PALLADIUM CALCIUM CARBONATE 10% pd
- Part number
- RXSOL-60-6605-166
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Catalyst for: Aqueous Heck coupling and hydroarylation. Reduction reactions. Hydrogenation reactions.Calcium carbonate is a dietary supplement used when the amount of calcium taken in the diet is not enough. Calcium is needed by the body for healthy bones, muscles, nervous system, and heart. Calcium carbonate also is used as an antacid to relieve heartburn, acid indigestion, and upset stomach.
Applications
Aqueous Heck coupling and hydroarylation. Reduction reactions. Hydrogenation reactions.
Dosage and directions
The filtrate of 0.4 mol % of 10% Pd/C 85.2 mg, 80.0 μmol)-catalyzed Sonogashira-type coupling reaction of 4′-iodoacetophenone (4.92 g, 20.0.
Characteristics and notes
synthesis of Lindlar catalyst for selective hydrogenation of alkynes.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | PALLADIUM CALCIUM CARBONATE 10% pd |
| Part Number | RXSOL-60-6605-166 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| web site |
| Chemical Name | CAS | EC number | Weight |
| PALLADIUM CALCIUM CARBONATE 10% pd | 7440-05-3 | 231-115-6 |
|
| Signal Word | Warning |
| Classification of the substance or mixture |
Classification according to Regulation (EC) No 1272/2008
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
For the full text of the H-Statements mentioned in this Section, see Section 16.
|
| Hazard Statements |
H315 Causes skin irritation.
H319 Causes serious eye irritation
H319 Causes serious eye irritation.H315 Causes skin irritation.
H319 Causes serious eye irritation.
|
| P280 Wear protective gloves.P305 + P351 + P338 | NA |
| Precautionary statements - response |
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
|
| Response | None |
| Disposal | NA |
| Prevention | NA |
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
|
| General advice | Consult a physician. Show this material safety data sheet to the doctor in attendance. |
| If inhaled |
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physicianIf breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician
|
| Eye Contact |
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician |
| swallowed | NA |
| Skin Contact | Wash off with soap and plenty of water. Consult a physician |
| Inhalation: | NA |
| Ingestion: | NA |
| Notes to Physician | NA |
| If swallowed |
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
|
| Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
|
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | NA |
| Flash Point | NA |
| Suitable extinguishing media | Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide |
| Unsuitable extinguishing media | NA |
| Special hazards arising from the substance or mixture | Calcium oxide |
| Further information | Use water spray to cool unopened containers. |
|
Hazardous combustion products |
NA |
| Advice for firefighters | Wear self-contained breathing apparatus for firefighting if necessary. |
| Protective Equipment | NA |
| Specific Hazards Arising from the Chemical | NA |
| Personal precautions, protective equipment and emergency procedures | Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. |
| Spillage | NA |
| Personal Protection | NA |
| Enviromental Precaution | Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Sweep up and shovel. Contain spillage, and then collect with an electrically protected
vacuum cleaner or by wet-brushing and place in container for disposal according to local
regulations (see section 13). Keep in suitable, closed containers for disposal. Contain
spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and
transfer to a container for disposal according to local regulations (see section 13).
|
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | Avoid contact with skin and eyes. Avoid formation of dust and aerosols. |
| Advice on protection against fire and explosion |
Provide appropriate exhaust ventilation at places where dust is formed.Keep away from
sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
|
| Hygiene measures | Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. For precautions see section 2.2. |
| Precautions for safe handling | Advice on safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols |
| Conditions for safe storage, including any incompatibilities | Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. |
| Storage conditions |
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Handle and store under inert gas.
|
| Storage class | Storage class (TRGS 510): 13: Non Combustible Solids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling |
NA |
| Advice on general occupational hygiene | Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. |
| Occupational Exposure limit values | No data available |
| Biological limit values | No data available |
| Exposure controls | NA |
| Engineering Control | NA |
| Eye/face protection | Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). |
| Body Protection | Impervious clothing, Flame retardant antistatic protective clothing., The type o protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. |
| Skin protection | Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. |
| Respiratory protection |
Where risk assessment shows air-purifying respirators are appropriate use a fullface particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and Aldrich- 76030 Page 5 of 12 The life science business of Merck operates as MilliporeSigma in the US and
Canada approved under appropriate government standards such as NIOSH (US) or CEN (EU)
|
| Other Protection Measure | NA |
| Control of environmental exposure | Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
| Thermal hazards | No data available |
Gloves Suit
| Physical state | Powder |
| Colour | Gray |
| Odour | Odorless |
| Odor Threshold | Not Applicable |
| pH | Not Applicable |
| Melting Point | No data available |
| Boiling Point | No data available |
| Flash Point | No data available |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) |
The substance or mixture is a flammable solid with the category
2.
