell, seek medical  advice  immediately  ( show the  label  when possible).

S60 :  This  material  and its  container  must  be  disposed of  as  hazardous  waste.

S61 :  Avoid release  to the  environment. Refer  to special  instructions/Safety  data

Labelling Regulation  EC 1272/2008  (CLP)

Hazard  pictograms

Signal  words :  Danger

Hazard  statements :  H301 :  Toxic  if  swallowed.

H331 :  Toxic  if  inhaled. H315 :  Causes  skin irritation.

H334 :  May  cause  allergy  or  asthma  symptoms  or  breathing  difficultie

H317 :  May  cause  an allergic  skin  reaction.

H372 :  Causes  damage  to  organs  through prolonged or  repeated exposure.

H371 :  May  cause  damage  to organs.

H410 :  Very  toxic  to aquatic  life  with long  lasting effects. Precautionary statements

•  Prev ention sheets. s  if  inhaled. :  P285:  In  case  of  inadequate  ventilation wear  respiratory  protection

P280: Wear protective gloves, protective clothing, eye protection, face protection.

P271: Use only outdoors or in a well-ventilated area.

P260: Do not breathe dust, fume, gas, mist, vapours, spray.

P273: Avoid release to the environment.

P264: Wash thorou ghly after handling.

P270: Do not eat, drink or smoke when using this product.

P272: Contaminated work clothing should not be allowed out of the workplace.

• Response: P301+P310:IF SWALLOWED : Immediately call a POISON CENTER ordoctor.

P302+P352: IF ON SKIN : Wash with plenty of soap and water.

P309+P311: IF exposed or if you feel unwell : Call a POISON CENTER or doctor.

P391: Collect spillage

.P304+P340: IF INHALED : Remove tofresh air and keep at rest in a positioncomfortable for breathing.

P333+P313: If skin irritation or rash occurs : Get medical advice.

P342+P311: If experiencing respiratory symptoms : Call a POISON CENTER ordoctor.

P363: Wash contaminated clothing beforereuse.

P314: Get medical advice if you feel unwell.

• Storage: P403+P233: Store in well-ventilated place. Keep container tightly closed.

P405: Store locked up.

• Disposal considerations: P501: Dispose of this material and its container to hazardousor

special wastecollection point, in accordance with local, regional, national and/orinternationalregulation.

3.3. Other hazardsOther hazards: The substance does not fulfil the criteria to be identified

as PBTsubstance or vPvBsubstance according to Annex XIII of Regulation REACH.

4.1. Description of first aid measures

Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing.

Specific treatment (see on this label). Immediately call a POISON CENTER ordoctor.

If experiencing respiratory symptoms :

Skin contact:If skin irritation or rash occurs : Wash contaminated clothing before reuse.

Washwith plenty of soap and water. Get medical advice. Specific treatment (see on thislabel).

Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresentand easy to do.

Continue rinsing.Ingestion: Specific treatment (see on this label).

Immediately call a POISON CENTERordoctor. Do NOT induce vomiting. Rinse mouth.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms relating to use: Danger of serious damage to health by prolonged

exposurethrough inhalation.Causes damage to organs through prolonged or repeated

exposure.Swallowing a small quantity of this material will result in serious health hazard.

Causes skin irritation.May cause allergy or asthma symptoms or breathing difficulties ifinhaled.

May cause an allergic skin reaction.May cause damage to organs.

4.3. Indication of any immediate medical attention and specialtreatment needed

General information: Never give anything by mouth to an unconscious person.

If youfeel unwell, seekmedical advice (show the label where possible).

5.1. Extinguishing media

Suitable extinguishing media: Foam.Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media: Do not use a heavy water stream.

Surrounding fires: Use water spray or fog for cooling exposed containers.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products: Under fire conditions, hazardous fumes will bepresent.

5.3. Advice for fire-fighters

Protection against fire: Do not enter fire area without proper protective

equipment,including respiratoryprotection.Special procedures: Exercise caution

when fighting any chemical fire. Avoid (reject)fire-fighting water toenter environment.

6.1. Personal precautions, protective equipment and emergency procedures

For emergency responders: Equip cleanup crew with proper protection.

