Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substance: N,N’DICYCLOHEXYLCARBODIMIDE FOR SYNTHESIS
CAS No : 538-75-0
Substance.
Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal), H311
Category 3 Serious eye damage/eye irritation, H318
Category 1 Acute toxicity (oral), H302
Category 4 Sensitisation — Skin, H317
category 1 Classification according to Directive 67/548/EEC or 1999/45/EC
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Extra labelling to displayExtra classification(s) to display
Symbol(s) : T : Very toxic
R Phrase(s) : R22: Harmful if swallowed.
R24: Toxic in contact with skin.
R41: Risk of serious damage to eyes.
R43: May cause sensitization by skin contact.
S Phrase(s) : S24: Avoid contact with skin.
S26: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advise.
S45: In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
S37/39 : Wear suitable gloves and eye/face protection. Hazard pictograms
Signal word : Danger
Hazard statements : H302 - Harmful if swallowed
H311 - Toxic in contact with skin H317 -
May cause an allergic skin reaction
H318 - Causes serious eye damage
Precautionary statements : P280 - Wear protective gloves, protective clothing, eye protection, face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Assure fresh air breathing.
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention.
First-aid measures after skin contact : Wash with plenty of soap and water.
Wash contaminated clothing before reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after
skin contact : Repeated exposure to this material can result in absorption through
skin causing significant health hazard. Toxic in contact with
skin. Symptoms/injuries after eye contact : Causes serious eye damage.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without
proper protective equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay
or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes.
Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Do not eat, drink or smoke when using this product.
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 34 - 35 °C
Freezing point : No data available
Boiling point : 122 - 124 °C
Flash point : 113 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Insoluble
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Overheating. Open flame. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Dermal: Toxic in contact with skin.
Oral: Harmful if swallowed. Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects
and symptoms : Harmful if swallowed.
Toxic in contact with skin.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
recommendations : Dispose of contents/container to ... Ecology -
waste materials : Hazardous waste due to toxicity.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2811
UN-No. (IMDG) : 2811
UN-No.(IATA) : 2811
UN-No.(ADN) : Not regulated
UN-No. (RID) : Not regulated
14.2. UN proper shipping name
Proper Shipping Name (ADR) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (IMDG) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (IATA) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (ADN) : Not regulated
Proper Shipping Name (RID) : Not regulated
Transport document description (ADR) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, II, (
D/E) Transport document description (IMDG) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, II
Transport document description (IATA) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, II
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 6.1
Danger labels (ADR) : 6.1
IMDG- Transport hazard class(es) (IMDG) : 6.1
Danger labels (IMDG) : 6.1
IATA- Transport hazard class(es) (IATA) : 6.1
Hazard labels (IATA) : 6.1
ADN- Transport hazard class(es) (ADN) : Not regulated
RID- Transport hazard class(es) (RID) : Not regulated
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not regulated
Packing group (RID) : Not regulated
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport- Classification code (ADR) : T2
Special provision (ADR) : 274, 614
Limited quantities (ADR) : 500g
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T3
Portable tank and bulk container special provisions (ADR) : TP33
Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15,
TE19 Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage – Packages (ADR) : V11
Special provisions for carriage - Loading,
unloading and handling (ADR) CV13, CV28
Special provisions for carriage – Operation (ADR) : S9, S19
Hazard identification number (Kemler No.) : 60
Orange plates : Tunnel restriction code (ADR) : D/E EAC
code : 2X
Transport by sea-
Special provision (IMDG) : 274
Limited quantities (IMDG) : 500 g
Excepted quantities (IMDG) : E4
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08 IBC
special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A EmS-No.
(Spillage) : S-A
Stowage category (IMDG) : B
MFAG-No : 154
Air transport-
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y644
PCA limited quantity max net quantity (IATA) : 1kg
PCA packing instructions (IATA) : 669
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 676
CAO max net quantity (IATA) : 100kg
Special provision (IATA) : A3, A5 ERG
code (IATA) : 6L
Inland waterway transport-
Not regulated
Rail transport-
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations No
REACH Annex XVII restrictions N,N’DICYCLOHEXYLCARBODIMIDE is not on the
REACH Candidate List N,N’DICYCLOHEXYLCARBODIMIDE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18
years are not allowed to use the product Pregnant/breastfeeding women working
with the product must not be in direct contact with the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.