|
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No Data Available |
| Density | No data available |
| Vapour Density | No Data Available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | DMSO (Slightly), Water (Slightly) |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Other safety information | No data available |
| Reactivity | No data available |
| Stability | Stable under recommended storage conditions |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | Heat, flames and sparks. Extremes of temperature and direct sunlight. |
| Incompatible materials | No data available |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity |
LD50 Oral - Rat - female - > 2.000 mg/kg (calcium carbonate) (OECD Test Guideline 420) LC50 Inhalation - Rat - male and female - 4 h - > 3 mg/l - aerosol
(calcium carbonate) (OECD Test Guideline 403) LD50 Dermal - Rat - male and female - > 2.000 mg/kg (calcium carbonate) (OECD Test Guideline 402)
|
| Skin corrosion/irritation | Skin - reconstructed human epidermis (RhE) (calcium carbonate) Result: No skin irritation - 15 min (OECD Test Guideline 439) |
| Serious eye damage/eye irritation | Eyes - Bovine cornea (calcium carbonate) Result: No eye irritation - 4 h (OECD Test Guideline 437) |
| Respiratory or skin sensitization | Local lymph node assay (LLNA) - Mouse (calcium carbonate) Result: negative (OECD Test Guideline 429) |
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | NA |
| Toxic Effects on Human | NA |
| Germ cell mutagenicity |
Test Type: Ames test (calcium carbonate) Test system: Escherichia coli/Salmonella Typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration.
(calcium carbonate) Test system: Human lymphocytes Metabolic activation: with And without metabolic activation Method: OECD Test Guideline 473 Result: Negative Test Type: In vitro mammalian cell gene mutation test (calcium Carbonate) Test system: mouse lymphoma cells Metabolic activation: with and Without metabolic activation Method: OECD Test Guideline 476 Result: negative
|
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans: |
NA |
| Additional Information | Endocrine disrupting properties |
| Assessment | The substance/mixture does not contain components considered to have endocrine Disrupting properties according to REACH Article 57(f) or Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 48 Days - NOAEL (No observed adverse effect level) - 1.000 mg/kg (calcium carbonate) To The best of our knowledge, the chemical, physical, and toxicological properties Have not been thoroughly investigated. (calcium carbonate) Hazardous properties Cannot be excluded but are unlikely when the product is handled appropriately. (calcium carbonate) Handle in accordance with good industrial hygiene and safety Practice.(calcium carbonate) |
| Endocrine disrupting properties |
Product: Assessment : The substance/mixture does not contain components Considered to have endocrine disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 48 Days - NOAEL (No observed adverse effect level) - 1.000 mg/kg (calcium carbonate) To the best of our knowledge, the chemical, Physical, and toxicological properties have not been thoroughly investigated. (Calcium carbonate) Hazardous properties cannot be excluded but are unlikely When the product is handled appropriately. (calcium carbonate) Handle in Accordance with good industrial hygiene and safety practice.