Ventilate area.Avoid breathing dust, fume, gas, mist, vapours, spray.

For non-emergency personnel: Evacuate unnecessary personnel.

6.2. Environmental precautions

Environmental precautions: Prevent entry to sewers and public waters.

Notifyauthorities if product enterssewers or public waters.Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Clean up methods: On land, sweep or shovel into suitable containers.

Store away fromother materials.

6.4. Reference to other sections

See section 8. Exposure controls/personal protection

9.1. Information on basic physical and chemical properties

Physical state at 20 °C: Solid.

Odour threshold: No data available

.pH value: Not applicable.

Melting point [°C]: 10010C

Decomposition point [°C]: N/A

Critical temperature [°C]: N/A

Auto-ignition temperature [°C]: N/A

Flammability (solid, gas): N/A

Flash point [°C]: N/A

Boiling point [°C]: N/A

Initial boiling point [°C]:N/A

Final boiling point [°C]: N/A

Evaporation rate: N/A

Vapour pressure [20°C]: N/A

Vapour pressure mm/Hg: 1 mm Hg @ 6710C

Vapour density: N/A

Density [g/cm3]: 3,55

Relative density, gas (air=1): N/A

Relative density, liquid (water=1): N/A

Solubility in water [% weight]: 2.54 kg/L @ 200C

Solubility in water: N/A

Log Pow octanol / water at 20°C: No data available.

Solubility: 4Viscosity at 40°C [mm2/s]: N/A

9.2. Other information

Explosive properties: N/A

Explosion limits-upper [%]: N/A

Explosion limits-lower [%]: N/A

Oxidising properties: No data available.

11.1. Information on toxicological effectsAcute toxicity

• Inhalation: Toxic if inhaled.

• Dermal: Based on availabledata, the classification criteria are not met

.• Ingestion: Toxic if swallowed.Corrosion: Based on available data, the classification criteria are not met.

Irritation: Causes skin irritation.

Sensitization: May cause allergy or asthma symptoms or breathing difficulties ifinhaled.May

cause an allergic skin reaction.Mutagenicity: Based on available data, the classification criteria are not met.

Carcinogenicity: Based on available data, the classification criteria are not met.

Toxic for reproduction: Based on available data, the classification criteria are not met.

STOT-single exposure: Causes damage to organ.

STOT-repeated exposure: Causes damage to organs through prolonged or repeatedexposure.

Aspiration hazard: Based on available data, the classification criteria are not met.

12.1. Toxicity

Toxicity information: Very toxic to aquatic life with long lasting effects.

12.2. Persistence-degradability

Persistence-degradability: May cause long-term

adverse effects inthe environment.

12.3. Bioaccumulative potential

Bioaccumulative potential: Not established.

12.4. Mobility in soil

Mobility in soil: Not established.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment: The substance

does not fulfil the criteria to beidentified as PBT substance

or vPvBsubstance according to Annex XIII of RegulationREACH.

12.6. Other adverse effects

Environmental precautions: Avoid release to the environment.

13.1. Waste treatmentmethods

General: Avoid release to the environment.

Dispose in a safe manner in accordance withlocal/national regulations.

Dispose of this material and its container to hazardous orspecial waste

collectionpoint, in accordance with local, regional, national and/orinternational

regulation.Special precautions: Hazardous waste due to toxicity.

15.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixture

Safety, health and environmental: Ensure all national/local regulations are observed.

regulations/legislation specific for thesubstance or mixture

REACH Restrictions-Annex XVII: The components of this product are not subject torestrictions.

REACH Authorisation-Annex XIV: The components of this product are not subjecttoauthorization.

15.2. Chemical Safety Assessment

Chemical Safety Assessment: It has not been carried out.

Abbreviations and acronyms: PBT: persistent, bioaccumulative and toxic.vPvB: very persistent and very bioaccumulative

Sourcesof key data used: REGULATION (EC) No 1272/2008 OF THE EUROPEANPARLIAMENT AND OF THE COUNCIL

of 16 December 2008 on classification,labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006Further information: None.In accordance with REACH

Regulation (CE) Nº 1907/2006 and with CLP Regulation(CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.