|
| Persistence and degradability | No data available |
| Toxicity |
Toxicity to fish semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - > 100 mg/l - 96 h (calcium carbonate) (OECD Test Guideline 203) Toxicity to Daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (calcium carbonate) (OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 14 mg/l - 72 h (calcium carbonate) (OECD Test Guideline 201) Toxicity to Bacteria static test EC50 - activated sludge - > 1.000 mg/l - 3 h (calcium Carbonate) (OECD Test Guideline 209)
|
| Bioaccumulative potential | Bioaccumulation is unlikely. |
| Toxicity to fish | Semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - > 100 mg/l - 96 H (calcium carbonate) (OECD Test Guideline 203) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (calcium Carbonate) (OECD Test Guideline 202) |
| Toxicity to algae | Static test ErC50 - Desmodesmus subspicatus (green algae) - 14 mg/l - 72 h (Calcium carbonate) (OECD Test Guideline 201) |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | NA. |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have Endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Assessment | The substance/mixture does not contain components considered to have Endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No ecological problems are to be expected when the product is handled and Used with due care and attention. |
| Disposal methods | NA |
| Contaminated packaging | Dispose of as unused product. |
| Waste treatment Method | Product Burn in a chemical incinerator equipped with an afterburner and scrubber but Exert extra care in igniting as this material is highly flammable. Offer surplus and non-Recyclabl solutions to a licensed disposal company. |
| UN number |
ADR/RID: - NO IMDG: - NO IATA: - NO |
| UN proper shipping name | ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods |
| Transport hazard class(es) |
ADR/RID: - NO IMDG: - NO IATA: - NO |
| Packaging group |
ADR/RID: - NO IMDG: - NO IATA: - NO |
| Environmental hazards |
ADR/RID: no IMDG Marine pollutant: no IATA: no |
| Special precautions for user | No data available |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Transport in bulk according to IMOinstruments | No data available |
| Further information | Not classified as dangerous in the meaning of transport regulations |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Safety, health and environmental regulations specific for the product in question | NA |
| National legislation | NA |
| DSCL (EEC) | NA |
| Other regulations | NA |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
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PALLADIUM HYDROXIDE 20% ON CHARCOAL RXSOL-60-6605-163
PALLADIUM NITRATE 44% PD content RXSOL-60-6605-164
PALLADIUM SPONGE 99.9% POWDER RXSOL-60-6605-165
PALLADIUM CALCIUM CARBONATE 10% pd RXSOL-60-6605-166
PARAFFIN WAX 58 60C BLOCK BRICKS RXSOL-60-6605-180
P DIMETHYL AMINO BENZALDEHYDE AR RXSOL-60-6605-192
P DIMETHYL AMINO CINNAMALDEHYDE AR RXSOL-60-6605-193
PEPTONE BACTERIOLOGICAL GRANULAR RXSOL-60-6605-197
PETROLEUM ETHER 100-2000 C FOR SYNTHESIS RXSOL-60-6605-205
PHENOL RED INDICATOR SOLUTION RXSOL-60-6605-215
PHENOLDISULPHONIC ACID SOLUTION 25% RXSOL-60-6605-216
PHENOLPHTHALEIN INDICATOR RXSOL-60-6605-218
PHENYL CHLOROFORMATE FOR SYNTHESIS RXSOL-60-6605-219
PHENYL HYDRAZINE AR RXSOL-60-6605-220
PHENYL HYDRAZINE FOR SYNTHESIS RXSOL-60-6605-221
PHENYL HYDRAZINE HYDROCHLORIDE AR RXSOL-60-6605-223
PHENYL MERCURY ACETATE FOR SYNTHESIS RXSOL-60-6605-224
PHENYL PHOSPHATE DISODIUM SALT AR RXSOL-60-6605-226
PHENYL TRIMETHYL AMMONIUM CHLORIDE RXSOL-60-6605-227
PHLOXIN B FOR MICROSCOPY RXSOL-60-6605-229
PHTHALAMIDE FOR SYNTHESIS RXSOL-60-6605-237
PHTHALIC ACID AR RXSOL-60-6605-238
PHTHALIC ACID FOR SYNTHESIS RXSOL-60-6605-239
PHTHALIC ANHYDRIDE FOR SYNTHESIS RXSOL-60-6605-249
PHTHALIDE FOR SYNTHESIS RXSOL-60-6605-250
PHTHALIMIDE FOR SYNTHESIS RXSOL-60-6605-251
PICRIC ACID SOLUTION AR 1.2% RXSOL-60-6605-256
PIPERAZINE Anhydrous 98% RXSOL-60-6605-257
PIPERAZINE Anhydrous 98% RXSOL-60-6605-257
PIPES BUFFER piperazine NN-Bis-2-Ethene Sulfonic acid RXSOL-60-6605-260
PLATINIUM OXIDE Pt 80% RXSOL-60-6605-261
POLYETHYLENE GLYCOL 600 RXSOL-60-6605-269
POLYVINYL PYRROLIDONE PVP RXSOL-60-6605-241
PONCEAU S FOR ELECTROPHORESIS RXSOL-60-6605-242
POPOP Scintillation Grade 1 4-bis5-phenyloxaza-2yl benzene RXSOL-60-6605-243
POPSO BUFFER FOR BIOCHEMISTRY RXSOL-60-6605-244
POTASSIUM ACETATE AR RXSOL-60-6605-245
POTASSIUM ACETATE LR RXSOL-60-6605-246
SODAMIDE RXSOL-60-6605-451
SODIUM ACETATE TRIHYDRATE AR RXSOL-60-6605-462
SODIUM ARSENITE SOLUTION AR 0.1N N10 RXSOL-60-6605-468
SODIUM BENZOATE AR RXSOL-60-6605-472
SODIUM BISELENITE Sodium Hydrogen Selenite RXSOL-60-6605-473
SODIUM BROMATE LR RXSOL-60-6605-481
SODIUM BROMIDE AR RXSOL-60-6605-482
SODIUM BROMIDE LR RXSOL-60-6605-483
SODIUM CHLORIDE SOLUTION0 85% wv RXSOL-60-6605-488
SODIUM CHROMATE TETRAHYDRATE LR RXSOL-60-6605-490
SODIUM DI CHLOROISOCYANURATE RXSOL-60-6605-495
SODIUM HYDROXIDE SOLUTION IN 1M N1 RXSOL-60-6605-519
SODIUM LAURYL SULPHATE AR 99% RXSOL-60-6605-529
SODIUM LAURYL SULPHATE POWDER LR RXSOL-60-6605-531
SODIUM META BORATE TETRAHYDRATE LR RXSOL-60-6605-534
SODIUM METHOXIDE AR RXSOL-60-6605-535
SODIUM METHOXIDE POWDER LR RXSOL-60-6605-536
SODIUM MOLYBDATE AR DIHYDRATE RXSOL-60-6605-537
SODIUM NITRITE AR RXSOL-60-6605-541
SODIUM NITRITE LR RXSOL-60-6605-542
SODIUM NITRO PRUSIDE AR RXSOL-60-6605-543
SODIUM NITRO PRUSIDE LR RXSOL-60-6605-544
SODIUM OXALATE AR RXSOL-60-6605-545
SODIUM PERBORATE TRIHYDRATE PURE RXSOL-60-6605-548
SODIUM PER CARBONATE GRANULAR RXSOL-60-6605-549
SODIUM PER CARBONATE TABLET RXSOL-60-6605-550
SODIUM PERSULPHATE AR RXSOL-60-6605-553
SODIUM PERSULPHATE LR RXSOL-60-6605-554
SODIUM PHOSPHATE DI BASIC DIHYDRATE RXSOL-60-6605-559
SODIUM PYRUVATE RXSOL-60-6605-562
SODIUM SALICYLATE AR RXSOL-60-6605-563
SODIUM SELENITE AR ANHYDROUS RXSOL-60-6605-566
SODIUM SELENITE LR ANHYDROUS RXSOL-60-6605-567
SODIUM SELENITE PENTAHYDRATE LR RXSOL-60-6605-568
SODIUM SILICATE POWDER META HYDRATED RXSOL-60-6605-569
SODIUM SILICATE SOLUTION RXSOL-60-6605-570
SODIUM SILICO FLUORIDE 99% RXSOL-60-6605-571
SODIUM STANNATE LR RXSOL-60-6605-572
SODIUM SULPHATE ANHYDROUS AR RXSOL-60-6605-573
SODIUM SULPHIDE FLAKES AR RXSOL-60-6605-576
SODIUM SULPHITE ANHYDROUS AR RXSOL-60-6605-577
SODIUM SULPHITE ANHYDROUS LR RXSOL-60-6605-578
SODIUM TELLURITE 96% RXSOL-60-6605-579
SODIUM Tert BUTOXIDE 98% RXSOL-60-6605-580
SODIUM THIOCYANATE AR RXSOL-60-6605-581
SODIUM THIOSULPHATE AR PENTAHYDRATE RXSOL-60-6605-583
SODIUM TRI POLYPHOSPHATE ANHYDROUS STPP RXSOL-60-6605-585
SODIUM TUNGSTATE DIHYDRATE RXSOL-60-6605-586
SODIUM TUNGSTATE DIHYDRATE AR RXSOL-60-6605-587
SODIUM B GLYCERO PHOSPHATE AR RXSOL-60-6605-588
SOYA LECITHIN 30% RXSOL-60-6605-592
SOYA PEPTONE SOYATONE RXSOL-60-6605-593
SPADNS AR RXSOL-60-6605-595
SPAN 20 Sorbitan Monolaurate RXSOL-60-6605-596
SPAN 60 Sorbitane Monostearate
Availability
PALLADIUM CALCIUM CARBONATE 10% pd manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
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